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Quartz‐rich veins in metapelitic schists of the Sanandaj‐Sirjan belt, Hamadan region, Iran, commonly contain two Al2SiO5 polymorphs, and, more rarely, three coexisting Al2SiO5 polymorphs. In most andalusite and sillimanite schists, the types of polymorphs in veins correlate with Al2SiO5 polymorph(s) in the host rocks, although vein polymorphs are texturally and compositionally distinct from those in adjacent host rocks; e.g. vein andalusite is enriched in Fe2O3 relative to host rock andalusite. Low‐grade rocks contain andalusite + quartz veins, medium‐grade rocks contain andalusite + sillimanite + quartz ± plagioclase veins, and high‐grade rocks contain sillimanite + quartz + plagioclase veins/leucosomes. Although most andalusite and sillimanite‐bearing veins occur in host rocks that also contain Al2SiO5, kyanite‐quartz veins crosscut rocks that lack Al2SiO5 (e.g. staurolite schist, granite). A quartz vein containing andalusite + kyanite + sillimanite + staurolite + muscovite occurs in andalusite–sillimanite host rocks. Textural relationships in this vein indicate the crystallization sequence andalusite to kyanite to sillimanite. This crystallization sequence conflicts with the observation that kyanite‐quartz veins post‐date andalusite–sillimanite veins and at least one intrusive phase of a granite that produced a low‐pressure–high‐temperature contact aureole; these relationships imply a sequence of andalusite to sillimanite to kyanite. Varying crystallization sequences for rocks in a largely coherent metamorphic belt can be explained by P–T paths of different rocks passing near (slightly above, slightly below) the Al2SiO5 triple point, and by overprinting of multiple metamorphic events in a terrane that evolved from a continental arc to a collisional orogen.  相似文献   
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Mafic high-pressure granulite, eclogite and pyroxenite xenoliths have been collected from a Mesozoic volcaniclastic diatreme in Xinyang, near south margin of the Sino-Korean Craton (SKC). The high-pressure granulite xenoliths are mainly composed of fine-grained granoblasts of Grt+Cpx+Pl+Hbl±Kfs±Q±Ilm with relict porphyritic mineral assemblage of Grt+Cpx±Pl±Rt. PT estimation indicates that the granoblastic assemblage crystallized at 765–890 °C and 1.25–1.59 GPa, corresponding to crustal depths of ca. 41–52 km with a geotherm of 75–80 mW/m2. Calculated seismic velocities (Vp) of high-pressure granulites range from 7.04 to 7.56 km/s and densities (D) from 3.05 to 3.30 g/cm3. These high-pressure granulite xenoliths have different petrographic and geochemical features from the Archean mafic granulites. Elevated geotherm and petrographic evidence imply that the lithosphere of this craton was thermally disturbed in the Mesozoic prior to eruption of the host diatreme. These samples have sub-alkaline basaltic compositions, equivalent to olivine– and quartz–tholeiite. REE patterns are flat to variably LREE-enriched (LaN/YbN=0.98–9.47) without Eu anomaly (Eu/Eu*=0.95–1.11). They possess 48–127 ppm Ni and 2–20 ppm Nb with Nb/U and La/Nb ratios of 13–54 and 0.93–4.75, respectively, suggesting that these high-pressure granulites may be products of mantle-derived magma underplated and contaminated at the base of the lower crust. This study also implies that up to 10 km Mesozoic lowermost crust was delaminated prior to eruption of the Cenozoic basalts on the craton.  相似文献   
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Albite gneisses containing up to 8.7 percent Na2O and as little as 0.1% K2O comprise a significant part of the Proterozoic Lyon Mountain Gneiss in the Ausable Forks Quadrangle of the northeastern Adirondacks, New York State. Two distinct types of albite gneisses are present. One is a trondhjemitic leucogneiss (LAG) consisting principally of albite (Ab95–Ab98) and quartz with minor magnetite and, locally, minor amounts of amphibole or acmiterich pyroxene. LAG probably originated by metamorphism of a rhyolitie or rhyodacitic ash-flow tuff with A-type geochemical affinities, following post-depositional analcitization in a saline or saline-alkaline environment. The other type is a mafic albite gneiss (MAG) containing albite and pyroxene along with 0–45 percent quartz, minor amphibole, and titanite. MAG locally displays pinstripe banding and contains albite (Ab98) megacrysts up