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Sulfur biogeochemical cycling and novel Fe-S mineralization pathways in a tidally re-flooded wetland 总被引：1，自引：0，他引：1
Edward D. Burton Richard T. Bush Scott G. Johnston Leigh A. Sullivan Annabelle F. Keene 《Geochimica et cosmochimica acta》2011,75(12):3434-3451
Sulfur biogeochemical cycling and associated Fe-S mineralization processes exert a major influence over acidity dynamics, electron flow and contaminant mobility in wetlands, benthic sediments and groundwater systems. While S biogeochemical cycling has been studied intensively in many environmental settings, relatively little direct information exists on S cycling in formerly drained wetlands that have been remediated via tidal re-flooding. This study focuses on a tidal wetland that was drained in the 1970s (causing severe soil and water acidification), and subsequently remediated by controlled re-flooding in 2002. We examine reduction rates and Fe-S mineralization at the tidal fringe, 7 years after the commencement of re-flooding. The initial drainage of the wetland examined here caused in-situ pyrite (FeS2) oxidation, resulting in the drained soil layers being highly acidic and rich in -bearing Fe(III) minerals, including jarosite (KFe3(SO4)2(OH)6). Tidal re-flooding has neutralized much of the previous acidity, with the pore-water pH now mostly spanning pH 5-7. The fastest rates of in-situ reduction (up to ∼300 nmol cm−3 day−1) occur within the inter-tidal zone in the near-surface soil layers (to ∼60 cm below ground surface). The reduction rates correlate with pore-water dissolved organic C concentrations, thereby suggesting that electron donor supply was the predominant rate determining factor. Elemental S was a major short-term product of reduction, comprising up to 69% of reduced inorganic S in the near-surface soil layers. This enrichment in elemental S can be partly attributed to interactions between biogenic H2S and jarosite - a process that also contributed to enrichment in pore-water Fe2+ (up to 55 mM) and (up to 50 mM). The iron sulfide thiospinel, greigite (Fe3S4), was abundant in near-surface soil layers within the inter- to sub-tidal zone where tidal water level fluctuations created oscillatory redox conditions. There was evidence for relatively rapid pyrite re-formation within the re-flooded soil layers. However, the results indicate that pyrite re-formation has occurred mainly in the lower formerly drained soil layers, whereas the accumulation of elemental S and greigite has been confined towards the soil surface. The discovery that pyrite formation was spatially decoupled from that of elemental S and greigite challenges the concept that greigite is an essential precursor required for sedimentary pyrite formation. In fact, the results suggest that greigite and pyrite may represent distinct end-points of divergent Fe-S mineralization pathways. Overall, this study highlights novel aspects of Fe-S mineralization within tidal wetlands that have been drained and re-flooded, in contrast to normal, undisturbed tidal wetlands. As such, the long-term biogeochemical trajectory of drained and acidified wetlands that are remediated by tidal re-flooding cannot be predicted from the well-studied behaviour of normal tidal wetlands. 相似文献
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Wayne Erskine Anita Chalmers Annabelle Keene Michael Cheetham Richard Bush 《地球表面变化过程与地形》2009,34(7):941-953
Casuarina cunninghamiana Miq. is an important rheophytic tree in New South Wales, Australia because it is fast growing and can tolerate flood disturbance. Widden Brook is an active sand‐bed stream that has widened substantially since initial European settlement in the early 1800s and is characterized by high flood variability and multi‐decadal periods of alternating high and low flood frequency, called flood‐ and drought‐dominated regimes. Channel contraction by bench formation is currently occurring. Conversion of coarse‐grained point bars to benches is an important process of channel contraction. When point bars grow to a height where suspended sediment is first deposited to thicknesses of at least 50 mm by sub‐bankfull floods, rapid establishment of C. cunninghamiana occurs. As the trees grow they partially block bankside flows, thereby locally reducing flow velocity and inducing further deposition on the benches. Such synergistic relationships between bar height and inundation, fine‐grained sediment deposition, tree establishment and the development of a bankside low current velocity zone are fundamental for bench development. Size‐class frequency data demonstrate that C. cunninghamiana on the benches consists of pure even‐aged stands with most trees clustering near the average diameter. Two benches have similar size class frequency distributions but a third has significantly smaller trees. Recruitment on