Particulate content of savanna fire emissions   总被引：9，自引：0，他引：9  

Hélène Cachier  Catherine Liousse  Patrick Buat-Menard  Annie Gaudichet 《Journal of Atmospheric Chemistry》1995,22(1-2):123-148

As part of the FOS-DECAFE experiment at Lamto (Ivory Coast) in January 1991, various aerosol samples were collected at ground level near prescribed fires or under local background conditions, to characterize the emissions of particulate matter from the burning of savanna vegetation. This paper deals with total aerosol (TPM) and carbon measurements. Detailed trace element and polycyclic hydrocarbon data are discussed in other papers presented in this issue.Near the fire plumes, the aerosols from biomass burning are primarily of a carbonaceous nature (C%70% of the aerosol mass) and consist predominantly of submicron particles (more than 90% in mass.) They are characterized by their organic nature (black to total carbon ratio Cb/Ct in the range 3–20%) and their high potassium content (K/Cb0.6). These aerosols undergo aging during their first minutes in the atmosphere causing slight alterations in their size distribution and chemical composition. However, they remain enriched in potassium (K/Cb=0.21) and pyrene, a polycyclic aromatic hydrocarbon, such that both of these species may be used as tracers of savanna burning aerosols. We show that during this period of the year, the background atmosphere experiences severe pollution from both terrigenous sources and regional biomass burning (44% of the aerosol). Daynight variations of the background carbon concentrations suggest that fire ignition and spreading occur primarily during the day. Simultaneous TPM and CO₂ real-time measurements point to a temporal and spatial heterogeneity of the burning so that the ratio of the above background concentrations (TPM/CO₂) varies from 2 to 400 g/kg C. Smoldering processes are intense sources of particles but particulate emissions may also be important during the rapidly spreading heading fires in connection with the generation of heavy brown smoke. We propose emission factor values (EF) for aerosols from the savanna biomass burning aerosols: EF (TPM)=11.4±4.6 and 69±25 g/kg C_{dry plant} and EF(Ct)=7.4±3.4 and 56±16 g C/kg C_{dry plant} for flaming and smoldering processes respectively. In these estimates, the range of uncertainty is mostly due to the intra-fire variability. These values are significantly lower than those reported in the literature for the combustion of other types of vegetation. But due to the large amounts of vegetation biomass being burnt in African savannas, the annual flux of particulate carbon into the atmosphere is estimated to be of the order of 8 Tg C, which rivals particulate carbon emissions from anthropogenic activities in temperate regions.  相似文献   

Modelling of oxygen and nitrogen cycling as a function of macrophyte community in the Thau lagoon     

M. Plus  A. Chapelle  P. Lazure  I. Auby  G. Levavasseur  M. Verlaque  T. Belsher  J. -M. Deslous-Paoli  J. -M. Zaldívar  C. N. Murray 《Continental Shelf Research》2003,23(17-19):1877

A three-dimensional model coupling physical and biological processes for the whole Thau lagoon (Mediterranean coast of France) was developed in order to assess the relationships between macrophytes and the oxygen and nitrogen cycles. Ten species have been inserted as forcing variables in the model. Plankton dynamics, shellfish cultivation impact and mineralization of organic matter are also considered, as well as nutrient and oxygen exchanges between the sediment and the water column.Simulations with and without the macrophytes have shown that the system can be characterized as having a highly structured pattern involving lagoon nitrogen and oxygen cycles. This pattern is created by the combined influence of macrophytes, watershed and oyster farming.The model has been also used to assess the total annual macrophyte production at the whole lagoon scale. Comparisons with phytoplankton production and with results from other temperate lagoons have underlined the high productivity of the Thau lagoon supported by active nutrient regeneration.  相似文献   

Interpretation of gamma-ray logs: The distribution of uranium in carbonate platform     

Mohamed Chaker Raddadi  Annie Arnaud Vanneau  Grard Poupeau  Elisabeth Carrio-Schaffhauser  Hubert Arnaud  Alice Rivera 《Comptes Rendus Geoscience》2005,337(16):96

High gamma-radioactivity in carbonates is usually ascribed to uranium of detrital minerals and organic matter, and to thorium and potassium of clays. The present study based on Urgonian marls and marly limestones (France) shows that some of the most radioactive values correspond instead to some ‘pure’ limestones. These peaks are generally associated with a sequence boundary or a maximum flooding surface. Low-level γ-spectrometry and ICP–MS analyses show that although high radioactivities are mostly associated with uranium, there is no obvious correlation between uranium enrichment and lithology. Also, correlation between high radioactivity and argillaceous beds might not be systematic. To cite this article: M.C. Raddadi et al., C. R. Geoscience 337 (2005).  相似文献   

The removal kinetics of dissolved organic matter and the optical clarity of groundwater     

Francis H. Chapelle  Yuan Shen  Eric W. Strom  Ronald Benner 《Hydrogeology Journal》2016,24(6):1413-1422

Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d^?1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d^?1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L^?1) and ultraviolet absorption coefficient values (a ₂₅₄?<?5 m^?1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.  相似文献   

