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Internal morphology, habit and U-Th-Pb microanalysis of amphibolite-to-granulite facies zircons: geochronology of the Ivrea Zone (Southern Alps) 总被引：52，自引：2，他引：50
Gerhard Vavra Rolf Schmid Dieter Gebauer 《Contributions to Mineralogy and Petrology》1999,134(4):380-404
Several types of growth morphologies and alteration mechanisms of zircon crystals in the high-grade metamorphic Ivrea Zone
(IZ) are distinguished and attributed to magmatic, metamorphic and fluid-related events. Anatexis of pelitic metasediments
in the IZ produced prograde zircon overgrowths on detrital cores in the restites and new crystallization of magmatic zircons
in the associated leucosomes. The primary morphology and Th-U chemistry of the zircon overgrowth in the restites show a systematic
variation apparently corresponding to the metamorphic grade: prismatic (prism-blocked) low-Th/U types in the upper amphibolite
facies, stubby (fir-tree zoned) medium-Th/U types in the transitional facies and isometric (roundly zoned) high-Th/U types
in the granulite facies. The primary crystallization ages of prograde zircons in the restites and magmatic zircons in the
leucosomes cannot be resolved from each other, indicating that anatexis in large parts of the IZ was a single and short lived
event at 299 ± 5 Ma (95% c. l.). Identical U/Pb ages of magmatic zircons from a metagabbro (293 ± 6 Ma) and a metaperidotite
(300 ± 6 Ma) from the Mafic Formation confirm the genetic context of magmatic underplating and granulite facies anatexis in
the IZ. The U-Pb age of 299 ± 5 Ma from prograde zircon overgrowths in the metasediments also shows that high-grade metamorphic
(anatectic) conditions in the IZ did not start earlier than 20 Ma after the Variscan amphibolite facies metamorphism in the
adjacent Strona–Ceneri Zone (SCZ). This makes it clear that the SCZ cannot represent the middle to upper crustal continuation
of the IZ. Most parts of zircon crystals that have grown during the granulite facies metamorphism became affected by alteration
and Pb-loss. Two types of alteration and Pb-loss mechanisms can be distinguished by cathodoluminescence imaging: zoning-controlled
alteration (ZCA) and surface-controlled alteration (SCA). The ZCA is attributed to thermal and/or decompression pulses during
extensional unroofing in the Permian, at or earlier than 249 ± 7 Ma. The SCA is attributed to the ingression of fluids at
210 ± 12 Ma, related to hydrothermal activity during the breakup of the Pangaea supercontinent in the Upper Triassic/Lower
Jurassic.
Received: 7 July 1998 / Accepted: 4 November 1998 相似文献
2.
In the Barrios Formation of the southern Cantabrian Mountains pyroclastic rocks occur which have an Ordovician age. They form the filling of several craters and pipes, which are unconformably overlain by Ordovician respectively Silurian sediments. The pyroclastic material mainly consists of fractured quartz grains which are mixed with angular hydrothermally altered glas lapilli. The strong fragmentation of the volcanoclastic components, even in the lower parts of the pipes, is caused by phreatomagmatic eruptions under shallow marine conditions. The Barrios Formation which is disrupted by the volcanic necks, was deposited in a shallow marine environment with a very low sedimentation rate.Sills occur in the Oville-Formation below the Barrios Formation. They are partially older than the pyroclastic rocks. These older sills intruded into not yet lithified shales and sands where a high hydrostatic pressure prevented a phreatomagmatic explosion.Major and trace element analyses reveal that the sills in the Oville-Formation, volcanic bombs, subvolcanic xenoliths and a plug within the pyroclastic rocks belong to the alkali rock series. They are enriched in K, Ti, P and Zr and are similar to alkali olivine basalts and trachy-basalts.The Ordovician volcanism of the Cantabrian Mountains occured on continental crust which was subject to rifting in the Early Palaeozoic. The rifting processes are seen in connection with the separation of the Ibero-Armorican microplate from Gondwana.
