Atomistic simulation of Mg2SiO4 and Mg2GeO4 spinels: a new model     

M. Blanchard  K. Wright  J. D. Gale 《Physics and Chemistry of Minerals》2005,32(5-6):332-338

  相似文献   

The First Hop: Use of Beaufort Sea Deltas by Hatch-Year Semipalmated Sandpipers     

Roy T. Churchwell  Steve Kendall  Stephen C. Brown  Arny L. Blanchard  Tuula E. Hollmen  Abby N. Powell 《Estuaries and Coasts》2018,41(1):280-292

River deltas along Alaska’s Beaufort Sea coast are used by hatch-year semipalmated sandpipers (Calidris pusilla) after leaving their terrestrial natal sites, but the drivers of their use of these stopover sites on the first “hop” of fall migration are unknown. We quantified sandpiper temporal distribution and abundance as related to food resources at three river deltas during the beginning of their fall migration (post-breeding period) to compare the habitat quality among these deltas. We conducted population counts, sampled invertebrates, and captured birds to collect blood samples from individuals for triglyceride and stable isotope analyses to determine fattening rates and diet. Patterns of sandpiper and invertebrate abundance were complex and varied among deltas and within seasons. River deltas were used by sandpipers from late July to late August, and peak sandpiper counts ranged from 1000 to 4000 individuals, of which 98% were hatch-year semipalmated sandpipers. Isotopic signatures from blood plasma samples indicated that birds switched from a diet of upland tundra to delta invertebrate taxa as the migration season progressed, suggesting a dependence on delta invertebrates. Despite differences in diet among deltas, we found no differences in fattening rates of juvenile sandpipers as indicated by triglyceride levels. The number of sandpipers was positively associated with abundance of Amphipoda and Oligochaeta at the Jago and Okpilak-Hulahula deltas; an isotopic mixing model indicated that sandpipers consumed Amphipoda and Oligochaeta at Jago, mostly Chironomidae at Okpilak-Hulahula and Spionidae at Canning. Regardless of the difference in sandpiper diets at the Beaufort Sea deltas, their similar fattening rates throughout the season indicate that all of these stopover sites provide a critical food resource for hatch-year sandpipers beginning their first migration.  相似文献   

Can marine fisheries and aquaculture meet fish demand from a growing human population in a changing climate?     

Gorka Merino  Manuel Barange  Julia L. Blanchard  James Harle  Robert Holmes  Icarus Allen  Edward H. Allison  Marie Caroline Badjeck  Nicholas K. Dulvy  Jason Holt  Simon Jennings  Christian Mullon  Lynda D. Rodwell 《Global Environmental Change》2012,22(4):795-806

Expansion in the world's human population and economic development will increase future demand for fish products. As global fisheries yield is constrained by ecosystems productivity and management effectiveness, per capita fish consumption can only be maintained or increased if aquaculture makes an increasing contribution to the volume and stability of global fish supplies. Here, we use predictions of changes in global and regional climate (according to IPCC emissions scenario A1B), marine ecosystem and fisheries production estimates from high resolution regional models, human population size estimates from United Nations prospects, fishmeal and oil price estimations, and projections of the technological development in aquaculture feed technology, to investigate the feasibility of sustaining current and increased per capita fish consumption rates in 2050. We conclude that meeting current and larger consumption rates is feasible, despite a growing population and the impacts of climate change on potential fisheries production, but only if fish resources are managed sustainably and the animal feeds industry reduces its reliance on wild fish. Ineffective fisheries management and rising fishmeal prices driven by greater demand could, however, compromise future aquaculture production and the availability of fish products.  相似文献   

Major and trace elements in igneous rocks from apollo 15     

Philip A. Helmke  Douglas P. Blanchard  Larry A. Haskin  Karen Telander  Charles Weiss  Jeffrey W. Jacobs 《Earth, Moon, and Planets》1973,8(1-2):129-148

The concentrations of major and trace elements have been determined in igneous rocks from Apollo 15. All materials analyzed have typical depletions of Eu except for minerals separated from sample 15085. Four samples have concentrations of trace elements that are similar to those of KREEP. The samples of mare basalt from Apollo 15 have higher concentrations of FeO, MgO, Mn, and Cr and lower concentrations of CaO, Na₂O, K₂O, and rare-earth elements (REE) as compared to the samples of mare basalt from Apollos 11, 12, and 14. The samples can be divided into two groups on the basis of their normative compositions. One group is quartz normative and has low concentrations of FeO while the other is olivine normative and has high concentrations of FeO. The trace element data indicate that the samples of olivine normative basalt could be from different portions of a single lava flow. At least two and possible three parent magmas can be identified from the samples of the quartz normative group on the basis of their concentration ratios of Sm to Eu. Within each group, the compositions of the samples appear to be related by crystallization of olivine or pyroxene. Significant variations of the ratio of concentration of Sm to Eu cannot be produced without plagioclase-liquid equilibrium. The source material of mare basalt may be depleted in Eu. Alternatively, the magmas may have assimilated a small volume of material similar to KREEP.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.  相似文献   

