Defect properties of albite     

Stephan Lowitzer  Dan J. Wilson  Björn Winkler  Victor Milman  Julian D. Gale 《Physics and Chemistry of Minerals》2008,35(3):129-135

Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi₃O₈), as well as the Schottky defect energy for the removal of a Na₂O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.  相似文献   

Analysis of COMPTEL gamma-ray burst locations and spectra     

R. M. Kippen  J. Ryan  A. Connors  M. McConnell  C. Winkler  L. O. Hanlon  V. Schönfelder  J. Greiner  M. Varendorff  W. Collmar  W. Hermsen  L. Kuiper 《Astrophysics and Space Science》1995,231(1-2):231-234

In its first three years of operation, the COMPTEL instrument on theCompton Gamma-Ray Observatory has measured the locations (mean accuracy 1°) and spectra (0.75-30 MeV) of 18 gamma-ray bursts and continues to observe new events at a rate of 1/month. With good angular resolution and sensitivity at MeV energies, the growing COMPTEL burst catalog is an important new piece of evidence in the on-going GRB mystery. The COMPTEL burst locations are consistent with an isotropic distribution of sources, yet the spatial coincidence of two of the bursts indicates the possibility of repetition. The COMPTEL burst spectra are in most cases consistent with a single power law model with spectral index in the range 2–3. However, two bursts show evidence of a spectral break in the MeV range. Measurement of rapid variability at MeV energies in the stronger bursts provides evidence that either the sources are nearby (within the Galaxy) or the gamma-ray emission is relativistically beamed. We present an overview of analysis results obtained from the COMPTEL burst catalog concentrating on the search for burst repetition and the implications of highly variable MeV emission.  相似文献   

Microfossils in the ‘Complexe de base’ of the Prealpine Helminthoid Flysch (Dranse nappe,Switzerland). - Preliminary results     

A. Slaczka  M. A. Gasinski  W. Winkler 《International Journal of Earth Sciences》1992,81(2):579-580

The Swiss Prealpine Dranse nappe consists of the badly known shaley Complexe de base series and the overlying Campanian to Maastrichtian Helminthoid Flysch. Our preliminary data from the shaley series indicate an Albian to Early Campanian age. It represents mid-slope to abyssal plain starved basin sediments. The occurrence of similar and coeval series in the Carpathians and Ligurian Alps suggest common tectonic and oceanographic conditions.  相似文献   

Monte Carlo simulation of mixing in Ca3Fe2Ge3O12–Ca4Ge4O12 garnets and implications for the thermodynamic stability of pyrope–majorite solid solution     

Victor L. Vinograd  Bjoern Winkler  Daniel J. Wilson  Andrew Putnis  Julian D. Gale 《Physics and Chemistry of Minerals》2006,33(8-9):533-544

Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca₃Fe₂Ge₃O₁₂ and Ca₄Ge₄O₁₂. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca²⁺ and Ge⁴⁺ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite.  相似文献   

Statistical analysis for the hydrogeological evaluation of the fracture networks in hard rocks     

J. Hofrichter  G. Winkler 《Environmental Geology》2006,49(6):821-827

The hydrogeological effectiveness of fracture sets is determined and evaluated by the fuzzy c-mean and hierarchical clustering. These cluster analyses combine the geological spatial attributes and the hydraulic relevant attributes of fractures. Based on the results of the clustering the fracture set volumes are estimated.  相似文献   

Reviews on books, internet, and scientific media     

Andreas Winkler  Fakhry A. Assaad 《Environmental Geology》2006,51(1):167-169

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Detrital thermochronology – a new perspective on hinterland tectonics, an example from the Andean Amazon Basin, Ecuador     