Zusammenfassung In der Barrios-Formation des südlichen Kantabrischen Gebirges treten pyroklastische Gesteine auf, die ein ordovizisches Alter haben. Sie bilden die Füllung mehrerer Krater und Schlote, die an ihrer Obergrenze diskordant von ordovizischen bzw. silurischen Sedimenten überlagert werden. Das pyroklastische Material besteht zum größten Teil aus zerbrochenen Quarzkörnern mit eingestreuten, scharfkantigen, hydrothermal veränderten Glaslapilli. Die starke Fragmentierung des vulkanoklastischen Anteiles selbst in den tieferen Bereichen der Schlote wurde durch phreatomagmatische Eruptionen unter flachmarinen Bedingungen verursacht. Der Barriosquarzit, der von den Schloten und Kratern durchschlagen wird, wurde in einem flachmarinen Bereich mit sehr niedriger Sedimentationsrate abgelagert.Lagergänge treten in der Oville-Formation im Liegenden der Barrios-Formation auf. Sie sind teilweise älter als die pyroklastischen Gesteine. Diese älteren Lagergänge intrudierten in die noch nicht verfestigten Tone und Sande, wo ein zu großer hydrostatischer Druck eine phreatomagmatische Explosion verhinderte.Haupt- und Spurenelementanalysen zeigen, daß die Lagergänge in der Oville-Formation, vulkanische Bomben, subvulkanische Xenolithe und ein Lavapfropfen innerhalb der Pyroklastika zu den Alkaligesteinen gehören. Sie sind angereichert an K, Ti, P und Zr und ähneln Alkaliolivinbasalten und Trachybasalten.Der ordovizische Vulkanismus des Kantabrischen Gebirges ereignete sich auf kontinentaler Krustenunterlage, welche im Altpaläozoikum einer Dehnung ausgesetzt war. Die Dehnungsprozesse werden im Zusammenhang mit der Abtrennung der ibero-amerikanischen Mikroplatte von Gondwana gesehen.
Résumé Dans la formation de Barrios, dans les Monts Cantabriques méridionaux, existent des roches pyroclastiques d'âge ordovicien. Elles forment le remplissage de cratères et de cheminées surmontés en discordance par des sédiments ordoviciens ou siluriens. Pour leur plus grande part, ces matériaux pyroclastiques consistent en grains brisés de quartz mêlés de fragments hyaloclastiques anguleux altérés par des solutions hydrothermales. Les composants volcanoclastiques sont fortement fragmentés, même dans les zones les plus profondes des cheminées, phénomène causé par des explosions phréatomagmatiques dans une mer peu profonde. De fait, la formation du quartzite de Barrios, qui est percée par les cheminées, s'est déposée dans un milieu marin peu profond, à faible vitesse de sédimentation.La formation d'Orville, située sous la formation de Barrios, renferme des sills. Ces sills, en partie plus vieux que les roches pyroclastiques, se sont intrudés dans des pélites et des sables non encore lapidifiés, où la haute pression hydrostatique empêchait une explosion phréatomagmatique.Les analyses des éléments chimiques majeurs et en trace montrent que les sills, les bombes volcaniques, les xénolithes subvolcaniques et un culot de lave dans les roches pyroclastiques font partie de la séries alcaline. Ces roches sont enrichies en K, Ti, P, Zr et semblables aux basaltes alcalins à olivine et aux trachybasaltes.Le volcanisme ordovicien des Monts Cantabriques s'est manifesté dans une croûte continentale soumise à extension pendant le Paléozoque inférieur. Cette extension est mise en relation avec la séparation entre la micro-plaque ibéroarmoricaine et le continent de Gondwana.
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3.
Post-granulite facies monazite growth and rejuvenation during Permian to Lower Jurassic thermal and fluid events in the Ivrea Zone (Southern Alps) 总被引：11，自引：2，他引：9
U-Pb analyses of single monazite grains from two granulite facies metapelites in the Ivrea Zone (Southern Alps) reveal the
presence, in both samples, of at least three different ages and prove that earlier interpretations of supposedly concordant
monazite data as cooling ages are unwarranted. One group of monazite data defines a subconcordant discordia line with an upper
intercept age of 293.4 ± 5.8 Ma and a lower intercept age of 210 ± 14 Ma. The upper intercept is interpreted as the real cooling
age of the monazites. The lower intercept is interpreted as an episode of fluid-driven Pb-loss, indicated by the presence
of internal and external corrosion structures not only of the monazites but also of the zircons in the same samples that are
also rejuvenated at 210 ± 12 Ma. Another group of monazite data lies above the concordia. The presence of excess 206Pb indicates that these crystals have grown below the monazite blocking temperature, thus after the granulite facies metamorphism.