Meteoroid ablation spheres from deep-sea sediments     

M.B. Blanchard  D.E. Brownlee  T.E. Bunch  P.W. Hodge  F.T. Kyte 《Earth and Planetary Science Letters》1980,46(2):178-190

We present analyses of spheres magnetically extracted from mid-Pacific abyssal clays 0–500,000 years old. The concentration of spheres >200 μm is a few times 10 ppb. The spheres were divided into three groups using their dominant mineralogy, and are named iron, glassy, and silicate. Most spheres were formed from particles that completely melted as they separated from their parent meteoroids during the ablation process. However, some of the silicate spheres contain relict grains of the parent meteoroids that did not experience any melting. Typically, these relict grains are olivine crystals whose cores are Mg-rich (Fo_89–99). Commonly the outer rims of these grains were altered during heating. Other relict mineral grains include enstatite, ferrous spinel, chromite, and pentlandite.The three groups of spheres may possibly indicate some genetic significance. It seems reasonable to expect iron-rich spheres to be produced during ablation of iron and metal-rich silicate meteoroids. Metal spheres are probably not produced by ablation of predominantly silicate meteoroids because studies of fusion crusts and laboratory ablated silicate materials have never yielded separate metal spheres, but rather have produced spheres with intergrown iron oxide and silicate phases. The iron spheres possess identical mineralogy with the fusion crusts of Boguslavka, Norfork, and N'Kandhla iron meteorites as well as with the ablation debris created in the laboratory using iron and nickel-iron samples.The glassy spheres are considerably more Fe-rich than the silicate spheres. They consist of magnetite and a Fe-rich glass which is relatively low in Si. Some of these spheres may have experienced pronounced volatile depletion during the ablation process and could have been derived from silicate or metal-rich silicate meteoroids.The silicate spheres are undoubtedly derived from ablation of stony meteoroids. Two of the mineral assemblages occurring in these spheres (olivine-magnetite-glass and sulfide) are identical to those described in the natural fusion crusts of Allende, Orgueil, and Murchison meteorites, laboratory-made ablation debris, and melted interplanetary dust collected from the stratosphere. Bulk compositions and relict grains are useful for determining the parent meteoroid types for the silicate spheres. Bulk analyses of spheres have non-volatile elemental abundances similar to chondritic abundances. Analyses of relict grains identified high-temperature minerals which often occur as larger crystals in a fine-grained matrix that is characterized by voids. These voids were caused by escaping volatiles as minerals decomposed during ablation. Because larger crystals of higher-temperature minerals are associated with fine-grained, low-temperature, volatile-rich matrix, the obvious candidates for parent meteoroids of the silicate spheres containing relict grains are carbonaceous chondrites.  相似文献   

Trace element distribution in mineral separates of the Allende inclusions and their genetic implications     

Hiroshi Nagasawa  Douglas P Blanchard  Jeffrey W Jacobs  Joyce C Brannon  John A Philpotts  Naoki Onuma 《Geochimica et cosmochimica acta》1977,41(11):1587-1600

Concentrations of the REE, Sc, Co, Fe, Zn, Ir, Na and Cr were determined by instrumental neutron activation and mass spectrometric isotope dilution analysis for mineral separates of the coarseand fine-grained types (group I and II of Martin and Mason's classification) of the Allende inclusions.These data, combined with data on mineral/liquid partition coefficients, oxygen isotope distributions and diffusion calculations, suggest the following: (1) Minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements. On the other hand, differences in oxygen isotope distributions among minerals preclude a totally molten stage in the history of the inclusion. Group I inclusions were formed by rapid condensation (either to liquid or solid) in a supercooled solar nebula; extrasolar pyroxene and spinel dust were included but not melted in the condensing inclusions, thus preserving their extrasolar oxygen isotope composition. REE were distributed by diffusion during the subsequent heating at subsolidus temperatures; because oxygen diffuses much more slowly at these temperatures, the oxygen isotope anomalies were preserved. (2) The fine-grained (group II) inclusions were also formed by condensation from a super-cooled nebular gas; however, REE-rich clinopyroxene and spinel were formed early and REE-poor sodalite and nepheline were formed later and mechanically mixed with clinopyroxene and spinel to form the inclusions. The REE patterns of the bulk inclusions and the mineral separates are fractionated, indicating that REE abundances in the gaseous phase were already fractionated at the time of condensation of the minerals. (3) Pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage thus resetting the ²⁶Al-²⁶Mg chronometer.  相似文献   

The effects of frequency-dependent quasar variability on the celestial reference frame     

Stanislav S. Shabala  Jonathan G. Rogers  Jamie N. McCallum  Oleg A. Titov  Jay Blanchard  James E. J. Lovell  Christopher S. Watson 《Journal of Geodesy》2014,88(6):575-586

