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This study was undertaken to elucidate the impact of early diagenetic processes on the accumulation of trace metals in Sapelo Island saltmarsh sediments as a function of time, space and sediment properties. Samples were collected from three sites in summer (May 1997) and winter (January 1998) along a transect from an unvegetated Creek Bank through a vegetated Tidal Levee to the vegetated midmarsh with evident lateral heterogeneity caused by hydrologic regime, macrophytes and microbial and macrofaunal activities. A suite of trace metals (As, Ba, Cr, Co, Cu, Cd, Mo, Ni, Pb, Th, Ti, U, V, Zn and Zr) was analyzed to obtain their depth-distribution at the three sites. Spatially marked differences were observed, that were primarily related to hydraulic flushing of trace metals away from the sites in high-energy regimes, rapid downward mixing and reworking of sediment via bioturbation, and below-ground degradation and production of Spartina biomass. Although sulfate reduction and the formation of acid volatile sulfide and pyrite were dominant processes throughout the marsh, the trace metal scavenging role of sulfides was not apparent. However, possible sulfurization of organic matter, leading to enhanced trapping of trace metals with organic carbon, may have played an important role in sequestration of trace metals.No similarity was observed visually between the depth trends of trace metals and sediment properties (grain size, iron-oxyhydroxide content, acid volatile sulfides and pyrite content) that are known to play a major role in trace metal partitioning. Only organic carbon content closely followed the trace metal profiles at all the three sites. Minor variation in depth-integrated sediment trace metal content was observed seasonally at each of the three sites. Furthermore, the depth trend of profiles of individual trace metals also did not vary significantly over the seasons either.  相似文献   
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The paper presents the 3D finite element simulation of tidal flow and Sediment transport in the estuarine region of the Haihe river. The proposed model adopts sigma-transformation of the hydrodynamic and sediment transport equations. The hydrodynamic and sediment transport models are verified in case of a simple test problem for which analytical solutions are available. Finally the models are applied to muddy Haihe river estuary of North China and it is claimed that hydrodynamic and sediment transport models give a reliable comparison with the observed field data. However, there are certain discrepancies, and some reasonable questions regarding the present state-of-art, in the modeling of three-dimensional multilevel hydrodynamics and sediment transport, which are provided below for answer.  相似文献   
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— Seismic responses of weathered and non-weathered ridge models were simulated to study the ridge effects on the ground motion characteristics. The range of ridge slope from 19.98° to 45° was considered to produce a possible set of generalized results. 2.5-D modeling based on parsimonious staggered grid approximation of elastodynamic wave equations was adopted in simulations. Computed results reveal an increase of amplitude of incoming waves with both elevation and the slope of the ridge. Further, the characteristics of surface waves are highly ridge slope dependent. The analysis of responses of weathered and non-weathered ridge models reveals that ridge has caused a strong generation of surface waves near its top. The surface waves are not dominating on the top of the ridge but at some lower elevation. The increase of weathering of ridge further intensified the ridge effect. Analysis in frequency domain, based on spectral ratio method, does not indicate any pattern in the spectral amplification factor and is very much sensitive to slope, source focal mechanism and location. However, on an average there is a continuous decrease of amplification with slope in the vertical component and increase in the transverse component, and it is increasing in the radial component up to slope =38.0° and thereafter decreasing.  相似文献   
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—An algorithm has been developed to compute the dispersive and dissipative seismic response using FUTTERMAN’S (1962) third attenuation-dispersion relationship. In the computation, frequency-dependent velocity and quality factor Q have been used but in the case of the nondispersive synthetic seismogram, frequency-independent velocity has been used. The model’s parameters are density, phase velocity, quality factors and thicknesses of the layers. Dispersive and nondispersive synthetic seismograms have been computed with and without absorption for a layered earth geological model. Fast Fourier transform (FFT) technique has been adopted for converting the frequency domain response into the time domain. The frequency spacing, Δf = 0.976?Hz, has been considered to avoid the aliasing effect. The results have revealed changes in the reflected waveforms in the frequency domain as well as in the time domain for absorption and dispersion cases. It is also concluded that dispersion reduces the arrival time and this effect is increasing with the travel time. The effect of constant Q on the seismic response has also been studied.  相似文献   
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Since the Paris Agreement was adopted in 2015, both national and subnational governments have been encouraged to submit Mid-Century Strategies, outlining how they would reach their deep decarbonization goals. However, research on the design and potential of these strategies has been very limited. To address this shortcoming, here we assess 13 such strategies – six national, seven subnational – in a comparative fashion. We find that the energy-economy-climate models underpinning these strategies are generally of high quality, though national jurisdictions generally performed better. However, most strategies are not plausible without significant changes to policy, and the industrial sector in particular presents a major limitation. The strategies are helpful in revealing this gap, but much works remains to be done for plausible mid-century decarbonization trajectories to become a reality. We also find that public input and societal participation in strategy building were a double-edged sword depending on the constellation of domestic preferences.
  • Governmental Mid-Century Strategies for deep decarbonization are underpinned by high-quality energy-economy-climate models

  • Governments’ proposed strategies require significant new policies, as even among jurisdictions that have an MCS, extant policies are insufficient to achieve deep decarbonization

  • No jurisdiction studied has yet put forward a plausible decarbonization policy for the industrial sector.

  • Public input and societal participation can be a double-edged sword: they can increase durability of the strategy but also enable opposing forces to mobilize against ambitious changes.

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Numerical solution of the scalar and elastic wave equations has greatly aided geophysicists in modeling seismic wave fields in the complicated geologic structures containing hydrocarbons and hence increases the geologic interpretation. Finite-difference method offers a versatile approach to compute synthetic seismograms numerically for given subsurface complex geological structures. To avoid the spatial derivative of the elastic parameters and density, elastodynamic equation (first-order hyperbolic equation) has been solved using the Lax-Wendroff scheme. A numerical finite-difference modeling program has been developed for the P-SV wave using the above solution. A line source with a time delay of 0.015s and dominant frequency of 120 Hz has been utilized in the simulation. In order to avoid the large values of the displacement vector in the source region,Alterman andKaral's method (1968) has been utilized. Horizontal and vertical component synthetic seismograms have been computed for two different geological models with and without oil and gas bearing zones. It has been concluded from the response that a finite-difference technique not only yields the relative arrival times but also accounts for the variation in amplitude and phase according to the elastic impedance contrast across the interfaces. It should come as no surprise to learn that in spite of the limitation of this numerical method, the scheme has provided a valid response for the thin layer, high acoustic impedance contrast and the pinch out.  相似文献   
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