G. M. H. Ruiz  D. Seward  W. Winkler 《Basin Research》2004,16(3):413-430

In order to understand the significance of detrital grain ages in sedimentary basins, a new approach is presented. Five characteristic paths, identified by the change in age of detrital grain populations combined with the change in lagtime over time, can be related to different geodynamic settings in the source regions. When lagtime and grain age increase over time, a change in source must be invoked – this is usually a direct response to a geological event. A constant cooling age, a vertical path, associated implicitly with increasing lagtime, implies erosion of materials that had passed through the closure temperature rapidly – exhuming sufficient rock to supply detritus over the time of the path. Constant lagtimes, regardless of the lagtime itself, are indicative of thermochronological stability in the source region. This can involve fast or slow cooling. Finally, decreasing lagtimes support the notion of increasing cooling rates in the source regions over time. A test study is presented from sediments of the northern Ecuadorian Sub‐Andean Zone where geological events had previously been identified using alternative methods. The addition of heavy‐mineral studies increased the precision in the interpretation. At 90 Ma, rapidly decreasing lagtimes point to a phase of tectonic activity. From about 85 Ma until about 60 Ma the lagtimes were approximately zero. This represents a phase of rapid exhumation of the source regions correlating with the previously identified Pallatanga event. An associated increase of metamorphic minerals occurs over this time span, pointing to increased erosion from deeper horizons. At about 70 Ma, the oldest source region, the shield to the east, was switched off. This timing correlates with a change from marine to continental conditions in the basin, a change in palaeocurrent directions from the east to the west, as well as an associated influx of material from the growing Cordillera Real. At about 55 Ma, a change in source is identified by a change in slope of the lagtime curve together with a change in heavy minerals. From 50 to 35 Ma a renewed period of tectonism in the source region is correlated with the docking of the Macuchi terrane which clearly had an effect of increased erosion in the Cordillera Real bringing in higher grade metamorphic minerals. From about 32 Ma onwards the lagtime has been somewhat constant at about 30 Myr. This does not imply, however, a steady‐state environment as it is well known from other geological evidence that there have been other events within this time frame. One must be cautious about over‐interpreting the lagtime as a method to determine steady state in any region. It is a matter of scale.  相似文献   

Richtlinien zur stratigraphischen Nomenklatur     

Jürgen Remane&#;  Thierry Adatte  Jean-Pierre Berger  Reto Burkhalter  Stephan Dall&#;Agnolo  Danielle Decrouez  Hermann Fischer  Hanspeter Funk  Heinz Furrer  Hans-Rudolf Graf  Yves Gouffon  Werner Heckendorn  Wilfried Winkler 《Eclogae Geologicae Helvetiae》2005,98(3):385-405

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Hiscock KM,Bense VF (eds) | Hydrogeology—principles and practice, 2nd edition     

Andreas Winkler 《Environmental Earth Sciences》2016,75(4):305

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Evaluating igneous sources of the Taveyannaz formation in the Central Alps by detrital zircon U–Pb age dating and geochemistry     

Gang Lu  Wilfried Winkler  Meinert Rahn  Albrecht von Quadt  Sean D. Willett 《Swiss Journal of Geoscience》2018,111(3):399-416

Late Palaeogene syn-tectonic volcanic products have been found in the Northern Alpine foreland basin and in the South Alpine hemipelagic basin. The source of abundant volcanic fragments is still in debate. We analyzed the geochronology and geochemistry of detrital zircons, and evaluated their temporal and genetic relationships with potential volcanic sources. The study shows that the detrital zircon U–Pb age patterns have two major age groups: a dominance (ca. 90%) of pre-Alpine zircons was found, as commonly observed in other Alpine flysch formations. These zircons apparently derived from erosion of the early Alpine nappe stack in South Alpine and Austroalpine units. Furthermore, a few Neo-Alpine zircons (ca. 10%) have ages ranging from Late Eocene to Early Oligocene (~ 41–29 Ma). Both source materials were mixed during long riverine transport to the basin margins before being re-deposited by gravity flows. These Palaeogene ages match with the activity of Peri-Adriatic magmatism, including the Biella volcanic suite as well as the Northern Adamello and Bergell intrusions. The values of REE and ¹⁷⁶Hf/¹⁷⁷Hf_(t) ratios of the Alpine detrital zircons are in line with the magmatic signatures. We observe an in time and space variable supply of syn-sedimentary zircons. From late Middle Eocene to Late Eocene, basin influx into the South Alpine and Glarus (A) basins from the Northern Adamello source is documented. At about 34 Ma, a complete reorganisation is recorded by (1) input of Bergell sources into the later Glarus (B) basin, and (2) the coeval volcaniclastic supply of the Haute-Savoie basin from the Biella magmatic system. The Adamello source vanished in the foreland basin. The marked modification of the basin sources at ~ 34 Ma is interpreted to be initiated by a northwestern shift of the early Alpine drainage divide into the position of the modern Insubric Line.  相似文献