We examine the relationship between source position stability and astrophysical properties of radio-loud quasars making up the International Celestial Reference Frame (ICRF2). Understanding this relationship is important for improving quasar selection and analysis strategies, and therefore reference frame stability. We construct flux density time series, known as light curves, for 95 of the most frequently observed ICRF2 quasars at both the 2.3 and 8.4 GHz geodetic very long baseline interferometry (VLBI) observing bands. Because the appearance of new quasar components corresponds to an increase in quasar flux density, these light curves alert us about potential changes in source structure before they appear in VLBI images. We test how source position stability depends on three astrophysical parameters: (1) flux density variability at X band; (2) time lag between flares in S and X bands; (3) spectral index root-mean-square (rms), defined as the variability in the ratio between S and X band flux densities. We find that the time lag between S and X band light curves provides a good indicator of position stability: sources with time lags $<$ 0.06 years are significantly more stable ( $>$ 20 % improvement in weighted rms) than sources with larger time lags. A similar improvement is obtained by observing sources with low $(<$ 0.12) spectral index variability. On the other hand, there is no strong dependence of source position stability on flux density variability in a single frequency band. These findings can be understood by interpreting the time lag between S and X band light curves as a measure of the size of the source structure. Monitoring of source flux density at multiple frequencies therefore appears to provide a useful probe of quasar structure on scales important to geodesy. The observed astrometric position of the brightest quasar component (the core) is known to depend on observing frequency. We show how multi-frequency flux density monitoring may allow the dependence on frequency of the relative core positions along the jet to be elucidated. Knowledge of the position–frequency relation has important implications for current and future geodetic VLBI programs, as well as the alignment between the radio and optical celestial reference frames.  相似文献   

Wilson Bentley's auroral observations     

S.M. Silverman  D.C. Blanchard 《Planetary and Space Science》1983,31(10):1131-1135

  相似文献   

Radar backscattering from artificially grown sea ice     

Bredow  J. Gogineni  S.P. Gow  A.J. Blanchard  P.F. Moore  R.K. 《Oceanic Engineering, IEEE Journal of》1989,14(3):259-264

Fine-resolution X-band backscatter measurements were made at the US Army Cold Region Research and Engineering Laboratory in Jan. 1987. Backscatter data were collected from unmodified smooth ice and snow-covered ice and from ice from which the snow had been removed (slightly roughened ice). The results indicate that vertically polarized returns were consistently higher than horizontally polarized echoes from both the slightly roughened and snow-covered saline ice. A 6.5-cm-thick dry snow layer altered the σ^o of the original smooth-surfaced saline ice only slightly, but introduced a noticeable volume scattering component. It is shown that although substantial agreement exists between the bare first-year ice measurements and commonly used surface-scatter model predictions, a complete model of first-year ice must include a volume-scatter contribution  相似文献   

Distribution,sediment magnetism and geochemistry of the Saksunarvatn (10 180 ± 60 cal. yr BP) tephra in marine,lake, and terrestrial sediments,northwest Iceland     

John T. Andrews  Aslaug Geirsdttir  Jrunn Hardardttir  Sarah Principato  Karl Grnvold  Grta B. Kristjansdttir  Gudrún Helgadttir  John Drexler  Arny Sveinbjrnsdttir 《第四纪科学杂志》2002,17(8):731-745

In 1997, seismic surveys in the troughs off northwest and north Iceland indicated the presence of a major, regional sub‐bottom reflector that can be traced over large areas of the shelf. Cores taken in 1997, and later in 1999 on the IMAGES V cruise, penetrated through the reflector. In core MD99‐2269 in Húnaflóaáll, this reflector is shown to be represented by a basaltic tephra with a geochemical signature and radiocarbon age correlative with the North Atlantic‐wide Saksunarvatn tephra. We trace this tephra throughout northwest Iceland in a series of marine and lake cores, as well as in terrestrial sediments; it forms a layer 1 to 25 cm thick of fine‐ to medium‐grained basaltic volcanic shards. The base of the tephra unit is always sharp but visual inspection and other measurements (carbonate and total organic carbon weight %) indicate a more diffuse upper boundary associated with bioturbation and with sediment reworking. Off northwest Iceland the Saksunarvatn tephra has distinct sediment magnetic properties. This is evident as a dramatic reduction in magnetic susceptibility, an increase in the frequency dependant magnetic susceptibility and ‘hard’ magnetisation in a −0.1T IRM backfield. Geochemical analyses from 11 sites indicate a tholeiitic basalt composition, similar to the geochemistry of a tephra found in the Greenland ice‐core that dates to 10 180 ± 60 cal. yr BP, and which was correlated with the 9000 ¹⁴C yr BP Saksunarvatn tephra. We present accelerator mass spectrometry ¹⁴C dates from the marine sites, which indicate that the ocean reservoir correction is close to ca. 400 yr at 9000 ¹⁴C yr BP off northwest Iceland. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献