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C. Lerouge A. Kunov C. Flhoc S. Georgieva A. Hikov J.L. Lescuyer R. Petrunov N. Velinova 《Journal of Geochemical Exploration》2006,90(3):166-182
Voluminous areas of advanced argillic alteration (AAA) constitute major exploration targets for surficial Cu–Au epithermal and potentially underlying porphyry-type deposits. In Bulgaria, more than 30 alunite occurrences are recognised, few of them being associated with a mineralised system. A mineralogical study combined with a stable isotopic (O, H, S) study has been carried out on nine alunite occurrences of advanced argillic zones hosted by volcanic rocks of Late Cretaceous age in the Srednogorie belt and of Oligocene age in the Rhodopes belt. This work was realised in order to constrain the origin of alunite and to define criteria to discriminate alunite from ore deposits and alunite from large barren alteration systems.Mineralogy of the nine occurrences consists of alunite + quartz + minor alumino-phospho-sulphates, associated with more or less kaolinite, dickite, pyrophyllite, diaspore and zunyite, depending on formation temperature. Alunite generally occurs as tabular crystals but is also present as fine-crystalline pseudocubic phases at Boukovo and Sarnitsa, in Eastern Rhodopes. In the advanced argillic alterations associated with economic ore, the presence of zunyite in the deeper parts indicates acid–fluorine–sulphate hydrothermal systems, whereas it is absent in uneconomic and barren advanced argillic alteration. All occurrences are formed at temperatures between 200 and 300 °C.(H, O, S) isotopic signatures of alunite combined with mineralogical features from all the studied occurrences, whatever their type, show characteristics of magmatic-hydrothermal systems. Sulphur data indicate essentially a magmatic origin for sulphur. Oxygen and hydrogen data suggest that hydrothermal fluids result from a mixing between magmatic fluids and an external component, which is identified as seawater-derived fluids or meteoric water in the vicinity of a sea. In most of the alunite occurrences, magmatic fluids are dominant and H2S/SO4 ratios are estimated to be higher than 2. Two exceptions exist in the Rhodopes. At Boukovo and Sarnitsa, where the estimated formation temperatures of alunite are the lowest, the external fluids are dominant and H2S/SO4ratios are estimated to be lower than or close to 1.At this stage of the work, the mineralogical and isotopic criteria do not enable a clear distinction between economic and uneconomic systems. However, some features are common in the economic ore deposits: the presence of zunyite in the deeper part of the system, the relatively high temperatures suggested by the zunyite + pyrophyllite + alunite + diaspore assemblages, the (O, H, S) signature of alunite, which is characteristic of dominant magmatic–hydrothermal acid–sulphate–fluorine systems. 相似文献
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Massimiliano Burlando Emilia Georgieva Corrado F. Ratto 《Boundary-Layer Meteorology》2007,125(2):389-397
The planetary boundary-layer (PBL) parameterization is a key issue for the definition of initial wind flow fields in diagnostic
models. However, PBL theories usually treat separately stable, neutral, and convective stability conditions, so that their
implementation in diagnostic wind models is not straightforward. In the present paper, an attempt is made to adopt a comprehensive
PBL parameterisation, covering stable/neutral and unstable atmospheric conditions, which appears suitable to diagnostic models.
This parameterisation is implemented into our diagnostic mass-consistent code. A validation of the consistency between the
implemented PBL parameterisations has been checked through an analysis of the sensitivity of the vertical wind profiles to
atmospheric stability. 相似文献
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Sandra Freiboth Holger Class Rainer Helmig Tobias Graf Wolfgang Ehlers Viktoria Schwarz Christos Vrettos 《Computational Geosciences》2009,13(3):281-300
Multiphase flow processes in unsaturated cohesive soils are often affected by deformation due to swelling and shrinking as
a result of varying water contents. This paper presents a model concept which is denoted ‘phenomenological’ in terms of the
processes responsible for soil deformation, since the effects of deformation on flow and transport are only considered by
constitutive relations that allow an adaptation of the hydraulic properties. This new model is validated in a detailed intercomparison
study with two state-of-the-art models that are capable of explicitly describing the processes relevant for the deformation.
A ‘numerical experiment’ with a state-of-the-art reference model is used to produce ‘measurement data’ for an inverse-modelling-based
estimation of the model input parameters for the phenomenological concept. 相似文献
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This study presents the first suite of apatite fission‐track (AFT) ages from the SE part of the Western Sudetes. AFT cooling ages from the Orlica‐?nie?nik Dome and the Upper Nysa K?odzka Graben range from Late Cretaceous (84 Ma) to Early Palaeocene–Middle Eocene (64–45 Ma). The first stage of basin evolution (~100–90 Ma) was marked by the formation of a local extensional depocentre and disruption of the Mesozoic planation surface. Subsequent far‐field convergence of European microplates resulted in Coniacian–Santonian (~89–83 Ma) thrust faulting. AFT data from both metamorphic basement and Mesozoic sedimentary cover indicate homogenous Late Cretaceous burial of the entire Western Sudetes. Thermal history modeling suggests that the onset of cooling could be constrained between 89 and 63 Ma with a climax during the Palaeocene–Middle Eocene basin inversion phase. 相似文献
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The correlation between geomagnetic activity and the sunspot number in the 11-year solar cycle exhibits long-term variations due to the varying time lag between the sunspot-related and non-sunspot related geomagnetic activity, and the varying relative amplitude of the respective geomagnetic activity peaks. As the sunspot-related and non-sunspot related geomagnetic activity peaks are caused by different solar agents, related to the solar toroidal and poloidal fields, respectively, we use their variations to derive the parameters of the solar dynamo transforming the poloidal field into toroidal field and back. We find that in the last 12 cycles the solar surface meridional circulation varied between 5 and 20 m/s (averaged over latitude and over the sunspot cycle), the deep circulation varied between 2.5 and 5.5 m/s, and the diffusivity in the whole of the convection zone was ～108 m2/s. In the last 12 cycles solar dynamo has been operating in moderately diffusion dominated regime in the bulk of the convection zone. This means that a part of the poloidal field generated at the surface is advected by the meridional circulation all the way to the poles, down to the tachocline and equatorward to sunspot latitudes, while another part is diffused directly to the tachocline at midlatitudes, “short-circuiting” the meridional circulation. The sunspot maximum is the superposition of the two surges of toroidal field generated by these two parts of the poloidal field, which is the explanation of the double peaks and the Gnevyshev gap in sunspot maximum. Near the tachocline, dynamo has been operating in diffusion dominated regime in which diffusion is more important than advection, so with increasing speed of the deep circulation the time for diffusive decay of the poloidal field decreases, and more toroidal field is generated leading to a higher sunspot maximum. During the Maunder minimum the dynamo was operating in advection dominated regime near the tachocline, with the transition from diffusion dominated to advection dominated regime caused by a sharp drop in the surface meridional circulation which is in general the most important factor modulating the amplitude of the sunspot cycle. 相似文献