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1.
Mafic granulite xenoliths from the lower crust of the Pannonian Basin are dominated by LREE-depleted bulk-rock compositions. Many of these have MORB-like 143Nd/144Nd but 87Sr/86Sr is elevated relative to most MORBs. Their '18O values cover a wide range from +3.8 to +9.5‰. A group of LREE-enriched mafic granulites have higher 87Sr/86Sr (0.704-0.708) and lower 143Nd/144Nd (0.5128-0.5124), with higher '18O values on average (+7.8 to +10.6‰) than the LREE-depleted granulites. The LREE-enriched granulites are, however, isotopically similar to newly discovered metasedimentary granulite xenoliths. A sublinear correlation in )Hf-)Nd isotope space has a shallower slope than the crust-mantle array, with the metasedimentary rocks forming the low )Hf end member; the radiogenic end is restricted to the LREE-depleted granulites and these overlap the field of MORB. Pb isotopes for the LREE-depleted samples are less radiogenic on average than those of the LREE-enriched and metasedimentary xenoliths, and metasedimentary granulites have consistently higher 208Pb/204Pb. The wide range in '18O over a restricted range in Nd and Sr isotope values, in combination with the predominance of LREE-depleted trace-element compositions, is consistent with an origin as a package of hydrothermally altered oceanic crust. The existence of '18O values lower than average MORB and/or mantle peridotite requires that at least some of these rocks were hydrothermally altered at high temperature, presumably in the oceanic lower crust. The low 143Nd/144Nd of the LREE-enriched mafic granulites cannot be explained by simple mixing between a LREE-depleted melt and an enriched component, represented by the recovered metasediments. Instead, we interpret these rocks as the metamorphic equivalent of the shallowest levels of the ocean crust where pillow basalts are intimately intercalated with oceanic sediments. A possible model is accretion of oceanic crustal slices during subduction and convergence, followed by high-grade metamorphism during the Alpine orogeny.  相似文献   
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In the Upper Pliocene, during the final phase of igneous activity within the Pannonian Basin, alkali basalts were erupted. Their occurrences are restricted to two main regions in Hungary: 1) Transdanubia; 2) Nógrád County. The clinopyroxene phenocrysts of these rocks are zoned titanaugites which often have distinctive colourless or green cores. Two kinds of green cores can be distinguished: 1. olive-green cores (fassaitic augite and fassaite), and 2. grassgreen cores (salite and ferrosalite). Both types of green cores are comparatively iron-rich and they occur only in the basalts of Nógrád County. The olive-green fassaites probably precipitated from relatively evolved melts which have been mixed into their present host magmas, whereas the grassgreen salites and ferrosalites are xenocrysts derived probably from upper mantle rocks. The clinopyroxene zoning patterns suggest, that after being generated by small-degree partial melting in the mantle the Transdanubian basalts ascended to the surface with little or no modification en route, whereas those of Nógrád County had a more complex evolution, in which fractionation at depth and magma mixing played an important role.  相似文献   
3.
Summary The mineral chemistry of several Pliocene alkali basaltic rocks from Burgenland and Styria (Eastern Austria) have been investigated in order to determine the evolution path of the basalt magmas prior to eruption. With their wide range of substitutions, clinopyroxenes provide the best records of the evolution history of rocks. Pyroxene phenocrysts of the investigated basalts show both concentric and sector zoning. The investigation of sector zoned crystals shows, that not only Ti, Al and Fe contents are different in different sectors but there can be significant differences also in their Cr content. This fact apparently suggests that the distribution of Cr between clinopyroxene and melt could be influenced by crystallization kinetics.The depth of crystallization and differentiation of the basalts can be estimated from Ti and Al contents of clinopyroxene phenocrysts. From a combination of data on clinopyroxene composition, compatible trace element contents and mg-values of the rocks, it is concluded, that the alkali basalts of Pauliberg and Steinberg underwent slight olivine and clinopyroxene fractionation in shallow magma chambers prior to eruption, while the nephelinite of Stradnerkogel evolved mainly through clinopyroxene fractionation under high pressure conditions, probably in the upper mantle.
Chemie der Pyroxene und Entwicklung von Alkalibasalten aus dem Burgenland und der Steiermark, Österreich
Zusammenfassung Einige pliozäne alkalibasaltische Gesteine aus dem Burgenland und der Steiermark wurden mineral-chemisch untersucht, um Aufschluß über ihre Evolution vor der Eruption zu erhalten. Klinopyroxene mit ihren vielfältigen Subtitutionsmöglichkeiten erlauben am besten eine Abschätzung der Evolution der Basalte. Pyroxen-Einsprenglinge der Basalte zeigen sowohl konzentrischen als auch sektoralen Zonarbau. Die von uns untersuchten Einsprenglinge zeigen in den verschiedenen Sektoren nicht nur unterschiedliche Gehalte an Ti, Al und Fe, sondern vielfach auch unterschiedliche Cr-Gehalte. Dies macht es wahrscheinlich, daß die Verteilung von Cr zwischen Klinopyroxen und Schmelze von der Kristallisations-Kinetik beeinflußt wird.Die Tiefe in der die Basalte kristallisierten und differenzierten kann von den Ti- und Al-Gehalten der Klinopyroxen- Einsprenglinge abgeschätzt werden. Die Zusammensetzung der Klinopyroxene im Verein mit den Gehalten an kompatiblen Spurenelementen und denmg-Werten der Gesteine erlauben den Schluß, daß die Alkalibasalte von Pauliberg und Steinberg vor ihrer Eruption eine geringfügige Olivinund Klinopyroxen-Fraktionierung in einer seichten Magmakammer erlebten. Der Nephelinit vorn Stradnerkogel hingegen erfuhr hauptsächlich eine Klinopyroxen Fraktionierung unter Hochdruck-Bedingungen, möglicherweise im oberen Erdmantel.


