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Höhn Stefan Koglin Nikola Klopf Lisa Schüssler Ulrich Tragelehn Harald Frimmel Hartwig E. Zeh Armin Brätz Helene 《International Journal of Earth Sciences》2018,107(1):359-377
International Journal of Earth Sciences - Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were... 相似文献
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Combined U–Pb and Lu–Hf isotope analyses of detrital zircon grains from the auriferous Eldorado Reef conglomerate, upper Central Rand Group, reveal new insights into the provenance of the sediments and thus, by implication, possibly also into that of the gold. Most of the detrital zircon grains, which are of magmatic origin, yielded Mesoarchaean ages clustering around 2.94 and 3.06 Ga. A subordinate zircon population gave ages with maxima at 3.28 and 3.44 Ga. The Mesoarchaean zircon grains mostly show super-chondritic ?Hft of up to +5.2, whereas the Palaeoarchaean zircon grains have nearly chondritic composition with ?Hft between −1.3 and +2.0. The new dataset of the Mesoarchaean zircon populations provides the first unambiguous evidence of the formation of juvenile crust not only at 3.06 but also at 2.94 Ga. As the analysed zircon grains are from the ruditic fraction, they must be derived from a comparatively proximal source in close vicinity to the Central Rand Basin. Based on currently available data, this source was most likely a magmatic arc that existed at the northern edge of the Witwatersrand Block at 3.06 Ga. An additional source might be the 2.94 Ga magmatic rocks of the Kraaipan Greenstone Belt that occurs to the west of the Witwatersrand Block. The minor fraction of Palaeoarchaean zircon grains in the Eldorado Reef perhaps stem from sources that are isotopically similar to the Barberton Greenstone Belt and the Limpopo Belt but were more proximal to the Central Rand Basin. 相似文献
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A. Zeh 《Journal of Metamorphic Geology》2001,19(4):329-350
Generally, P–T pseudosections for reduced compositional systems, such as K2O–FeO–MgO–Al2O3–SiO2–H2O, Na2O–K2O–FeO–MgO–Al2O3–SiO2–H2O and MnO–K2O–FeO–MgO–Al2O3–SiO2–H2O, are well suited for inferring detailed P–T paths, comparing mineral assemblages observed in natural rocks with those calculated. Examples are provided by P–T paths inferred for four metapelitic samples from a 1 m2 wide outcrop of the Herbert Mountains in the Shackleton Range, Antarctica. The method works well if the bulk composition used is reconstituted from average mineral modes and mineral compositions (AMC) or when X‐ray fluorescence (XRF) data are corrected for Al2O3 and FeO. A plagioclase correction is suitable for Al2O3. Correction for FeO is dependent on additional microscopic observations, e.g. the kind and amount of opaque minerals. In some cases, all iron can be treated as FeOtot, whereas in others a magnetite or hematite correction yields much better results. Comparison between calculated and observed mineral modes and mineral compositions shows that the AMC bulk composition is best suited to the interpretation of rock textures using P–T pseudosections, whereas corrected XRF data yield good results only when the investigated sample has few opaque minerals. The results indicate that metapelitic rocks from the Herbert Mountains of the Northern Shackleton Range underwent a prograde P–T evolution from about 600 °C/5.5 kbar to 660 °C/7 kbar, followed by nearly adiabatic cooling to about 600 °C at 4.5 kbar. 相似文献
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Oscar?LaurentEmail author Armin?Zeh Axel?Gerdes Arnaud?Villaros Katarzyna?Gros Ewa?S?aby 《Contributions to Mineralogy and Petrology》2017,172(9):80
In plutonic systems, magma mixing is often modelled by mass balance based on whole-rock geochemistry. However, magma mixing is a chaotic process and chemical equilibration is controlled by non-linear diffusive–advective processes unresolved by the study of bulk samples. Here we present textural observations, LA-(MC-)ICP-MS trace element and Sr–Nd isotopic data of accessory apatites and titanites from a hybrid granodiorite of the Neoarchean Matok pluton (South Africa), collected in a zone of conspicuous mixing between mafic and felsic magmas. Apatite grains mostly show a pronounced zoning in CL images, corresponding to abrupt changes in REE and HFSE concentrations recording their transfer through compositionally different melt domains during mixing. These grains crystallized early, at temperatures of 950–1000 °C. Titanite grains crystallized at temperatures of 820–900 °C (Zr-in-sphene thermometry). They show limited intra-grain chemical variations but huge inter-grain compositional scatter in REE and HFSE, pinpointing crystallization within a crystal mush, from isolated melt pockets having different composition from one another owing to incomplete chemical homogenization and variable Rayleigh fractionation. These chemical–textural characteristics, in combination with partitioning models and Polytopic Vector Analysis, point to “self-mixing” between co-genetic dioritic and granodioritic/granitic magmas. Both resulted from differentiation of mantle-derived mafic melts, showing that mixing does not necessarily involve magmas from contrasted (crust vs. mantle) sources. Systematic variations in εNd t (?4.5 to ?2.5) and 87Sr/86Sr(i) (0.703–0.707) of titanite and apatite grains/domains crystallized from the two magmas point to an isotopically inhomogeneous mantle source, which is not resolved by bulk-rock isotopic data. Interaction between the two magmas must have occurred at relatively high temperatures (ca. 900°C) so that their viscosity contrast remained low, allowing efficient mechanical mixing. Despite this, chemical homogenization was incomplete, as recorded by diffusive fractionation between REE–HFSE and Sr. Modelling thereof reveals that chemical exchange between the liquid phases of the two mixed magmas did not last more than a few tens to hundreds of years. The chemical equilibration between mixed magmas thus strongly depends on the considered elements and observational length scales. 相似文献
