Magmatic gases in well fluids aid the mapping of the flow pattern in a geothermal system     

H. Ármannsson  G. Gíslason  T. Hauksson 《Geochimica et cosmochimica acta》1982,46(2):167-177

Gas composition and silica concentrations of well fluids are used in conjunction with pressure, temperature and enthalpy data to obtain a model of the drilled part of the Krafla geothermal field (Northeast Iceland).A magma chamber is located at 3–8 km depth under the field. Magmatic gases emanate from the chamber and travel via a channel reaching the surface at the Hveragil eruptive fissure. The composition of the gases is apparently modified on the way, in that sulphur, which presumably is in the form of sulphur dioxide to begin with, is removed on the way, and what remains is in the form of hydrogen sulphide at the end. It is suggested that the major removal mechanism is the deposition of pyrite and pyrrhotite during the passage of the gases through the hydrothermal system.The hydrothermal system is divided into a lower part whose temperature exceeds 300°C and whose fluids are to a varying extent affected by the magmatic gases, and an upper part whose temperature is ca 200°C. This upper part is a run-off from the lower part but the magmatic effects have mostly disappeared there.  相似文献   

The behaviour of Li and Mg isotopes during primary phase dissolution and secondary mineral formation in basalt   总被引：1，自引：0，他引：1  

Josh Wimpenny  Sigurður R. Gíslason  Abdelmouhcine Gannoun  Philip A.E. Pogge Von Strandmann 《Geochimica et cosmochimica acta》2010,74(18):5259-6026

This study presents lithium (Li) and magnesium (Mg) isotope data from experiments designed to assess the effects of dissolution of primary phases and the formation of secondary minerals during the weathering of basalt. Basalt glass and olivine dissolution experiments were performed in mixed through-flow reactors under controlled equilibrium conditions, at low pH (2-4) in order to keep solutions undersaturated (i.e. far-from equilibrium) and inhibit the formation of secondary minerals. Combined dissolution-precipitation experiments were performed at high pH (10 and 11) increasing the saturation state of the solutions (moving the system closer to equilibrium) and thereby promoting the formation of secondary minerals.At conditions far from equilibrium saturation state modelling and solution stoichiometry suggest that little secondary mineral formation has occurred. This is supported by the similarity of the dissolution rates of basalt glass and olivine obtained here compared to those of previous experiments. The δ⁷Li isotope composition of the experimental solution is indistinguishable from that of the initial basalt glass or olivine indicating that little fractionation has occurred. In contrast, the same experimental solutions have light Mg isotope compositions relative to the primary phases, and the solution becomes progressively lighter with time. In the absence of any evidence for secondary mineral formation the most likely explanation for these light Mg isotope compositions is that there has been preferential loss of light Mg during primary phase dissolution.For the experiments undertaken at close to equilibrium conditions the results of saturation state modelling and changes in solution chemistry suggest that secondary mineral formation has occurred. X-ray diffraction (XRD) measurements of the reacted mineral products from these experiments confirm that the principal secondary phase that has formed is chrysotile. Lithium isotope ratios of the experimental fluid become increasingly heavy with time, consistent with previous experimental work and natural data indicating that ⁶Li is preferentially incorporated into secondary minerals, leaving the solution enriched in ⁷Li. The behaviour of Mg isotopes is different from that anticipated or observed in natural systems. Similar to the far from equilibrium experiments initially light Mg is lost during olivine dissolution, but with time the δ²⁶Mg value of the solution becomes increasingly heavy. This suggests either preferential loss of light, and then heavy Mg from olivine, or that the secondary phase preferentially incorporates light Mg from solution. Assuming that the secondary phase is chrysotile, a Mg-silicate, the sense of Mg fractionation is opposite to that previously associated with silicate soils and implies that the fractionation of Mg isotopes during silicate precipitation may be mineral specific. If secondary silicates do preferentially remove light Mg from solution then this could be a possible mechanism for the relatively heavy δ²⁶Mg value of seawater. This study highlights the utility of experimental studies to quantify the effects of natural weathering reactions on the Li and Mg geochemical cycles.  相似文献   

Effects of volcanic eruptions on the CO₂ content of the atmosphere and the oceans: the 1996 eruption and flood within the Vatnajökull Glacier, Iceland     