benches is episodic, may occur in areas open to grazing and is dependent on favourable conditions that allow tree survival. These favourable conditions include high seed availability, low levels of competition, deposition of fine sediments and adequate moisture for tree growth. Although C. cunninghamiana germinates on bars, seedlings are eliminated by prolonged inundation or flood scour and do not reach maturity. Recurring catastrophic floods or a sequence of large floods in rapid succession episodically destroy benches by substantial channel widening and initiate a new phase of bar and bench development. A conceptual model of the conversion of point bars to benches by thick mud deposition and C. cunninghamiana recruitment has been developed for sand‐bed streams draining similar sandstone catchments. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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Scott G. Johnston Edward D. Burton Richard T. Bush Annabelle F. Keene Leigh A. Sullivan Douglas Smith Angus E. McElnea Col R. Ahern Bernard Powell 《Applied Geochemistry》2010
Tidal inundation was restored to a severely degraded tropical acid sulfate soil landscape and subsequent changes in the abundance and fractionation of Al, Fe and selected trace metals were investigated. After 5 a of regular tidal inundation there were large decreases in water-soluble and exchangeable Al fractions within former sulfuric horizons. This was strongly associated with decreased soil acidity and increases in pH, suggesting pH-dependent immobilisation of Al via precipitation as poorly soluble phases. The water-soluble fractions of Fe, Zn, Ni and Mn also decreased. However, there was substantial enrichment (2–5×) of the reactive Fe fraction (FeR; 1 M HCl extractable) near the soil surface, plus a closely corresponding enrichment of 1 M HCl extractable Cr, Zn, Ni and Mn. Surficial accumulations of Fe(III) minerals in the inter-tidal zone were poorly crystalline (up to 38% FeR) and comprised mainly of schwertmannite (Fe8O8(OH)6SO4) with minor quantities of goethite (α-FeOOH) and lepidocrocite (γ-FeOOH). These Fe (III) mineral accumulations provide an effective substrate for the adsorption/co-precipitation and accumulation of trace metals. Arsenic displayed contrary behaviour to trace metals with peak concentrations (∼60 μg g−1) near the redox minima. Changes in the abundance and fractionation of the various metals can be primarily explained by the shift in the geochemical regime from oxic–acidic to reducing-circumneutral conditions, combined with the enrichment of reactive Fe near the soil surface. Whilst increasing sequestration of trace metals via sulfidisation is likely to occur over the long-term, the current abundance of reactive Fe near the sediment–water interface favours a dynamic environment with respect to metals in the tidally inundated areas. 相似文献
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Annabelle Cruz-Trinidad Rollan C. Geronimo Reniel B. Cabral Porfirio M. Aliño 《Ocean & Coastal Management》2011,54(9):696-705
The Total Economic Value of the estimated 200 km2 of coral reef area straddling the municipalities of Alaminos, Anda, Bani and Bolinao in Pangasinan, Philippines is estimated to reach US$38 million per year consisting mainly of indirect benefits from shoreline protection. Direct use from fisheries, aquaculture, and tourism was valued at US$6 million based on the coral reef interaction index. Non-use values for coral reef conservation were based on estimates of willingness to pay across the three economic sectors plus the general public as a fourth sector. Results varied across sectors and municipalities although the ranges were not wide, especially for fishers. Fishers’ willingness to pay averaged at US$0.25 per individual per year. Except for aquaculture operators in Bolinao, which yielded willingness to pay values reaching US$3 per individual per year, the range of conservation funding was narrow for the three other municipalities for all sectors. Using binary logistic regression (logit model), differences in willingness to pay among fishers are explained by the age, number of children, and employment status. 相似文献
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Annabelle Cruz-Trinidad Rollan C. Geronimo Porfirio M. Aliño 《Ocean & Coastal Management》2009,52(3-4):173-180
