Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

长江上游洪涝暴雨环流形势中期演变趋势分析     

郁淑华  骆红  芮良生 《成都信息工程学院学报》1990,(1)

本文通过对1980年以来长江上游10次洪涝过程的500hpa环流形势分析,并用车比雪夫多项式对500hpa高度场进行展开,研究了各类洪涝过程的中期演变特征,发现代表不同洪涝过程环流形势变化的不同的车氏系数值都有明显的特征变化,结合欧洲中心中期数值预告96小时500hpa高度场的车氏系数分析,可为洪涝暴雨的中期预报提供一种新的思路。  相似文献   

A critical state model for sands dependent on stress and density     

Y.P. Yao  D.A. Sun  T. Luo 《国际地质力学数值与分析法杂志》2004,28(4):323-337

An elastoplastic model for sands is presented in this paper, which can describe stress–strain behaviour dependent on mean effective stress level and void ratio. The main features of the proposed model are: (a) a new state parameter, which is dependent on the initial void ratio and initial mean stress, is proposed and applied to the yield function in order to predict the plastic deformation for very loose sands; and (b) another new state parameter, which is used to determine the peak strength and describe the critical state behaviour of sands during shearing, is proposed in order to predict simply negative/positive dilatancy and the hardening/softening behaviour of medium or dense sands. In addition, the proposed model can also predict the stress–strain behaviour of sands under three-dimensional stress conditions by using a transformed stress tensor instead of ordinary stress tensor. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

行星磁场与卫星引力及其相对运动的统计关系     

罗葆荣 《天文研究与技术》1997,(3)

从知道某些天体具有磁场起，人们就对其磁场的起源提出种种解释，例如有电池说，转子说，化石说，发电机说等等。但由于这些学说都分别与某些观测事实相抵触而未被公认，因此星球磁场的起源一直是未能解决的命题。余先河先生提出，星球的磁场起源可能与所受的引力有关，行星的磁场强度正比于其所受卫星的引力；正比于卫星与行星的引力连线转动的相对角速度。本文对这两方面的命题分别进行了相关分析，得到其相关系数分别为：ｒ＝０．８４８１和ｒ＝０．８４２５，它们都在ａ＝０．０１的信度水平上相关。结果表明余新河关于行星磁场起源的设想是有基础的。本文还对其统计结果和可能机制进行了讨论。  相似文献   

The induced turbulence effect on propagation of radio emission in pulsar magnetospheres     

Qinghuan Luo  D. B. Melrose 《Monthly notices of the Royal Astronomical Society》2006,371(3):1395-1404

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海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

南海北缘北东东向构造活动性研究     

任镇寰  任奔滔  罗振暖  陈益明  钟贻军 《大地测量与地球动力学》1996,(2)

从地形地貌特征、重磁地球物理场、深部构造与断裂构造以及地震活动、震源机制等多方面论述北东东向构造是南海北缘的主要活动构造。对于长期以来认为新华夏系北东向构造是该区主要活动构造的观点来说，这是一种新的学术思想。  相似文献   

Tidal effects on temperature front in the Yellow Sea   总被引：5，自引：0，他引：5  

Ma Jian  Qiao Fangli  Xia Changshui  Yang Yongzeng 《中国海洋湖沼学报》2004,22(3):314-321

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).  相似文献   

CATASTROPHIC ECO-ENVIRONMENTAL CHANGE IN THE SONGNEN PLAIN, NORTHEASTERN CHINA SINCE 1900S   总被引：1，自引：1，他引：0  

WANGHai-xia WANZhong-juan YUShao-peng LUOXin-zheng SUNGuang-you 《中国地理科学(英文版)》2004,14(2):179-185

Although the Songnen Plain in the northeastern China was developed relatively late in the temperate zone of the world, its eco-environment has changed greatly. This paper analyzes the changes of land cover and the rates and trends ofdesertification during the past 100 years in the Songnen Plain. According to the macroscopic analysis, we find that the eco-environment in the plain has reached to the threshold of catastrophic change since the 1950s. The Thorn Needle Catastrophic Model was used to determine and validate this conclusion. Human activities, including large-scale construction projects, such as huge dams and dikes, and excessive grazing were the primary factors contributing to regional eco-environmental catastrophe. And irrational reclamation of the wilderness also affected the eco-environmental change. The results reveal the complex human-land interactions.  相似文献   

河西走廊东部地区早二叠世地层研究的新认识     

罗桂昌  汪明洲 《地球科学与环境学报》1992,(2)

本文讨论了河西走廊东部地区早二叠世地层研究的有关问题,认为甘肃山丹青羊泉下二叠统剖面是北祁连山—河西走廊地区的重要代表剖面之一。以该剖面研究为依据,提出走廊东部地区下二叠统的进一步划分方案,分析该区早二叠世地层岩性特征差异的原因,并与走廊西部地区同期地层进行对比,进一步明确了大黄沟组的含意。  相似文献