The age of growth of the new monazite crystals is approached by their 207Pb/235U ages that range between 273 and 244 Ma. The two groups of post-cooling age (post-293.4 ± 5.8 Ma) monazite data correspond
to two distinct late- and post-Variscan geotectonic regimes that affected the Southern Alps, (1) Permian transtension with
decompression and anatectic melting; (2) Upper Triassic to Lower Jurassic rifting with geographically dispersed hydrothermal
activity and alkaline magmatism.
Received: 7 July 1998 / Accepted: 4 November 1998 相似文献
4.
5.
Metamictisation of natural zircon: accumulation versus thermal annealing of radioactivity-induced damage 总被引：12，自引：0，他引：12
Lutz Nasdala Marita Wenzel Gerhard Vavra Gert Irmer Thomas Wenzel Bernd Kober 《Contributions to Mineralogy and Petrology》2001,141(2):125-144
Annealing of the radiation damage generated in !-decay events is a common phenomenon in natural zircons. We have studied relationships between radiation damage, age and radionuclide content of natural zircons on a micro-scale. The degree of metamictisation was estimated by means of confocal laser-Raman spectroscopic measurements. Raman band broadening in well-ordered to moderately metamict zircons that have not experienced significant healing of the radiation damage since the time of their growth, shows a nearly linear dependence on the !-fluence. This dependence is proposed as a calibration line for examining unknown zircons in order to consider complete or incomplete damage storage, which may contribute to the understanding of the low-T thermal history of their host rocks. Seven examples for the application are presented. Radiation damage may anneal heterogeneously, with preferred re-ordering in more damaged micro-areas. Results suggest that single point defects do not anneal continuously over geologic periods of time but are, in contrast, a comparably stable type of radiation damage. In contrast to recrystallisation processes, structural recovery due to simple thermal annealing is not necessarily connected with loss of radiogenic Pb. The most prominent example for this are concordant zircons from Sri Lanka. Although they are excellent standards for U-Pb dating, Sri Lankan zircons should not be used as standards for structural radiation damage. The experimental work is completed by Monte Carlo simulations of !-decay events in zircon. 相似文献
6.
G. Vavra Dieter Gebauer Rolf Schmid William Compston 《Contributions to Mineralogy and Petrology》1996,122(4):337-358
Zircons from a metasedimentary and a meta-igneous quartz-feldspar granulite from the Val Sesia and Val Mastallone area of
the Ivrea Zone (Southern Alps) differ in their response to granulite facies metamorphism with respect to crystal morphology
and U/Pb ages. Detrital zircons in the metasediment developed an isometric overgrowth by the addition of Zr derived mainly
from co-existing minerals, most probably biotite, decomposing during anatectic melting. The overgrowth started in the pelitic
layer of the metasediment in the Late Carboniferous at approximately 296 Ma, significantly earlier than in the adjacent psammitic
layer where it started only at 261 ± 4 Ma (95% confidence level). These ages are ascribed to the differential initiation of
anatexis in the two layers. The delay of melting in the psammitic layer was probably due to the different position and less
steep slope of its solidus in P-T-space, as compared to the solidus in the pelitic layer. Accordingly, the melting in the psammitic layer at 261 Ma was initiated
by a thermal pulse and/or by a decompression event. Decompression melting is supported by a characteristic shell morphology
of the zircon overgrowth in the psammitic layer, which might have grown under shear movements during high-temperature extensional
faulting. The typically magmatic zircon population of the meta-igneous granulite crystallized at 355 ± 6 Ma (95% confidence
level). The morphology of the zircons and the chemistry of the rock suggest that the magma was calcalkaline. A minor subpopulation
of crystals is morphologically similar to the zircons in the pelitic layer of the metasediment. This points to the admixture
of a minor sediment component and, thus, to a largely volcaniclastic origin of the protolith. In contrast to the detrital
zircons in the metasediment, the magmatic zircons show rare and little overgrowth and, instead, have been strongly resorbed
by anatectic melt. In addition, they became partially recrystallized and the rejuvenated ages from the most thoroughly recrystallized
domains indicate that the rock was subject to prograde metamorphism after 279 Ma. This may correspond to the regional temperature
increase prior to the climax of metamorphism or to a local thermal pulse due to nearby mafic intrusions. An Upper Triassic
event at 226 ± 5 Ma is reflected by distinct peripheral zones in the overgrowths of some zircons in the metapelite. These
are interpreted as a second metamorphic pulse, possibly induced by the infiltration of fluids.
