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1.
The primary phases and minerals of the Plombières dumps include typical smelting furnace products such as metallic Fe, Pb, Cu, Zn, Fe-Zn alloys, carbides, phosphides, sulfides of Fe, Zn, Pb, Cu, Mn (alabandite), and FeAs. Spinels, mainly of Fe and Al, are common constituents of the primary assemblage; substitution by Zn, V, Cr, Ti, Mg, and Ca occurs. Primary phases also include the most common Zn-rich fayalite, Zn-rich Ca-Fe silicates, melilite, corundum, and apatite. Most of the Zn is incorporated in iron silicates, ZnO and ZnS. Lead occurs mainly as PbS, metallic lead, and is also present in coal residues. Cadmium is found mainly in metallic zinc and its alloys and in ZnO. The dumps also contain mining wastes composed of pyrite, melnikovite, and iron oxides produced by natural weathering of Zn-Pb ores. Melnikovite and iron oxides are rich in As, Pb, and Zn and possess an increased content of Tl. Leaching tests carried out on the surfaces of polished sections indicate that acid rain (solutions I and II) will mobilize mainly Zn and Cd and, to a much smaller extent, Pb and Sb. Leaching of metals by sulfate-chloride fluids present in the pore network of dumps (solutions III, IV, and V) depends on the pH, which in the dumps is controlled by the proportion of carbonates to sulfides. The more acid fluids leach both sulfides and silicates. 相似文献
2.
The lithogeochemical distribution patterns of Mg, Sr, Na, Zn, Pb, Fe, Mn, K, Corg (organic matter) and IR (insoluble residue) in the Dinantian limestones and dolomites from the eastern part of Belgium have been studied (Dinant and Verviers synclinorium). Comparison of geochemical data of non-mineralized strata revealed higher background values in the strata of the Verviers synclinorium where Pb-Zn mineralizations occur. In this area a relation may exist with the metallogenetic district (Herve-Vesdre-Theux district; proposed by Dejonghe 1985b). However, the higher background values also could relate to the more restricted sedimentation conditions in the Verviers synclinorium as opposed to the more open marine conditions in the Dinant synclinorium. The influence of mineralization on the geochemistry of limestones is limited and unpredictable. In dolomites, however, the effect can be important. In these rocks, the lithogeochemical distribution of Zn, Pb and Mn can be subdivided into three populations, i.e. a regional background, a local high background and a halo population. The higher trace element concentrations in the halo population is caused by the existence of disseminated sulfide minerals (sphalerite, galena and pyrite) and Zn-bearing goethite (mainly pseudomorphs after pyrite) and Mn-oxides. The sulfides relate to the ore emplacement. In the local high background only the Zn-bearing oxides occur. Their presence and thus the development of the local high background relates to weathering processes. 相似文献
3.
Peloids from sediment-hosted Zn-Pb deposits in Belgium, Ireland and Poland are composed of Zn-calcite, siderite, smithsonite, silica, pyrite, melnikovite, sphalerite, galena, thiosulphates and Zn-As-bearing limonite. The size of peloids is between 7 and 60 m. The core and the shell of peloids are composed of different minerals and the shell is usually coarsely crystalline. Peloids are present in collapse breccias of karst cavities, stromatactis cavities, debris-flow breccias, and fractures cross-cutting carbonates hosting the mineralization. In places peloids form a major microtexture of the sulfide mineralization. Peloids are cemented and replaced by sulfides. Organic acids extracted from sulfide peloids are composed of amido-acids considered to be characteristic of bacterial origin. The size and specific texture of peloids are independent of mineralogy, location and age of the mineralization. Therefore the peloids disussed are considered as forms induced by bacterial activity rather than forms precipitated inorganically. 相似文献
4.
This method has been developed for the determination of tungsten in silicate rocks containing resistant minerals. The method consists of fusion of the sample with lithium metaborate, followed by evaporation with hydrofluoric acid in order to remove silicon. Thereafter the residue is treated with concentrated hydrochloric acid. By the reaction of tungsten with dithiol, a blue-green complex is formed. This is extracted with petroleum spirit and its absorption is measured in a spectrophotometer. This method was found to provide a thorough sample attack and an adequate determination of tungsten. 相似文献
5.