With 8 Figures  相似文献   
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Micron-scale iron-distribution patterns in sphalerite grains derived from two contrasting mineral assemblages of the Nagybörzsöny hydrothermal ore deposits (high temperature stockwork and low temperature veins), were determined with electron microprobe, pointcounter and continuous chart-recorder measurements along radial profiles. A significant oscillation of iron-content ranging from 8.1 to 18 per cent for stockwork and 4.3 to 15.8 per cent for veins took place during crystal growth. Homogeneous crystal cores are characteristic for vein-filling, while replacement occurring in deeper levels of the stockwork results in mosaic cores. Frequent oscillation of iron content is relevant to top-sections of the ore bodies, copious supply being recorded in recurring shells, whereas scanty, unilateral ones produce crescents arranged in onion-like structure.
Zusammenfassung Bestimmungen der Eisenverteilung wurden an Zinkblendekörnern aus zwei verschiedenen Mineralparagenesen (Hochtemperatur-Stockwerk und Gangfüllungen niederiger Bildungstemperatur) der hydrothermalen Erzlagerstätte Nagybörzsöny im Mikronbereich durch Elektronen-Mikrosonde-Messungen (Punktzählung und kontinuierliche Band-Registrierung) entlang radialer Profile vorgenommen. Bedeutende Schwankungen des Eisengehaltes (8,1–18% für das Stockwerk und 4,3–15,8% für die Gänge) wurden registriert. Homogene Kristallkerne kennzeichnen die Gangfüllungen, wogegen in tieferen Horizonten des Stockwerks Verdrängungen zur Bildung von Kristallen mit Mosaik-Kernen führen. Allgemein ist in den Gipfel-Partien der Erzkörper Fluktuation des Eisengehaltes häufig. Gleichmäßiger Nachschub während des Kristallwachstums führte zu ringförmigen Zonen gleicher Eisengehalte, spärlicher oder einseitiger dagegen zu halbmondförmigen Hüllen mit Zwiebelstruktur.
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Water protection is one of the most important goals in environmental protection. The Clean Water Act in the USA and the Water Framework Directive (WFD) in Europe are the legal frameworks to facilitate the achievement of this goal. The question is raised of whether more information can be extracted from WFD-related groundwater data. To answer it, a methodology has been developed that is easy to use and could be implemented into official practice. A case study is presented in which the groundwater data of a sodic area in Austria (Seewinkel) is assessed. Eighteen parameters in groundwater sampled from 23 wells (1991–2011) were analyzed. With basic statistics, trend-, cluster-, Wilks’ λ and spatial sampling density analysis, local phosphorus and boron phenomena were described, along with the determining role of sulphate, groundwater flow, and the oxygen gradient in the area. As a final step, the spatial sampling density was determined. Regarding the current set of parameters, all the sampling sites are necessary and only in the case of certain parameters (Ca2+, Mg2+, K+, NO3 ?, pH) could one sampling site be abandoned. The methodology applied brings a new perspective to exploring groundwater data collected according to the requirements of the WFD.  相似文献   
8.
Peridotite xenoliths erupted by alkali basaltic volcanoes in the western Pannonian Basin can be divided into two fundamentally contrasting groups. Geochemical characteristics of the abundant protogranular, porphyroclastic and equigranular nodules suggest that these samples originate from an old consolidated and moderately depleted lithospheric mantle domain. In contrast, the geochemical features of the worldwide rare, but in the Pannonian Basin relatively abundant, poikilitic xenoliths attest to a more complex evolution. It has been argued that the origin of the peculiar texture and chemistry may be intimately linked to melt/rock reactions at successively decreasing liquid volumes in a porous melt flow system. The most likely site where such reactions can take place is the asthenosphere–lithosphere boundary. In this context, poikilitic xenoliths may provide petrological and geochemical evidence for reactions between magmatic liquids issued from the uprising asthenosphere and the solid mantle rocks of the lithosphere. These reactions are important agents of the thermal erosion of the lithosphere; thus, they could have considerably contributed to the thinning of the lithosphere in the Pannonian region. We suggest that in the Pannonian Basin, there could be a strong relation between the unusual abundance of poikilitic mantle xenoliths and the strongly eroded lithosphere.  相似文献   
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