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1.
The interrelations of the latitudinal distribution of the coronal green emission maxima, maximal numbers and areas of prominences, magnetic fields, sunspots, and polar faculae in the 20th and 21st sunspot cycles have been investigated. It is again demonstrated how the behaviour of all studied data depends on their heliographic latitude. In the polar zone, well separated from the equatorial we observe following polarity magnetic fields transported only polewards, while the equatorial zone is occupied mostly by leading polarity fields, developed there, moving equatorwards, and crossing the equator to the other hemisphere with the new cycle during the minimum of sunspot activity.This magnetic field distribution is well emphasized by the places of maximal occurrence of prominences and by the distribution of coronal green emission maxima which also differ in dependence on latitude.The question of identifying the first and last evolutionary stages of an extended cycle of activity is discussed and the existence of a magnetic activity cycle lasting 15–17 years is suggested. 相似文献
2.
To discriminate possible anthropogenic and lithogenic sources of Pb in Lower Silesia (SW Poland), the Pb isotope composition was investigated in a spectrum of rocks and anthropogenic materials as well as within 10 soil profiles. Silicate rocks in Lower Silesia have 206Pb/207Pb ratios that vary from 1.17 for serpentinites to 1.38 for gneisses, and this variability is reflected in the isotope composition of the mineral soil horizons. The Pb isotope composition of coals, ores and anthropogenic materials (slags and fly ashes) is rather uniform, with 206Pb/207Pb ratios ranging from 1.17 to 1.18. Similar ratios were observed in ore and coal samples from Upper Silesia. The O soil horizons also have uniform 206Pb/207Pb ratios of 1.17–1.18 and the heterogeneity of the 206Pb/207Pb ratios increases with depth in the soil profiles. Five soils, with varying Pb concentrations, analysed far from contamination centres, show consistent, approximately 2-fold enrichment in Pb concentration from the C to A horizons, which is consistent with natural re-distribution of Pb within the profiles. The increase in the Pb concentration is accompanied by a decrease in 206Pb/207Pb ratios, also attributed to natural Pb isotope fractionation. Four soil profiles from industrial areas show variable enrichments in Pb concentrations and these are attributed to anthropogenic input from air-borne pollutants or even slag particles at smelting sites. The implication is that a lithogenic Pb source can deviate from the basement rock composition, and detailed isotope characteristics of the geological background and natural enrichments in soils are often needed to determine the lithogenic/anthropogenic proportions of Pb in soils. 相似文献
3.
The leaching behaviour of electrostatic precipitator dust from the Mufulira Cu smelter (Copperbelt, Zambia) was studied using a 48-h pH-static leaching experiment (CEN/TS 14997). The release of metals (Cd, Co, Cu, Ni, Pb and Zn) and changes in mineralogical composition using X-ray diffraction and PHREEQC-2 modelling were investigated in the pH range of 3–7. The highest concentrations of metals were released at pH 3–4.5, which encompasses the natural pH of the dust suspension (～4.3). About 40% of the total Cu was leached at pH 3, yielding 107 g/kg. Chalcanthite (CuSO4·5H2O), magnetite (Fe3O4) and delafossite (CuFeO2) represented the principal phases of the studied dust. In contact with water, chalcanthite was dissolved and hydrated Cu sulphates precipitated at pH 4–7. Gypsum (CaSO4·2H2O) and secondary Fe or Al phases were observed in the leached residues. Serious environmental impact due to leaching may occur in dust-contaminated soil systems in the vicinity of the smelting plants. 相似文献
4.
The north-south asymmetry of the Fe XIV 530.3 nm coronal emission line (the green corona) over cycle 22 was investigated. The green corona line brightness was dominant in the southern hemisphere during cycle 22 (A = –0.07), except for short periods of the ascending phase of the activity cycle. The asymmetry of the semi-annual mean over the period 1940 – 1996 was also studied. The asymmetry, during these years, reached its maximum in 1962 – 1966, and then decreased. Important periodicities of the asymmetry in cycle 22, e.g., 158 and 350 days, 2.39 years were found. Similar periodicities were also detected in the years 1940 – 1996. An FFT analysis was used to detect these periodicities. 相似文献
5.
Ccile Quantin Vojt ch Ettler Jrmie Garnier Ond&#x;ej &#x;ebek 《Comptes Rendus Geoscience》2008,340(12):872-882
Soil profiles developed on serpentinites from several localities in the Czech Republic were investigated by a combination of geochemical and mineralogical methods (selective extractions, XRD, SEM/EDS) to determine the partitioning and mobility of chromium (Cr) and nickel (Ni). Whereas Cr is released from pyroxenes, amphiboles and Cr-spinels present in the bedrock, Ni is primarily mobilized from olivines and small Fe-Ni sulphide inclusions. The results of extraction methods indicated significant differences in the availability and mobility of Cr and Ni in soils. Chromium is almost not phytoavailable, as indicated by the DTPA extractions. The selective extractions showed that Cr is tightly bound to well-crystallised Fe-oxides and primary rock-derived phases. In contrast, Ni is substantially more mobile in soil, being mainly controlled by Mn-oxides and amorphous/less crystallised Fe-oxides. The DTPA extraction indicated that up to 10% of total Ni might be phytoavailable. 相似文献
6.
A coronal index (CI) derived from the limb observations of the 530.3 nm emission corona (green corona) over 1964–1987 was analyzed by the Fourier transform technique (FTT) to find periodicity in this layer of solar atmosphere. As expected, two pronounced periods were indicated: the rotational, about 27 d, and the activity cycle length, 11 years. Beside these there are seen other periodicities of less significancies, namely of about 5,2.2,1 and 0.5 year. The values of these periodicities in individual cycles 20 and 21 slightly differs that could be related to different activity zone depths beneath the photosphere. 相似文献
7.