P. Muchez Y. Zhang L. Dejonghe W. Viaene E. Keppens 《International Journal of Earth Sciences》1998,87(3):373-380
The geochemical evolution of the fluids migra- ting at the Variscan thrust front in eastern Belgium has been investigated by a petrographic, mineralogical and geoche-mical study of ankerite, quartz and ferroan calcite veins hosted by lower Devonian rocks. Three vein generations have been recognized. The first generation consists of quartz, chlorite and ankerite filling pre- to early Variscan extensional fractures. The second generation is present as shear veins of Variscan age, and contains quartz, chlorite and ferroan calcite. The third generation consists of ankerite filling post-Variscan fractures. The oxygen and carbon isotopic composition of the two ankerite phases and of the ferroan calcites are respectively between –16.4 and –11.4‰ PDB between –17.8 and –1.7‰ PDB. This range is greater than that of calcite nodules in the lower Devonian siliciclastic sediments (δ18O= –15.6 to –11.1‰ PDB and δ13C= –13.4 to –10.2‰ PDB). This suggests precipitation of the carbonate veins from a fluid which was at most only partly isotopically buffered by the calcite nodules in the host rock. The calculated oxygen isotopic composition of the ambient fluid from which the calcite veins formed is between +7.8 and +10.0‰ SMOW. Two main fluid types have been recognized in fluid inclusions in the quartz and carbonates. The first fluid type is present as secondary fluid inclusions in the first and second vein generations. The fluid has a salinity of 0.5–7.2 eq. wt.% NaCl and a high, but variable, homogenization temperature (Th=124–188°C). Two origins can be proposed for this fluid. It could have been expelled from the lower Devonian or could have been derived from the metamorphic zone to the south of the area studied. Taking into account the microthermometric and stable-isotope data, and the regional geological setting, the fluid most likely originated from metamorphic rocks and interacted with the lower Devonian along its migration path. This is in agreement with numerical simulations of the palaeofluid and especially the palaeotempera-ture field, which is based on chlorite geothermometry and vitrinite reflectance data. The second fluid type occurs as secondary inclusions in the shear veins and as fluid inclusions of unknown origin in post-Variscan ankerite veins. Therefore, it has a post-Variscan age. The inclusions are characterized by a high salinity (18.6–22.9 eq. wt.% CaCl2). The composition of the fluid is similar to that which caused the development of Mississippi Valley-type Pb–Zn deposits in Belgium. 相似文献
6.
An interatomic interaction potential for silica polymorphs is derived based on the SCD model (cfr. Tijskens et al. 1994). This interaction potential incorporates all classical electrostatic interactions arising from the spherical part of the spatial extent of the atoms including many body interactions. The potential is derived from Hartree-Fock energies and electron densities for a set 72 [SiO4]4-- and [Si2O7]6--clusters with variable configuration. The long range impact of the surroundings on these clusters in the infinite system has been successfully mimicked by embedding the clusters in a finite three-dimensional array of point charges. This three-dimensional array of point charges is optimized as to reproduce the average site potential and its gradient occurring in II–IV-coordinated silica polymorphs at the central atoms of the clusters. The resulting interaction potential consists of two functions of the configurational coordinates, ?, describing spherical “atomic” electron densities, σa(x, ?) for A=Si, O. All classical electrostatic interactions are derived from these densities. A Born-Mayer type correction term ΔE qm(?) models the quantum mechanical interactions and the electrostatic interactions arising from the non-spherosymmetrical component of the electron density. The new interaction potential model shows a slightly improved reproduction of the potential surface with respect to the classical Born-Mayer ionic model and demonstrates the importance of many body interactions as charge transfer and expansion/contraction of the atomic electron densities in these systems. Also the dependence of the quantum mechanical correction term ΔE qm(?) on the Si-O-Si-bond angle proves covalent effects to be larger than suggested by the classical Born-Mayer ionic model thereby clarifying the controversy in literature on the importance of covalent effects in silica polymorphs and polymerised silicates in general. 相似文献
7.
