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1.
G. Diego Gatta Nicola Rotiroti Martin Fisch Milen Kadiyski Thomas Armbruster 《Physics and Chemistry of Minerals》2008,35(9):521-533
The elastic and structural behaviour of the synthetic zeolite CsAlSi5O12 (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V 0 = 1,155(4) Å3, K T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a 3, b 3, c 3) for the volume. The refined axial-EoS parameters are: a 0 = 16.701(44) Å, K T0a = 14(2) GPa (βa = 0.024(3) GPa?1), K′ a = 6.2(8) for the a-axis; b 0 = 13.778(20) Å, K T0b = 21(3) GPa (βb = 0.016(2) GPa?1), K′ b = 10(2) for the b-axis; c 0 = 5.018(7) Å, K T0c = 33(3) GPa (βc = 0.010(1) GPa?1), K′ c = 3.2(8) for the c-axis (K T0a:K T0b:K T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi5O12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi5O12 allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes. 相似文献
2.
Werner Lottermoser Karl Forcher Georg Amthauer Martin Kunz Thomas Armbruster 《Physics and Chemistry of Minerals》1997,24(1):2-6
Mössbauer measurements on neptunite (KNa2Li(Fe,Mn,Mg)2Ti2Si8O24) at 400?K reveal the distribution of Fe-ions on the crystallographic sites in agreement with neutron diffraction results published elsewhere. Even the previously postulated small amount of Fe-ions on the Ti(2) site has been detected, combined with a charge transfer which is in agreement with optical absorption investigations by other authors. A qualitative site occupation model is able to explain the different features of our observations. Single crystal Mössbauer measurements with the k-vector of incident γ-rays parallel to the crystallographic b-axis (space group Cc) of neptunite at different temperatures yield the angle β between the main component of the electric field gradient (EFG), V zz and b. This angle is in close accordance with a calculated value of β for the Fe(1) position from electron density maps. The latter also reveal an absolute value of V zz which is in satisfactory agreement with V zz derived from Mössbauer spectroscopy. 相似文献
3.
4.
Thomas Armbruster 《Physics and Chemistry of Minerals》1985,12(4):233-245
Ar, N2 and CO2 were introduced into the structural cavities of channel-evacuated single-crystals of White Well cordierite with the composition: K0.01Na0.03(Mg1.91Fe0.09Mn0.01)Al3.98Si5.01O18. The gas refilling experiments were carried out in conventional hydrothermal bombs at 6–7 kbar and 600–700°C. The increase in the mean refractive indices for gas-treated crystals, as determined with a spindle-stage equipped microscope, was used along with point-dipole calculations to estimate the percentage of occupied structural cavities. The steep increase of the electronic polarizability parallel to the a-axis, which can be derived from the increase of the refractive index n γ (Z∥a) upon introduction of volatiles, indicates that N2 and CO2 are preferentially aligned parallel to the a-axis of cordierite. Single-crystal structure refinements at room temperature confirm these predictions. Additionally, decreased C–O and N–N bond lengths suggest a librational motion with a mean rotary oscillation angle of 35° (N2) and 25° (CO2) about a, where c is the rotation axis. Mean libration angles of 40° (N2) and 28° (CO2) were estimated from the electronic polarizability tensors of CO2 and N2. Site occupancy refinements of the channel position are in good agreement with the optically derived values for the volatile concentrations, both indicating about 70% and 60% filled cavities for Ar- and N2-cordierite, respectively. Chemical analyses and point-dipole calculations confirm that about 45% of the cavities are occupied in the CO2-treated crystal. The structural framework of cordierite is slightly but specifically altered by the various channel occupants. 相似文献
5.