Received: 2 June 1995 / Accepted: 15 September 1995 相似文献
7.
On the kinematics of zircon growth and its petrogenetic significance: a cathodoluminescence study 总被引：26，自引：0，他引：26
Gerhard Vavra 《Contributions to Mineralogy and Petrology》1990,106(1):90-99
The relative growth rates of zircon crystal faces are recorded by growth zoning, which is recognizable in cathodoluminescence photographs of oriented crystal sections. The kinematics of zircon growth is graphically presented by the slopes of Grabahnen between crystal sectors. The relative velocities of advance of crystal faces correlate to the pattern of growth zoning. Widely spaced zoning, interrupted by surfaces of dissolution, on the one hand, and narrowly spaced uninterrupted oscillatory zoning, on the other hand, are interpreted as markers of low and high zircon-supersaturation of the melt, respectively. The following model is deduced from this correlation. The prism {110} is that crystal form, the growth rate of which reacts most sensitively to the zircon-supersaturation of the melt. The growthrate of the steep pyramid {211} is not primarily controlled by zircon-supersaturation. Instead, the growth of {211} is delayed by the adsorption of foreign atoms on its faces. The kinematics of zircon growth in anatectic, plutonic and meta-rhyolitic host rocks in the pre-Mesozoic basement of the Tauern Window (Eastern Alps) is explained by this model. Results show that the kinematics of zircon growth carry a much greater petrogenetic significance than has been previously suggested for the final shape of crystals alone. 相似文献
8.
Gerhard Vavra 《Contributions to Mineralogy and Petrology》1994,117(4):331-344
The internal morphologies of zircon crystals from different types of granitoids (alkaline, calcalkaline and anatectic) are revealed by cathodoluminescence imaging and are described in terms of growth rates of the crystal faces relative to each other. Zircons in the alkaline granitoids are characterized by high and constant growth rates of {010} relative to the pyramidal forms and by symmetric grwoth of {011}. Zircons in the calcalkaline and anatectic granitoids are characterized by fluctuating or gradually decreasing relative growth rates of {010}, by asymmetric and highly variable growth of {011}, and by a tendency of {110} to become grwoth-inhibited. Corrosion events are interspersed during zircon growth in the calcalkaline magmas. In the calcalkaline and anatectic magmas, a discontinuity breaks the morphological evolution at late stages of crystallization. The discontinuity coincides with a sharp drop in cathodoluminescence. The growth behaviour of each crystal form is analysed and compared with predictions made by the periodic bond chain (PBC) theory. It is argued that the relative growth rate of {010} depends on supersaturation, that the growth rates of {011} faces are changed in response to different ratios of adsorbing cations (Na, K, Al), and that {110} faces become growth-inhibited by the adsorption of H2O or trace elements enriched in the residual liquid. Morphological and chemical discontinuities at late stages of crystallization are reasonably explained by the formation of larger growth units (from smaller ionic entities) in the residual liquid. Important factors controlling the zircon morphology in different types of granitoids are: high cooling rates (alkaline magmas), magma mixing (calcalkaline magmas), enrichment of H2O and trace elements in residual liquids (calcalkaline and anatectic magmas), and the major element chemistry of the magma, possibly the ratio of Na and K to Al (agpaicity). 相似文献
9.
