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K. S. Voudouris N. J. Lambrakis G. Papatheothorou P. Daskalaki 《Mathematical Geology》1997,29(1):43-59
R- andQ-mode factor analysis is applied to 51 groundwater samples collected from wells drilled in the Plio-Pleistocene aquifers of
NW Achaia, Greece. The purpose ofR- andQ-mode factor analysis application is to identify (i) the regional groundwater flow pattern, and (ii) the deterioration of
groundwater quality. Sixteen hydrogeological parameters are used in order to examine their importance and to provide significant
insight into their correlations. In theR-mode factor analysis, a six-factor model is suggested which can explain more than 77.5% of the total variance. The contribution
of each factor at every site (factor scores) also is computed. Maps are constructed showing the geographical distribution
of the factor scores. From these maps, the high salinity areas are delineated (seawater intrusion, possible appearance of
halite layers) and the areas with elevated contribution of karastic-water are defined. Using theQ-mode correspondence analysis the meaning of the electrical conductivity as the most important variable in groundwater quality
characterization is demonstrated. 相似文献
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LI Hongzhong HE Junguo LIANG Jin YANG Fei ZHAI Mingguo ZHANG Lianchang Voudouris PANAGIOTIS 《《地质学报》英文版》2019,93(6):1738-1754
Precambrian banded iron formation(BIF) is one of the most important mineral resources in China, mostly abundant in the North China Craton(NCC) with relatively less common in South China. Since the BIF and siliceous rocks both originated from chemical deposition, the syngenetic BIF and Siliceous rocks can help evaluate their environment of formation. We examine here the mineralogy and geochemistry of siliceous rocks associated with the Tieshanmiao Formation BIF, aiming to decipher the conditions of formation of both BIF and Siliceous rocks in the Wuyang area in the NCC. Analysis of the geochemical characteristics of whole rock shows that the Si O2 content of the siliceous rock ranges from 90.11% to 94.85% and is relatively high overall. Trace element contents of Ba and U are also high, the Ba/Sr ratio ranges from 3.89 to 25.28 and the U/Th ratio ranges from 0.09 to 0.20. Finally, the ΣREE value of rare earth elements ranges from 57.03 ppm to 152.59 ppm, and these indexes all indicate that siliceous rock resulted from hydrothermal deposition. Plots of Al2 O3-Si O2, Si O2/(K2 O+Na2 O)-Mn O2/Ti O2 and Mn-10×(Cu+Co+Ni)-Fe in discrimination diagrams also verify this interpretation. However, both the Mg O content, ranging from 0.16 to 0.32, and the Fe/Ti ratio, ranging from 2.50 to 9.72, suggest that terrigenous material was added during the depositional process. Major and trace element parameters of siliceous rock, such as the Al/(A1+Fe+Mn) ratio(from 0.81 to 0.93), Mn O/Ti O2(from 0.00 to 0.17), Al/(Al+Fe)(from 0.82 to 0.93), Sc/Th ratio(from 0.21 to 0.50), U/Th(from 0.09 to 0.20),(La/Yb)N(from 0.83 to 3.04), and the(La/Ce)N(from 0.01 to 0.02) all imply that the siliceous rock formed in a continental margin. In addition, the Sr/Ba ratio from 0.08 to 0.26, the δCe value from 0.31 to 0.90, and the δEu value from 0.14 to 0.58, all indicate that the siliceous rock was formed at a relatively deeper water depth and under weak hydrodynamic conditions. Siliceous rock and BIF formed in the same geological setting, with the Si O2/(K2 O+Na2 O) ratio of siliceous rock ranging from 28.61 to 47.43, the Si O2/Al2 O3 ratio from 16.53 to 32.37, and the Si O2/Mg O ratio from 287.28 to 592.81, which are all in agreement with chemical deposition associated with volcanic eruptions. The Al2 O3/Ti O2 ratio from 37.82 to 50.30 indicates that the magma source of siliceous rock was of slightly intermediate composition. During the Late Archean in the Wuyang area, the high concentration and high purity Si O2 quickly precipitated from hydrothermal fluids to finally result in the accumulation of siliceous rock in a marginal sea, while the input corresponding to iron formation components was deposited to form iron formation layers, and limestone was only the product formed during the deposition intervals of siliceous rock and iron formations. In this study, the synsedimentary siliceous rocks of BIF act as a new way to provide direct evidence to understand the formation environment of BIF due to its high geochemical stability. 相似文献
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A. Katerinopoulou A. Katerinopoulos P. Voudouris A. Bieniok M. Musso G. Amthauer 《Mineralogy and Petrology》2009,95(1-2):113-124