S. R. Gí  slason    . Snorrason  H. K. Kristmannsd  ttir    . E. Sveinbj  rnsd  ttir  P. Torsander  J.   lafsson  S. Castet  B. Dupr 《Chemical Geology》2002,190(1-4):181-205

The October 1996 eruption within the Vatnajökull Glacier, Iceland, provides a unique opportunity to study the net effect of volcanic eruptions on atmospheric and oceanic CO₂. Volatile elements dissolved in the meltwater that enclosed the eruption site were eventually discharged into the ocean in a dramatic flood 35 days after the beginning of the eruption, enabling measurement of 50 dissolved element fluxes. The minimum concentration of exsolved CO₂ in the 1×10¹² kg of erupted magma was 516 mg/kg, S was 98 mg/kg, Cl was 14 mg/kg, and F was 2 mg/kg. The pH of the meltwater at the eruption site ranged from about 3 to 8. Volatile and dissolved element release to the meltwater in less than 35 days amounted to more than one million tonnes, equal to 0.1% of the mass of erupted magma. The total dissolved solid concentration in the floodwater was close to 500 mg/kg, pH ranged from 6.88 to 7.95, and suspended solid concentration ranged from 1% to 10%. According to H, O, C and S isotopes, most of the water was meteoric whereas the C and S were of magmatic origin. Both C and S went through isotopic fractionation due to precipitation at the eruption site, creating “short cuts” in their global cycles. The dissolved fluxes of C, Ca, Na, Si, S and Mg were greatest ranging from 1.4×10¹⁰ to 1.4×10⁹ mol. The dissolved C flux equaled 0.6 million tonnes of CO₂. The heavy metals Ni, Mn, Cu, Pb and Zn were relatively mobile during condensation and water–rock interactions at the eruption site. About half of the measured total carbon flood flux from the 1996 Vatnajökull eruption will be added to the long-term CO₂ budget of the oceans and the atmosphere. The other half will eventually precipitate with the Ca and Mg released. Thus, for eruptions on the ocean floor, one can expect a net long-term C release to the ocean of less than half that of the exsolved gas. This is a considerably higher net C release than suggested for the oceanic crust by Staudigel et al. [Geochim. Cosmochim. Acta, 53 (1989) 3091]. In fact, they suggested a net loss of C. Therefore, magma degassed at the ocean floor contributes more C to the oceans and the atmosphere than magma degassed deep in the oceanic crust. The results of this study show that subglacial eruptions affecting the surface layer of the ocean where either Mn, Fe, Si or Cu are rate-determining for the growth of oceanic biomass have a potential for a transient net CO₂ removal from the ocean and the atmosphere. For eruptions at high latitudes, timing is crucial for the effect of oceanic biota. Eruptions occurring in the wintertime when light is rate-determining for the growth of biota have much less potential for bringing about a transient net negative CO₂ flux from the ocean atmosphere reservoir.  相似文献   

Diffuse volcanic degassing and thermal energy release from Hengill volcanic system, Iceland     

Pedro A. Hernández  Nemesio M. Pérez  Thráinn Fridriksson  Jolie Egbert  Evgenia Ilyinskaya  Andri Thárhallsson  Gretar ívarsson  Gestur Gíslason  Ingvi Gunnarsson  Birgir Jónsson  Eleazar Padrón  Gladys Melián  Toshiya Mori  Kenji Notsu 《Bulletin of Volcanology》2012,74(10):2435-2448