Attenuation in the uppermost inner core from broad-band GEOSCOPE PKP data   总被引：1，自引：0，他引：1  

Annie Souriau  Pascal Roudil 《Geophysical Journal International》1995,123(2):572-587

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Present limitations of accurate satellite Doppler positioning for tectonics. An example: Djibouti     

Annie Souriau  Alfred Piuzzi  Micheline Etchegorry  Philippe Machetel 《Journal of Geodesy》1984,58(1):53-72

One of the possibilities of the Doppler positioning from satellite is to provide geodetic measurements continuous in time without the need for reference stations. If measurements of sufficient accuracy can be achieved they may be used to study local surface displacements in relation to tectonic activity. A Doppler receiver of the MEDOC network is located near Djibouti in the Ghoubhat-Asal rift region which corresponds to the accreting plate boundary between the Arabian and African plates. In November 1978, a seismic and volcanic crisis occured in this area. Surface geodetic measurements and levellings performed in 1973 and 1978–79, just after the crisis, reveal a 60–80 cm sinking of the graben floor and a lateral extension of about 2 meters. Here we analyse Doppler measurements for the period January 1977 to November 1980. Point positions are computed for 7 to 10 day intervals using a precise ephemeris, and a moving window analysis is applied to the data. An apparent 2 meter uplift preceding the November 1978 seismic crisis is detected at Djibouti, whereas no similar phenomenon is observed at the two closest stations, Pretoria and Uccle-Brussels. However, field observations rule out a tectonic origin for this uplift. In Djibouti, the correlation between the apparent vertical station position and the electron density in the ionospheric F-layer reveals that a bias may be induced by the third order term of the ionospheric refractive index not previously taken into account, or more probably by the ray curvature through the ionosphere. This bias is particularly strong for our data set, from a station located close to the magnetic equator, and related to a period of rapid increase in the solar activity. Although our analysis fails to detect any tectonic displacement related to the rift seismic activity, it shows that similar tectonic studies by the Doppler method will be possible once the residual ionospheric errors are removed, for example by use of higher radio frequencies.  相似文献   

Evidence for Enhanced Mineral Dissolution in Organic Acid-Rich Shallow Ground Water   总被引：3，自引：0，他引：3  

Peter B. McMahon  Don A. Vroblesky  Paul M. Bradley  Francis H. Chapelle  Cheryl D. Gullett 《Ground water》1995,33(2):207-216

Total concentrations of formate, acetate, and isobutyrate varied from less than 5 to greater than 9,000 μmol/l over distances of < 3 m in ground water from a shallow hydrocarbon contaminated aquifer. Laboratory incubations of aquifer material indicate that organic acid concentrations were dependent on the amount of hydrocarbon loading in the sediment and the relative rates of microbial organic acid production and consumption. In heavily contaminated sediments, production greatly exceeded consumption and organic acid concentrations increased. In lightly contaminated sediments rates were essentially equal and organic acid concentrations remained low. Concentrations of dissolved calcium, magnesium, and iron generally were one to two orders of magnitude higher in organic acid-rich ground water than in ground water having low organic acid concentrations. Carbonate and Fe(III)-oxyhydroxide minerals were the likely sources of these elements. Similarly, concentrations of dissolved silica, derived from quartz and k-feldspar, were higher in organic acid-rich ground water than in other waters. The positive relation (r = 0.60, p < .05, n = 16) between concentrations of silica and organic acids suggests that the microbially mediated buildup of organic acids in ground water enhanced quartz/k-feldspar dissolution in the aquifer, although it was not the only factor influencing their dissolution. A model that included organic acid microequivalents normalized by cation microequivalents significantly strengthened the correlation (r = 0.79, p < .001, n = 16) between dissolved silica and organic acid concentrations, indicating that competition between silica and cations for complexation sites on organic acids also influenced quartz/k-feldspar dissolution. Physical evidence for enhanced mineral dissolution in organic acid-rich waters included scanning electron microscopy images of highly corroded quartz and k-feldspar grains from portions of the aquifer containing organic acid-rich ground water. Microporosity generated in hydrocarbon contaminated sediments may adversely affect remediation efforts that depend on the efficient injection of electron acceptors into an aquifer or on the recovery of solutes from an aquifer.  相似文献   

Investigation of Reductive Dechlorination Supported by Natural Organic Carbon   总被引：1，自引：0，他引：1  

Heather V. Rectanus  Mark A. Widdowson  Francis H. Chapelle  Catherine A. Kelly  John T. Novak 《Ground Water Monitoring & Remediation》2007,27(4):53-62

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Competitive Exclusion of Sulfate Reduction by Fe(lll)-Reducing Bacteria: A Mechanism for Producing Discrete Zones of High-Iron Ground Water     

Francis H. Chapelle  Derek R. Lovley 《Ground water》1992,30(1):29-36

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Exposure of amino acids and derivatives in the Earth orbit     

Bernard Barbier  Odile HeninFrançois Boillot  Annie ChabinDidier Chaput  André Brack 《Planetary and Space Science》2002,50(4):353-359

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