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Cabral Alexandre Raphael Tupinambá Miguel Zeh Armin Lehmann Bernd Wiedenbeck Michael Brauns Michael Kwitko-Ribeiro Rogerio 《Mineralogy and Petrology》2017,111(6):807-819
Mineralogy and Petrology - The platiniferous gold–palladium belt of Minas Gerais, Brazil, forms an approximately 240-km-long, roughly north–south-trending domain that includes numerous... 相似文献
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Detrital zircon grains from Beit Bridge Group quartzite from the Central Zone of the Limpopo Belt near Musina yield mostly ages of 3.35-3.15 Ga, minor 3.15-2.51 Ga components, and numerous older grains grouped at approximately 3.4, 3.5 and 3.6 Ga. Two grains yielded concordant Late Hadean U-Pb ages of 3881 ± 11 Ma and 3909 ± 26 Ma, which are the oldest zircon grains so far found in Africa. The combined U-Pb and Lu-Hf datasets and field relationships provide evidence that the sedimentary protolith of the Beit Bridge Group quartzite was deposited after the emplacement of the Sand River Gneisses (3.35-3.15 Ga), but prior to the Neoarchean magmatic-metamorphic events at 2.65-2.60 Ga. The finding of abundant magmatic zircon detritus with concordant U-Pb ages of 3.35-3.15 Ga, and 176Hf/177Hf of 0.28066 ± 0.00004 indicate that the Sand River Gneiss-type rocks were a predominant source. In contrast, detrital zircon grains older than approximately 3.35 Ga were derived from the hinterland of the Limpopo Belt; either from a so far unknown crustal source in southern Africa, possibly from the Zimbabwe Craton and/or a source, which was similar but not necessarily identical to the one that supplied the Hadean zircons to Jack Hills, Western Australia. The Beit Bridge Group zircon population at >3.35 Ga shows a general εHft increase with decreasing age from εHf3.9Ga = −6.3 to εHf3.3-3.1Ga = −0.2, indicating that Hadean crust older than 4.0 Ga (TDM = 4.45-4.36 Ga) was rejuvenated during magmatic events between >3.9 and 3.1 Ga, due to a successive mixing of crustal rocks with mantle derived magmas. The existence of a depleted mantle reservoir in the Limpopo’s hinterland is reflected by the ∼3.6 Ga zircon population, which shows εHf3.6Ga between −4.6 and +3.2. In a global context, our data suggest that a long-lived, mafic Hadean protocrust with some tonalite-trondhjemite-granodiorite constituents was destroyed and partly recycled at the Hadean/Archean transition, perhaps due to the onset of modern-style plate tectonics. 相似文献
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The Bulai pluton represents a calc-alkaline magmatic complex of variable deformed charnockites, enderbites and granites, and contains xenoliths of highly deformed metamorphic country rocks. Petrological investigations show that these xenoliths underwent a high-grade metamorphic overprint at peak P–T conditions of 830–860 °C/8–9 kbar followed by a pressure–temperature decrease to 750 °C/5–6 kbar. This P–T path is inferred from the application of P–T pseudosections to six rock samples of distinct bulk composition: three metapelitic garnet–biotite–sillimanite–cordierite–plagioclase–(K-feldspar)–quartz gneisses, two charnoenderbitic garnet–orthopyroxene–biotite–K-feldspar–plagioclase–quartz gneisses and an enderbitic orthopyroxene–biotite–plagioclase–quartz gneiss. The petrological data show that the metapelitic and charnoenderbitic gneisses underwent uplift, cooling and deformation before they were intruded by the Bulai Granite. This relationship is supported by geochronological results obtained by in situ LA-ICP-MS age dating. U–Pb analyses of monazite enclosed in garnet of a charnoenderbite gneiss provide evidence for a high-grade structural-metamorphic–magmatic event at 2644 ± 8 Ma. This age is significantly older than an U–Pb zircon crystallisation age of 2612 ± 7 Ma previously obtained from the surrounding, late-tectonic Bulai Granite. The new dataset indicates that parts of the Limpopo's Central Zone were affected by a Neoarchaean high-grade metamorphic overprint, which was caused by magmatic heat transfer into the lower crust in a ‘dynamic regional contact metamorphic milieu’, which perhaps took place in a magmatic arc setting. 相似文献
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Abundance regularities for heavy nuclei (A>58) are investigated and formulated as abundance rules. Abundance values of carbonaceous chondrites of type 1 and 2 as well as most probable values for primordial abundances are listed. The abundance rules definitely require minor connections of the empirical values. A measurement of the (n, ) cross-section of Pd104 would make possible to decide whether type-1 or type-2 carbonaceous chondrites have a more primitive elemental composition.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973. 相似文献