The most CO2-rich cordierite thus far encountered in nature with about 2.2 wt.% CO2 and 0.3 wt.% H2O occurs as large poikiloblasts in a strange non-foliated reaction rock that dissects well-foliated granulites being part of the classical Lapland granulite area described by Eskola. The cordierite is optically positive with the highest optic angle 2V
x (106°) and birefringence (– = 0.017) ever measured on natural cordierites, but it is also optically very heterogeneous due to secondary loss of CO2 along fractures and zones paralleling the fluid-bearing channels. Based on the optical properties of the degassed Lapland cordierite and on literature data a ternary diagram is given, which shows the variations of this cordierite in 2V
x and birefringence as a function of channel-filling with both CO2 and H2O.Following Losert (1971) the cordierite coexists with calcite, a thus far unique mineral assemblage that is probably only stable at very high CO2 pressures. In the present case, the
of the cordierite (0.75) indicates, on the basis of literature data, a coexisting fluid with
>0.95.The carbon isotope composition
13C of CO2 in cordierite lies near –7, that of the calcite is slightly lighter than about –9. Thus, at least for the CO2 in cordierite, a deep-seated origin may be possible.Based on the geologic occurrence it is speculated that the cordierite-bearing reaction rock could perhaps represent an annealed channel of late degassing in the granulitic lower crust. 相似文献
6.
V. V. Gurzhii A. A. Bessonov S. V. Krivovichev I. G. Tananaev T. Armbruster B. F. Myasoedov 《Geology of Ore Deposits》2009,51(8):833-837
A new potassium uranyl selenate compound K(UO2)(SeO4)(OH)(H2O) has been synthesized for the first time using the technique of evaporation from water solution. Its crystal structure has been solved by direct methods (monoclinic, P21/c,a = 8.0413(9) Å, b = 8.0362(9) Å, c = 11.6032(14) Å, β = 106.925(2)°, V = 717.34(14) Å3) and refined to R 1 = 0.0319 (wR 2 = 0.0824) for 1285 reflections with |F 0| > 4σ F . The structure consists of [(UO2(SeO4)(OH)(H2O)]? chains extending along axis b. In the chains, the uranyl pentagonal bipyramids are linked via bridged hydroxyl anions and tetrahedral oxoanions [SeO4]2?. Potassium ions are situated between these chains. No chains of that type have been observed in uranyl compounds earlier, but they had been detected in the structures of butlerite, parabutlerite, uklonskovite, fibroferrite, and a number of synthetic compounds. 相似文献
7.
Boudier Françoise Godard Marguerite Armbruster Catherine 《Marine Geophysical Researches》2000,21(3-4):307-326
The eastern end of the Haylayn massif exposes a complex paleoridge structure interpreted as the tip of a northwestward propagating segment (Nicolas et al., this issue). The area, revisited from a petrostructural and geochemical viewpoint, offers the most documented exposures of the association of olivine gabbros and gabbronorites in Oman (Juteau et al., 1988). Gabbronorites were injected while the main gabbro unit was deforming in the magmatic state. Both units do not differ chemically, except for the SiO2 enrichment of the orthopyroxene-rich gabbros relative to olivine-gabbro. In addition, they display the same trace element signature, which implies the same parent magma for both units. The extension of the stability field of orthopyroxene is assigned to increase of oxygen fugacity due to hydration. The source of hydration is the ridge axis hydrothermal circulation, suggesting hydrothermal/magma interaction at temperatures above the gabbro solidus. The distribution of gabbronorites at the scale of the entire ophiolite suggests a relation with ridge tectonics where high-T conditions of hydrothermal-magmatic interaction are met. Such conditions are met when propagating segments rotate the structures of the dying magma chamber. 相似文献
8.