Ann Vanclooster Nina Vanhaeren Pepijn Viaene Kristien Ooms Laure De Cock Veerle Fack 《International journal of geographical information science》2013,27(11):2284-2304
ABSTRACTPresent-day indoor navigation systems are often not well adapted to the specific needs and requirements of its users. This research aims at improving those indoor navigation systems by providing navigation support that cognitively closer to user preferences and behaviour. More specifically, the focus is on the implementation of an accurate turn calculation method in a turn minimization algorithm, aiming to lower the complexity of routes and route instructions. This new-introduced perception-based turn calculation procedure is based on a direct door-to-door walking pattern, and, in contrast to previous algorithms, independent of the underlying indoor network type. It takes into account the effects of geometry of indoor space on human movement. To evaluate its functioning, both the traditional algorithm and the proposed perception-based algorithm are applied in the fewest turns path algorithm. It is demonstrated that the proposed algorithm accurately calculates turns in alignment with people’s perception. The implementation of the calculation algorithm in the fewest turns path algorithm also allows future applications in indoor simplest path algorithms, and overall contributes to cognitively richer indoor navigation systems. 相似文献
8.
A geochemical soil survey has been carried out near a known mineralized vein in the argentiferous area of Hiendelaencina, Spain. The distribution of Ag, Sb, As, Ba, Pb, Zn, Cu, Fe, Mn, Ni and Co was studied and the results treated with univariate and multivariate analysis. The geochemical halo around the known mineralization shows a longitudinal variation giving rise to specific element associations i.e. As-Sb-Ag(-Mn), Fe-Mn-Cu-Ni and Zn-Pb-Ba. About 500 m to the south of the known mineralization a strong geochemical anomaly of As, Sb and Ag is probably produced by a new vein. The whole pattern of anomalies and element associations is in agreement with existing metallogenetic hypotheses. 相似文献
9.
Van Keer I. Ondrak R. Muchez Ph. Bayer U. Dusar M. Viaene W. 《Geologie en Mijnbouw》1997,76(4):301-311
A 1D-modelling program has been applied to reconstruct the burial and thermal histories of two exploration boreholes, KB172 and KB174, located in the Campine Basin. The results show differences in geological histories. The coalification of the Westphalian A and B strata in KB174 (0.66–0.98% Ro) was pre-Permian. Calculated maximum temperatures, based on borehole data and vitrinite reflectance, regional thicknesses and a heat flow of 84 mW/m2 during the Late Westphalian, range from 110 °C at the top to 175 °C at the bottom of the Westphalian cored in this borehole. The high coalification (0.85–1.30% Ro) of the Westphalian C and D strata in KB172 could be the result of the deposition of 2500 m of Upper Permian to Middle Jurassic sediments in combination with elevated heat flows (71–80 mW/m2). Two coalification periods, i.e. Late Westphalian and Middle Jurassic, are suggested for this borehole. The simulated maximum temperatures range from 130 °C at the top to 175 °C at the bottom of the investigated Westphalian C and D. The differences in the burial and thermal histories of both boreholes can be related to the activity of the transversal Donderslag Fault, a major structural element in the Campine coalfield, and the Roer Valley Graben. 相似文献
10.
Compounds of Fe, Pb and Zn with mixed and intermediate sulfur valences form ubiquitous inclusions and relics in banded sphalerite, pyrite-melnikovite and galena. Banded sulfides continuously grade into banded compounds with mixed and intermediate sulfur valences, the latter with a fibrous microtexture. A fibrous microtexture is also shown by banded sphalerite and pyrite from Zn-Pb deposits of Belgium and Poland. It is therefore suggested that the fibrous sphalerite inherited such a microtexture, unusual for cubic ZnS, by direct replacement of a fibrous precursor with mixed and/or intermediate sulfur valences. The last band of banded sphalerite is often overgrown by idiomorphic, isometric sphalerite precipitated directly from the solution as ZnS. The following Fe, Pb and Zn compounds with mixed and intermediate sulfur valences were found in carbonate-hosted Zn-Pb deposits of Belgium and Poland: sulfoxylanes (M2+SO2; S2+), subsulfites (M2+S2O4; S3+), sulfites (M2+SO3; S4+), pyrosulfites (M2+S2O5; S4+) and thiosulphates(M2+S2O3; S2– and S6+). 相似文献