The pre-Mesozoic basement in the eastern and central part of the Tauern Window (Eastern Alps) consists mainly of anatectic plagioclase gneisses and amphibolites intruded and migmatized by Carboniferous granitoids. The gneisses are geochemically similar to calcalkaline dacites of modern primitive island arcs. Cathodoluminescence investigations and U/Pb-data on zircons indicate an uppermost Proterozoic or Cambrian extrusion age of the dacitic protoliths and a Carboniferous syngranitoid anatexis around 320 Ma. High-K calcalkaline meta-rhyolites in the north central Tauern Window form a separate part of the basement not affected by Carboniferous anatexis and plutonism. Their protoliths extruded in the Lower Carboniferous. In the Permian, high-K granitoids intruded the anatectic basement.Results are consistent with an island-arc system evolving from a Late Proterozoic and Early Paleozoic primitive stage to a Lower Carboniferous mature stage represented by K-rich rhyolite volcanism. An Upper Carboniferous collisional event caused anatexis, affecting mainly the K-rich calcalkaline rocks. The last calcalkaline magmas intruded in a Permian post-collisional setting.
Zusammenfassung Das prä-mesozoische Grundgebirge des östlichen und zentralen Tauernfensters (Ostalpen) besteht größtenteils aus anatektischen Plagioklasgneisen und Amphiboliten, welche von karbonischen Granitoiden intrudiert und migmatisiert werden. Die Plagioklasgneise entsprechen geochemisch kalkalkalischen Daziten primitiver Inselbögen. Die anhand von Kathodolumineszenzaufnahmen ausgewerteten U/Pb-Daten der Zirkone weisen auf ein jüngst-proterozoisches oder kambrisches Extrusionsalter der dazitischen Protolithe und auf eine karbonische syn-granitoide Anatexis um 320 Ma. High-K kalkalkalische Metarhyolithe im nördlichen Teil des zentralen Tauernfensters bilden einen separaten Teil des Grundgebirges, der von karbonischer Anatexis und Plutonismus nicht berührt wurde. Ihre Protolithe extrudierten im unteren Karbon. Das anatektisch überprägte Grundgebirge aus Plagioklasgneisen und Amphiboliten wurde im Perm von high-K Granitoiden intrudiert.Die Ergebnisse sind konsistent mit der Entwicklung von einem jung-proterozoischen und alt-paläozoischen primitiven Inselbogen zu einem unter-karbonischen reifen Inselbogen mit K-reichen Rhyolith-Vulkanismus. Ein ober-karbonisches Kollisions-Ereignis führte zur Anatexis insbesondere der K-reichen kalkalkalischen Gesteine. Die letzten kalkalkalischen Magmen intrudierten postkollisional im Perm.
Résumé Le socle pré-Mésozoïque du centre et de l'est de la Fenêtre des Tauern (Alpes orientales), est principalement composé de gneiss plagioclasiques anatectiques et d'amphibolites. Des granitoïdes carbonifères sont intrusifs dans ce socle et le migmatitisent. Les gneiss sont géochimiquement comparables à des dacites calco-alcalines d'arc insulaire immature. Des études sur zircons par cathodoluminescence et datation U-Pb indiquent, pour les dacites, un âge d'extrusion protérozoïque supérieur ou cambrien. L'anatexie contemporaine de la mise en place des granitoïdes est datée aux alentours de 320 Ma. Dans le nord de la partie centrale de la fenêtre, des méta-rhyolites calco-alcalines riches en potassium forment une zone distincte du socle et ne sont pas affectées par l'anatexie et le plutonisme carbonifère. Leur extrusion date du Carbonifère inférieur. Au Permien, des granitoïdes riches en potassium ont recoupé le socle anatectique.Les résultats sont en accord avec une évolution d'arc insulaire depuis un stade primitif d'âge protérozoïque supérieur ou paléozoïque inférieur jusqu'à un stade de maturité d'âge carbonifère inférieur représenté par les rhyolites riches en potassium. Au Carbonifère supérieur, un événement de collision a provoqué l'anatexie qui affecte principalement les roches calco-alcalines riches en potassium. Les derniers magmas calco-alcalins se sont intrudés dans le contexte post-collisionnel Permien.
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