X₆₀钢在CO₂饱和盐水中缓蚀作用的研究     

顾锦城  李文钦  林嘉信  冯湘珠  施维新 《海洋科学》1989,13(6):16-22

本文采用动电位极化、线性极化、电偶电流和高压釜挂片失重等法,研究了含氮、硫有机缓蚀剂和/或Me~(2+)对X60钢在CO_2饱和的盐水溶液中的缓蚀作用。结果表明,含氮、硫的有机缓蚀剂在缓蚀过程中,开始是以抑制阳极过程为主,随后是以抑制阴极过程为主的混合型缓蚀剂。如与Me~(2+)复配使用,能明显地提高缓蚀效能。  相似文献   

海底油气管道内CO₂腐蚀与防腐的研究     

顾锦城  林嘉信  冯湘珠  李文钦  施维新 《海洋与湖沼》1991,22(2):168-174

本工作采用2.4mV/s动态电位扫描极化、控制电位极化、电偶电流和高压釜挂片失重法研究了X60钢在含Ca~(2+)36.26mg/L,Mg~(2+)12.66mg/L和Cl~-3624mg/L的模拟氯化钠盐水中,CO_2引起腐蚀的电化学行为,以及含氮、硫的有机缓蚀剂和(或)Me~(2+)对腐蚀的抑制作用。结果表明:溶有CO_2的盐水腐蚀性强,盐浓度及温度会影响钢的腐蚀速度和阴极极化行为;75mg/L缓蚀剂的缓蚀率达90％,服从Langmuir吸附等温式;50mg/L缓蚀剂与127mg/LMe~(2+)复配,缓蚀率达91％以上,不服从Langmuir吸附等温式。  相似文献   

金属腐蚀闭塞区内电位和pH参数的探索          下载免费PDF全文

顾锦城  林嘉信  施维新 《海洋与湖沼》1988,19(3):272-277

模拟闭塞腐蚀电池的发生过程,研究了OCr 18Ni 9Ti奥氏体不锈钢在pH=6.86的3％ NaCl溶液中,在承受一定拉应力的情况下,闭区内试样段电位和介质pH值随闭区外试样段极化电位变化的规律。结果表明:不论闭区外试样段阳极极化电位值的高还是低,闭区内试样段的电位均落在试样自腐蚀电位范围内,闭区内介质pH=2.5—3.0。当闭区外试样段阴极极化时,闭区内试样段电位接近外部试样的极化电位值,但一般要正十几毫伏到几十毫伏,闭区内介质的pH值都随着闭区外试样段极化电位的负移而上升。  相似文献   

EFFECT OF Fe~(2+) IONS ON POLARIZATION BEHAVIOR OF X60 STEEL IN CO_2 SATURATED SALTY WATER     

顾锦城  冯湘珠  林加信  施维新  李文钦 《中国海洋湖沼学报》1989,(2)

The effects of ferrous ions on cathodic and anodic polarization behavior of the X60 steel in CO2 saturated salty water were studied by potentio - dynamic polarization method. The results show that the reducing current peak of cathodic polarization is affected significantly if FeCl2 is added to the salty solution of controlled pH, but not the anodic polarization. It is considered that the ferrous ions accelerate the formation of a protective ferrous carbonate film . Films formed by addition of ferrous ions and those formed by ferrous ions produced from steel corrosion have the same forming mechanism . The former can fully meet the formative condition of the film and can play the role of inhibitor .  相似文献