Management interventions to reduce pressures on coral reefs often include attracting fishers to non-extractive non-fishery supplemental livelihoods. We look at the case of coral reefs in Lingayen Gulf, Philippines to understand the impacts of local (i.e., aquaculture and tourism), regional, and national development on the artisanal fisheries sector. Using household surveys and a coral reef interaction index (CRII), we obtained relative levels of dependency and impacts of fisheries, aquaculture, and tourism on coral reefs for livelihood. Results show that overall dependency on coral reefs remains high despite its decreasing quality. Socio-economic profiles reveal steep hurdles in shifting fishers to aquaculture. Both aquaculture and fisheries will continue to grow and eventually compete for space if left unmanaged further resulting in reduced reef quality. Shifts of fishers to tourism-based and other low-capital requirement mariculture (e.g., sea ranching) are more realistic than the expectation of absorbing fishers into current aquaculture businesses. Strengthening local coastal governance capacity to improve proactive responses for micro–macro development interactive synergy will also help reduce the impacts of development on reefs. Improving safety nets for coastal communities through skills enhancement and supplemental livelihood options that facilitate stewardship and reef recovery is an imperative. Transforming the lessons learned at village level actions to sustain municipal scale programs and institutional cooperation among stakeholders such as through marine protected area networks remain a challenge. Sharing forums and joint financing of coastal resource management remain to be realized through public and private partnerships and expansion of development for investments in social enterprises. 相似文献
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Jaffrennou C Giamarchi P Cabon JY Stephan L Burel-Deschamps L Bautin F Thomas A Dumont J Le Floch S 《Marine pollution bulletin》2007,54(12):1932-1939
Coal is currently becoming an increasingly interesting fossil energy resource and that is the reason why its maritime transport, and hence the risk of collier accidents, increase. In this work, the environmental impact of an accidental coal immersion at sea is studied: the physicochemical effects are estimated using innovative experimental setups – a laboratory seawater canal called “polludrome” is used to evaluate the behaviour of coal particles submitted to a seawater flow, and a specifically designed tub is used to study the physicochemical consequences induced when coal is introduced into continuously renewed seawater. When coal is introduced into seawater, the most easily visible consequences are physical: fine coal particles reduce the daylight penetration up to 100% and move along with the flow, and coal chunks accumulate on the floor. Chemical effects are also measured: humic matters are dissolved from coal into seawater (up to 2 mg L−1), but no release of polycyclic aromatic hydrocarbons is evidenced. Some inorganic compounds are dissolved, among which manganese, whose concentrations can reach 1 μg L−1. Fortunately, the results show that the environmental impact of this type of accident would remain limited. 相似文献
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Scott G. Johnston Annabelle F. Keene Richard T. Bush Edward D. Burton Leigh A. Sullivan Lloyd Isaacson Angus E. McElnea Col R. Ahern C. Douglas Smith Bernard Powell 《Chemical Geology》2011,280(3-4):257-270
Tidal inundation is a new technique for remediating coastal acid sulfate soils (CASS). Here, we examine the effects of this technique on the geochemical zonation and cycling of Fe across a tidally inundated CASS toposequence, by investigating toposequence hydrology, in situ porewater geochemistry, solid-phase Fe fractions and Fe mineralogy. Interactions between topography and tides exerted a fundamental hydrological control on the geochemical zonation, redistribution and subsequent mineralogical transformations of Fe within the landscape. Reductive dissolution of Fe(III) minerals, including jarosite (KFe3(SO4)2(OH)6), resulted in elevated concentrations of porewater Fe2+ (> 30 mmol L?1) in former sulfuric horizons in the upper-intertidal zone. Tidal forcing generated oscillating hydraulic gradients, driving upward advection of this Fe2+-enriched porewater along the intertidal slope. Subsequent oxidation of Fe2+ led to substantial accumulation of reactive Fe(III) fractions (up to 8000 μmol g?1) in redox-interfacial, tidal zone sediments. These Fe(III)-precipitates were poorly crystalline and displayed a distinct mineralisation sequence related to tidal zonation. Schwertmannite (Fe8O8(OH)6SO4) was the dominant Fe mineral phase in the upper-intertidal zone at mainly low pH (3–4). This was followed by increasing lepidocrocite (γ-FeOOH) and goethite (α-FeOOH) at circumneutral pH within lower-intertidal and subtidal zones. Relationships were evident between Fe fractions and topography. There was increasing precipitation of Fe-sulfide minerals and non-sulfidic solid-phase Fe(II) in the lower intertidal and subtidal zones. Precipitation of Fe-sulfide minerals was spatially co-incident with decreases in porewater Fe2+. A conceptual model is presented to explain the observed landscape-scale patterns of Fe mineralisation and hydro-geochemical zonation. This study provides valuable insights into the hydro-geochemical processes caused by saline tidal inundation of low lying CASS landscapes, regardless of whether inundation is an intentional strategy or due to sea-level rise. 相似文献