Three types of smelting slags originating from historically different smelting technologies in the Tsumeb area (Namibia) were studied: (i) slags from processing of carbonate/oxide ore in a Cu–Pb smelter (1907–1948), (ii) slags from Cu and Pb smelting of sulphide ores (1963–1970) and (iii) granulated Cu smelting slags (1980–2000). Bulk chemical analyses of slags were combined with detailed mineralogical investigation using X-ray diffraction analysis (XRD), scanning electron microscopy (SEM/EDS) and electron microprobe (EPMA). The slags are significantly enriched in metals and metalloids: Pb (0.97–18.4 wt.%), Cu (0.49–12.2 wt.%), Zn (2.82–12.09 wt.%), Cd (12–6940 mg/kg), As (930–75,870 mg/kg) and Sb (67–2175 mg/kg). Slags from the oldest technology are composed of primary Ca- and Pb-bearing feldspars, spinels, complex Cu–Fe and Cu–Cr oxides, delafossite–mcconnellite phases and Ca–Pb arsenates. The presence of arsenates indicates that these slags underwent long-term alteration. More recent slags are composed of high-temperature phases: Ca–Fe alumosilicates (olivine, melilite), Pb- and Zn-rich glass, spinel oxides and small sulphide/metallic inclusions embedded in glass. XRD and SEM/EDS were used to study secondary alteration products developed on the surface of slags exposed for decades to weathering on the dumps. Highly soluble complex Cu–Pb–(Ca) arsenates (bayldonite, lammerite, olivenite, lavendulan) associated with litharge and hydrocerussite were detected. To determine the mineralogical and geochemical parameters governing the release of inorganic contaminants from slags, two standardized short-term batch leaching tests (European norm EN 12457 and USEPA TCLP), coupled with speciation-solubility modelling using PHREEQC-2 were performed. Arsenic in the leachate exceeded the EU regulatory limit for hazardous waste materials (2.5 mg/L). The toxicity limits defined by USEPA for the TCLP test were exceeded for Cd, Pb and As. The PHREEQC-2 calculation predicted that complex arsenates are the most important solubility controls for metals and metalloids. Furthermore, these phases can readily dissolve during the rainy season (October to March) and flush significant amounts of As, Pb and Cu into the environment in the vicinity of slag dumps. 相似文献
8.
Jay M. Pasachoff Shelby B. Kimmel Miloslav Druckmüller Vojtech Rušin Metod Saniga 《Solar physics》2006,238(2):261-270
The hybrid solar eclipse of April 8, 2005, provided a good opportunity to observe the white-light solar corona, even though
the eclipse lasted just 30 seconds and could be seen only from ships in the Pacific Ocean. During the eclipse, we detected
a unique ‘cloud’ of particles in the white-light corona above the west limb ≈260°–270°. We compare this feature with EUV images
from SOHO. The feature’s density and temperature seem comparable to a coronal condensation, and, like a coronal condensation,
it is connected to the emergence of material from the solar surface without a flare. However, the morphology of the feature
shows clear differences from a classical coronal condensation. 相似文献
9.
Analyzing daily values of the total solar irradiance (TSI), the coronal index of solar activity (CI), and the Mg II 280-nm
core-to-wing ratio (Mg II index), we have found that the temporal variations of these indices are very similar to each other
during the period from 1978 to 2005. The correlation between CI and TSI, with the PSI correction lying within the interval
under study, has been found to be 0.699, which is very close to the value of 0.703 of the correlation between Mg II and TSI
for 27-day averages (the CI – Mg correlation is 0.824). The regression equation between CI and TSI is almost linear, except
for TSI depletions when a large number of sunspots are present on the visible disk. By employing CI, an extrapolation of TSI
back to 1947 is presented. 相似文献
10.
Ladislav Strnad Vojtech Ettler Martin Mihaljevic Jindrich Hladil Vladislav Chrastny 《Geostandards and Geoanalytical Research》2009,33(3):347-355
We report new data on the trace element concentrations of Mg, Cr, Mn, Co, Ni, Cu, Zn, Sr, Cd, Ba, La, Ce, Nd, Pb and U in USGS carbonate reference materials (MACS-1 and MACS-2) and compare solution ICP-MS and LA-ICP-MS trace element determinations on landfill calcites using calibration to different reference materials (MACS-1 and MACS-2 carbonate and NIST SRM 612 glass). Very good agreement (differences below 10% relative) was found between laser ablation and solution ICP-MS data for MACS-1 with higher concentrations of trace elements (values between 100 and 150 μg g−1 ), with the exception of Cu and Zn. Similarly good agreement was found for MACS-2 with lower trace element concentrations (units to tens of μg g−1 ), with the exception of Cr, Co and Zn. The MACS-1 reference material for calibration of LA-ICP-MS was found to be extremely useful for in situ determination of trace elements in real-world carbonate samples (landfill calcites), especially those present in calcite in higher concentrations (Mn, Sr, Ba; < 5% RSD). Less accurate determinations were generally obtained for trace elements present at low concentrations (∼ units of μg g−1 ). In addition, good agreement was observed between the instrument calibration to MACS and NIST SRM 612 glass for in situ measurements of trace elements in landfill calcites K-2, K-3 and K-4 (differences below 15% relative for most elements). Thus, the application of MACS carbonate reference materials is promising and points to the need for the development of new carbonate reference materials for laser ablation ICP-MS. 相似文献