We report the first detailed study of spatial variations on the diffuse emission of carbon dioxide (CO₂) and hydrogen sulfide (H₂S) from Hengill volcanic system, Iceland. Soil CO₂ and H₂S efflux measurements were performed at 752 sampling sites and ranged from nondetectable to 17,666 and 722?g?m^?2?day^?1, respectively. The soil temperature was measured at each sampling site and used to evaluate the heat flow. The chemical composition of soil gases sampled at selected sampling sites during this study shows they result from a mixing process between deep volcanic/hydrothermal component and air. Most of the diffuse CO₂ degassing is observed close to areas where active thermal manifestations occur, northeast flank of the Hengill central volcano close to the Nesjavellir power plant, suggesting a diffuse degassing structure with a SSW?CNNE trend, overlapping main fissure zone and indicating a structural control of the degassing process. On the other hand, H₂S efflux values are in general very low or negligible along the study area, except those observed at the northeast flank of the Hengill central volcano, where anomalously high CO₂ efflux and soil temperatures were also measured. The total diffuse CO₂ emission estimated for this volcanic system was about 1,526?±?160?t?day^?1 of which 453?t?day^?1 (29.7?%) are of volcanic/hydrothermal origin. To calculate the steam discharge associated with the volcanic/hydrothermal CO₂ output, we used the average H₂O/CO₂ mass ratio from 12 fumarole samples equal to 88.6 (range, 9.4?C240.2) as a representative value of the H₂O/CO₂ mass ratios for Hengill fumarole steam. The resulting estimate of the steam flow associated with the gas flux is equal to 40,154?t?day^?1. The condensation of this steam results in thermal energy release for Helgill volcanic system of 1.07?×?10¹⁴?J?day^?1 or to a total heat flow of 1,237?MW_t.  相似文献   

The effect of gross primary production, net primary production and net ecosystem exchange on the carbon fixation by chemical weathering of basalt in northeastern Iceland     

Marin Ivanov Kardjilov  Sigurdur Reynir Gíslason  Gudrún Gísladttir 《Journal of Geochemical Exploration》2006,88(1-3):292

The overall objective of this study is to define and interpret the annual dissolved inorganic carbon (DIC) flux in selected river catchments in North Eastern Iceland. The flux stems primarily from chemical weathering of basalt. The DIC flux out of the catchments is compared with the spatial distribution of the various vegetation communities and their gross primary production (GPP), net primary production (NPP) and net ecosystem exchange (NEE). There is no correlation between the DIC flux and the GPP, but one between DIC and NPP. The DIC flux is highly dependent on the NEE, which in turn is governed by the area extent of wetlands in these catchments. A variation by a factor 5 of the NEE results in a variation by a factor 2.8 in the river dissolved inorganic flux.  相似文献   

Suspended basaltic glass–seawater interactions     

Matthildur B. Stefnsdttir  Sigurdur R. Gíslason 《Journal of Geochemical Exploration》2006,88(1-3):332

The objective of this study was to quantify by experiments the initial seawater–suspended basaltic glass interactions following the 1996 outburst flood from the Vatnajökull glacier, Iceland. The altered basaltic glass dissolved in seawater as recorded by the Si release from the glass. The dissolved concentrations of Na, Ca, Si, Ba, Cd, Co, Cu, Hg, Mn, Ni and total dissolved inorganic N increased with time but the concentrations of Mg, K, S, Sr, Fe, Pb and Zn decreased. Calculated 1 to 10 day fluxes for Si range from 38,000 tons/day to 70,000 tons/10 days. The fluxes for other major elements are more uncertain, but the positive flux (release from suspended matter to seawater) of Ca and Na, and negative flux of Mg, K and S are greater than the Si flux.  相似文献   

Flow under standing waves: Part 1. Shear stress distribution,energy flux and steady streaming     

Kjartan Gíslason  Jørgen Fredsøe  Rolf Deigaard  B. Mutlu Sumer 《Coastal Engineering》2009

The conditions for energy flux, momentum flux and the resulting streaming velocity are analysed for standing waves formed in front of a fully reflecting wall. The exchange of energy between the outer wave motion and the near bed oscillatory boundary layer is considered, determining the horizontal energy flux inside and outside the boundary layer. The momentum balance, the mean shear stress and the resulting time averaged streaming velocities are determined. For a laminar bed boundary layer the analysis of the wave drift gives results similar to the original work of Longuet–Higgins from 1953. The work is extended to turbulent bed boundary layers by application of a numerical model. The similarities and differences between laminar and turbulent flow conditions are discussed, and quantitative results for the magnitude of the mean shear stress and drift velocity are presented. Full two-dimensional simulations of standing waves have also been made by application of a general purpose Navier–Stokes solver. The results agree well with those obtained by the boundary layer analysis. Wave reflection from a plane sloping wall is also investigated by using the same numerical model and by physical laboratory experiments. The phase shift of the reflected wave train is compared with theoretical and empirical models.  相似文献