G. Diego Gatta Nicola Rotiroti Martin Fisch Thomas Armbruster 《Physics and Chemistry of Minerals》2010,37(4):227-236
Elastic behavior and pressure-induced structural evolution of synthetic boron-mullite “Al5BO9” (a = 5.678(2) Å, b = 15.015(4) Å and c = 7.700(3) Å, space group Cmc21, Z = 4) were investigated up to 7.4 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase transition or anomalous compressional behavior occurred within the investigated P range. Fitting the P–V data with a truncated second-order (in energy) Birch-Murnaghan Equation-of-State (BM-EoS), using the data weighted by the uncertainties in P and V, we obtained: V 0 = 656.4(3) Å3 and K T0 = 165(7) GPa (β V0 = 0.0061(3) GPa?1). The evolution of the Eulerian finite strain versus normalized stress (f E–F E plot) leads to an almost horizontal trend, showing that a truncated second-order BM-EoS is appropriate to describe the elastic behavior of “Al5BO9” within the investigated P range. The weighted linear regression through the data points gives: F E(0) = 159(11) GPa. Axial compressibility coefficients yielded: β a = 1.4(2) × 10?3 GPa?1, β b = 3.4(4) × 10?3 GPa?1, and β c = 1.7(3) × 10?3 GPa?1 (β a :β b :β c = 1:2.43:1.21). The highest compressibilities observed in this study within (100) can be ascribed to the presence of voids represented by five-membered rings of polyhedra: Al1–Al3–Al4–Al1–Al3, which allow accommodating the effect of pressure by polyhedral tilting. Polyhedral tilting around the voids also explains the higher compressibility along [010] than along [001]. The stiffer crystallographic direction observed here might be controlled by the infinite chains of edge-sharing octahedra running along [100], which act as “pillars”, making the structure less compressible along the a-axis than along the b- and c-axis. Along [100], compression can only be accommodated by deformation of the edge-sharing octahedra (and/or by compression of the Al–O bond lengths), as no polyhedral tilting can occur. In addition, a comparative elastic analysis among the mullite-type materials is carried out. 相似文献
9.
Abstract With increasing high-quality geological and geophysical data it becomes clear that seismicity of the continents is characterized by linear patterns which are closely associated with tectonic features. The aim of this paper is to give reasonable interpretation for the earthquake distribution in the contiguous continent of the United States. Seismic lines and earthquake concentrated zones are defined, which reflect the characteristics of the continental seismotectonics. Similarities and differences in seismotectonics between the continental part of China and the contiguous continent of US are analysed. It is demonstrated that the spatial distribution of earthquakes can provide the information of the active structures in the earth's crust. The authors consider that the patterns of continental seismotectonics are not only controlled by the pre—existing tectonic frameworks and the current boundary dynamic conditions, but also possibly affected by dynamic factors of global tectonics at a higher level. 相似文献
10.
T. Arlt T. Armbruster R. Miletich P. Ulmer T. Peters 《Physics and Chemistry of Minerals》1998,26(2):100-106
Single crystals of the garnet Mn2+ 3Mn3+ 2[SiO4]3 and coesite were synthesised from MnO2-SiO2 oxide mixtures at 1000°C and 9 GPa in a multianvil press. The crystal structure of the garnet [space group Ia3¯d, a=11.801(2) Å] was refined at room temperature and 100 K from single-crystal X-ray data to R1=2.36% and R1=2.71%, respectively. In contrast to tetragonal Ca3Mn3+ 2[GeO4]3 (space group I41/a), the high-pressure garnet is cubic and does not display an ordered Jahn-Teller distortion of octahedral Mn3+. A disordered Jahn-Teller distortion either dynamic or static is evidenced by unusual high anisotropic displacement parameters. The room temperature structure is characterised by following bond lengths: Si-O=1.636(4) Å (tetrahedron), Mn3+-O=1.995 (4) Å (octahedron), Mn2+-O=2.280(5) and 2.409(4) Å (dodecahedron). The cubic structure was preserved upon cooling to 100 K [a=11.788(2) Å] and upon compressing up to 11.8 GPa in a diamond-anvil cell. Pressure variation of the unit cell parameter expressed by a third-order Birch-Murnaghan equation of state led to a bulk modulus K 0=151.6(8) GPa and its pressure derivatives K′=6.38(19). The peak positions of the Raman spectrum recorded for Mn2+ 3Mn3+ 2[SiO4]3 were assigned based on a calderite Mn2+ 3Fe3+ 2[SiO4]3 model extrapolated from andradite and grossular literature data. 相似文献