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Annabelle F. Keene Scott G. Johnston Richard T. Bush Edward D. Burton Leigh A. Sullivan 《Marine pollution bulletin》2010,60(4):620-3451
This study examines the abundance of trace elements in surface sediments of a former acid sulfate soil (ASS) wetland subjected to marine tidal inundation. Sediment properties of this highly modified study site are compared with those of an adjacent unmodified, intertidal mangrove forest. Whilst some trace elements (Al, Cd, Mn, Ni and Zn) were clearly depleted due to mobilisation and leaching in the previous oxic-acidic phase, other trace elements (As and Cr) displayed significant enrichment in the tidally inundated ASS. Many trace elements were strongly associated with the reactive Fe and acid volatile sulfide (AVS) fractions, suggesting that trace elements may be adsorbed to abundant reactive Fe phases or sequestered as sulfide minerals. These findings provide an important understanding of the fate and mobility of reactive iron, AVS and trace elements during tidal remediation of a formerly acidified Great Barrier Reef (GBR) catchment. 相似文献
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Annabelle Workman Grant Blashki Kathryn J. Bowen David J. Karoly John Wiseman 《Climate Policy》2019,19(5):585-597
The 2015 Paris Agreement requires increasingly ambitious emissions reduction efforts from its member countries. Accounting for ancillary positive health outcomes (health co-benefits) that result from implementing climate change mitigation policies can provide Parties to the Paris Agreement with a sound rationale for introducing stronger mitigation strategies. Despite this recognition, a knowledge gap exists on the role of health co-benefits in the development of climate change mitigation policies. To address this gap, the case study presented here investigates the role of health co-benefits in the development of European Union (EU) climate change mitigation policies through analysis and consideration of semi-structured interview data, government documents, journal articles and media releases. We find that while health co-benefits are an explicit consideration in the development of EU climate change mitigation policies, their influence on final policy outcomes has been limited. Our analysis suggests that whilst health co-benefits are a key driver of air pollution mitigation policies, climate mitigation policies are primarily driven by other factors, including economic costs and energy implications.
Key policy insights
Health co-benefits are quantified and monetized as part of the development of EU climate change mitigation policies but their influence on the final policies agreed upon is limited.
Barriers, such as the immediate economic costs associated with climate action, inhibit the influence of health co-benefits on the development of mitigation policies.
Health co-benefits primarily drive the development of EU air pollution mitigation policies.
The separation of responsibility for GHG and non-GHG emissions across Directorate Generals has decoupled climate change and air pollution mitigation policies, with consequences for the integration of health co-benefits in climate policy.
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Michael D. Cheetham Annabelle F. Keene Wayne D. Erskine Richard T. Bush Kathryn Fitzsimmons Geraldine E. Jacobsen Stewart J. Fallon 《第四纪科学杂志》2010,25(7):1160-1168
A previous assessment of radiocarbon (14C) dates from alluvial units in southeastern Australia revealed a gap in the geochronological record that coincides with the Holocene climatic optimum. This gap in the alluvial record can be further refined using optically stimulated luminescence (OSL). The chronology of Holocene river terraces on Widden Brook, a sandy alluvial stream in southeastern Australia, was established using 14C and OSL techniques. Combined use of these independent techniques allows for a more rigorous assessment of the alluvial record. The robust chronology, consisting of 38 14C and 11 OSL samples, permitted identification of significant depositional variation within the catchment, resulting from localised geomorphic processes. The three terrace sequences identified yielded distinct chronologies, suggesting alluvial deposition at different times. The sequences exhibited a continuous chronology, which indicated continuous deposition throughout the Holocene. The chronology of terrace sequences within this catchment suggests that terrace formation can be attributed to localised geomorphic processes rather than climatic forcing. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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