to 5 cm across. Its precursor may have been a sediment composed of diagenetic analcite or albite, dolomite, and quartz. Both types of albite gneiss are interlayered with granitic gneisses (LMG) of variable composition derived from less altered tuffs. A potassium-rich (up to 9.7% K2O) microcline gneiss facies may have had a protolith rich in diagenetic K feldspar. We propose that the albite gneisses and associated granitic gneisses are the granulite-facies metamorphic equivalent of a bimodal, dominantly felsic, volcanic suite with minor intercalated sediments, probably including evaporites. The volcanics were erupted in an anorogenic setting, such as an incipient or failed intracontinental rift. Deposition took place in a closed-basin, playa lake environment, where diagenetic alteration resulted in redistribution of the alkalis and strong oxidation.  相似文献   
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The distribution of ammonium citrate-leachable lead, zinc and cadmium among size fractions in stream sediments is strongly influenced by the presence of hydrous Mn-Fe oxides in the form of coatings on sediment grains. Distribution curves showing leachable metals as a function of particle size are given for eight samples from streams in New York State. These show certain features in common; in particular two concentrations of metals, one in the finest fractions, and a second peak in the coarse sand and gravel fraction. The latter can be explained as a result of the increasing prevalence and thickness of oxide coatings with increasing particle size, with the oxides serving as collectors for the heavy metals. The distribution of Zn and Cd in most of the samples closely parallels that of Mn; the distribution of Pb is less regular and appears to be related to Fe in some samples and Mn in others. The concentration of metals in the coarse fractions due to oxide coatings, combined with the common occurrence of oxide deposition in streams of glaciated regions, raises the possibility of using coarse materials for geochemical surveys and environmental heavy-metal studies.  相似文献   
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Olivine metagabbros from the Adirondacks usually contain both clear and spinel-clouded plagioclase, as well as garnet. The latter occurs primarily as the outer rim of coronas surrounding olivine and pyroxene, and less commonly as lamellae or isolated grains within plagioclase. The formation of garnet and metamorphic spinel is dependent upon the anorthite content of the plagioclase. Plagioclase more sodic than An38±2 does not exhibit spinel clouding, and garnet rarely occurs in contact with plagioclase more albitic than An36±4. As a result of these compositional controls, the distribution of spinel and garnet mimics and visually enhances original igneous zoning in plagioclase. Most features of the arrangement of clear (unclouded) plagioclase, including the shells or moats of clear plagioclase which frequently occur inside the garnet rims of coronas, can be explained on the basis of igneous zoning. The form and distribution of the clear zones may also be affected by the metamorphic reactions which have produced the coronas, and by redistribution of plagioclase in response to local volume changes during metamorphism.Authors listed alphabeticallyPublished by permission of the Director, New York State Museum, Journal Series Number 299  相似文献   
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A geothermometric technique based on equilibria between coexisting plagioclase and alkali feldspar was applied to quartzo-feldspathic granulites from Salvador, BA, Brazil. The conditions of metamorphism were determined to be in the range 750 ° C–800 ° C, 4–8 Kb, by comparison with experimental data on the stabilities of sapphirine, phlogopite and other minerals occurring in the associated rocks. Selected feldspar data gives temperatures near, but slightly below, this range. Several variants of the Wood and Banno model, as well as an empirical two-pyroxene geothermometer, were also tested and found to give temperatures which were apparently 50 °–100 ° high. The solubility of Al2O3 in orthopyroxene indicates temperatures which are about 200 ° to high, suggesting that Fe in the natural assemblages significantly changes relationships observed experimentally in MgO-Al2O3-SiO2 systems.  相似文献   
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