Unusual Ti–Cr–Zr-rich garnet crystals from high-temperature melilitic skarn of the Maronia area, western Thrace, Greece, were investigated by electron-microprobe analysis, powder and single-crystal X-ray diffraction, IR, Raman and Mössbauer spectroscopy. Chemical data showed that the garnets contain up to 8 wt.% TiO2, 8 wt.% Cr2O3 and 4 wt.% ZrO2, representing a solid solution of andradite (Ca3Fe3+ 2Si3O12 ≈46 mol%), uvarovite (Ca3Cr2Si3O12 ≈23 mol%), grossular (Ca3Al2Si3O12 ≈10 mol%), schorlomite (Ca3Ti2[Si,(Fe3+,Al3+)2]O12 ≈15 mol%), and kimzeyite (Ca3Zr2[Si,Al2]3O12 ≈6 mol%). The Mössbauer analysis showed that the total Fe is ferric, preferentially located at the octahedral site and to a smaller extent at the tetrahedral site. Single-crystal XRD analysis, Raman and IR spectroscopy verified substitution of Si mainly by Al3+, Fe3+ and Ti4+. Cr3+ and Zr4+ are found at the octahedral site along with Fe3+, Al3+ and Ti4+. The measured H2O content is 0.20 wt.%. The analytical data suggest that the structural formula of the Maronia garnet can be given as: (Ca2.99Mg0.03)Σ=3.02(Fe3+ 0.67Cr0.54Al0.33Ti0.29Zr0.15)Σ=1.98(Si2.42Ti0.24Fe0.18Al0.14)Σ=2.98O12OH0.11. Ti-rich garnets are not common and their crystal chemistry is still under investigation. The present work presents new evidence that will enable the elucidation of the structural chemistry of Ti- and Cr-rich garnets. 相似文献
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Hydrogeological framework and estimation of aquifer hydraulic parameters using geoelectrical data: a case study from West Iran 总被引：1，自引：0，他引：1
Abduulah Taheri Tizro Kostantanous S. Voudouris Mortaza Salehzade Hassan Mashayekhi 《Hydrogeology Journal》2010,18(4):917-929
Detailed local geological, geophysical, and hydrogeological investigations were carried out for the alluvial aquifer in the Kangavar basin, West Iran to delineate the architecture of different subsurface geological horizons using lithologs and generated vertical electrical sounding (VES) data. An attempt has also been made to estimate aquifer transmissivity from resistivity data. Forty VESs were recorded with the Schlumberger electrode configuration in the study area; 28 of these were selected for evaluation. The maximum current electrode spacing was 400–500 m. The data obtained were interpreted by computer iterative modeling with curve matching for calibration purposes. In order to ascertain the subsurface geological framework, the general distribution of resistivity responses of the geological formations was obtained and geoelectrical sections along a number of lines were prepared. Probable aquifer horizons from these sections were identified. The transmissivity of the unconfined aquifer was computed by determining the Dar-Zarrouk parameters (longitudinal unit conductance and transverse unit resistance) and were compared with the actual field transmissivity. The results showed a direct relation between aquifer transmissivity and modified transverse resistance. 相似文献
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The application of multivariate statistical analyses of hydrochemical data has proved to bemost successful in the assessment of groundwater hydrochemistry, especially in situationswhere numerous samples are available. Fifteen (15) hydrochemical parameters were considered(pH, E.C., T.D.S., T.H, Ca, Mg, Na, K, HCO3, Cl, SO4, NO3, NO2, NH4, PO4) in 131 samplescollected from the alluvial aquifer of NE Korinthia, during May 1997. Simple and multipleregression, factor, and trend-surface analyses were applied in order to examine the importance ofeach parameter, investigate correlations among them, and separate them into groups. Statisticalfactors were selected and their geographical distribution was mapped. It was concluded thatuse of such methods reveal the prevailing evolutionary mechanisms of the studied system,thus enabling accurate and relatively quick hydrochemical assessments. 相似文献
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Panagiotis Christos Voudouris 《Mineralogy and Petrology》2011,101(1-2):97-113
The Mavrokoryfi Cu?CAg?CAu?CTe prospect, northeastern Greece, consists of atypical, high-sulfidation mineralization where precious metals were introduced contemporaneously with advanced argillic alteration from magmatic vapors. It occurs as veins of massive sulfides in zones of silicic and advanced argillic alteration spatially associated with an andesitic lava dome and hyaloclastites. Mineralogical data demonstrate an unusual ore and gangue mineralogy that is compatible with formation under very oxidizing conditions (logfO2 values of >?31.8) at temperatures of 200°C to 250°C. Oxidizing conditions favored the formation of hypogene lead sulfates (anglesite and barian celestite) instead of galena. Selenian acanthite, cadmian freibergite, and argentian goldfieldite are the main carriers of silver in the deposit and are reported in Greece for the first time. They were deposited at logfS2 of ?9 to ?7 and logfTe2 values of ?9 to ?12.5 (250°C). Ag-poor goldfieldite at Mavrokoryfi has up to 3.7 apfu Te and is the most Te-rich goldfieldite yet reported. The mineralization is accompanied by aluminum?Cphosphate?Csulfate minerals of magmatic-hydrothermal origin and an unusual Pb-enrichment. Ore-forming components were likely derived from andesite porphyries. 相似文献