Measurement and Interpretation of Low Levels of Dissolved Oxygen in Ground Water   总被引：1，自引：0，他引：1  

Art F. White  Maria L. Peterson  Ray D. Solbau 《Ground water》1990,28(4):584-590

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Chemical equilibrium and mass balance relationships associated with the Long Valley hydrothermal system, California, U.S.A.     

Art F. White  Maria L. Peterson 《Journal of Volcanology and Geothermal Research》1991,48(3-4)

Recent drilling and sampling of hydrothermal fluids from Long Valley permit an accurate characterization of chemical concentrations and equilibrium conditions in the hydrothermal reservoir. Hydrothermal fluids are thermodynamically saturated with secondary quartz, calcite, and pyrite but are in disequilibrium with respect to aqueous sulfide-sulfate speciation. Hydrothermal fluids are enriched in ¹⁸O by approximately 1‰ relative to recharge waters. ¹⁸O and Cl concentrations in well cuttings and core from high-temperature zones of the reservoir are extensively depleted relative to fresh rhyolitic tuff compositions. Approximately 80% of the Li and 50% of the B are retained in the altered reservoir rock. Cl mass balance and open-system ¹⁸O fractionation models produce similar water-rock ratios of between 1.0 and 2.5 kg kg⁻¹. These water-rock ratios coupled with estimates of reservoir porosity and density produce a minimum fluid residence time of 1.3 ka. The low fluid Cl concentrations in Long Valley correlate with corresponding low rock concentrations. Mass balance calculations indicate that leaching of these reservoir rocks accounts for Cl losses during hydrothermal activity over the last 40 ka.  相似文献   

Bootstrapped discrete scale invariance analysis of geomagnetic dipole intensity     

Art R. T. Jonkers 《Geophysical Journal International》2007,169(2):646-658

The technique of bootstrapped discrete scale invariance allows multiple time-series of different observables to be normalized in terms of observed and predicted characteristic timescales. A case study is presented using the SINT2000 time-series of virtual axial dipole moment, which spans the past 2 Myr. It is shown that this sequence not only bears a clear signature of a preferred timescale of about 55.6 Ka, but additionally predicts similar features (of shorter and longer duration) that are actually observed on the timescales of historical secular variation and dipole reversals, respectively. In turn, the latter two empirical sources both predict the characteristic timescale found in the dipole intensity sequence. These communal scaling characteristics suggest that a single underlying process could be driving dynamo fluctuations across all three observed timescales, from years to millions of years.  相似文献   

Sodium and potassium coprecipitation in aragonite     

Art F White 《Geochimica et cosmochimica acta》1977,41(5):613-625

The coprecipitation of Na and K was experimentally investigated in aragonite. The distribution functions were determined at pH 6.8 and 8.8 over aqueous Na and K concentrations of between 5 × 10^?4and 2.0 M and temperatures of between 25 and 75°C.The mole fractions of Na and K in aragonite are related to the aqueous ratios of Na and Ca by a function of the form where C₀ and C₁ are constants at a given temperature. This equation was derived by a statistical model assuming a heterogeneous energy distribution for the sites of incorporation. The independence of the coprecipitation process from aqueous anion activities suggests that carbonate is the only anionic species in the solid solution.  相似文献   

Mineralogy and geochemical behaviour during weathering of greenstone belt under tropical dry conditions in the extreme North Cameroon (Central Africa)     

Jean Pierre Nguetnkam  Fredéric Villiéras  Richard Kamga  Georges Emmanuel Ekodeck  Jacques Yvon 《Chemie der Erde / Geochemistry》2014

Mineralogy, major, trace and rare earth elements of a weathering profile developed on tertiary greenstone belt in the extreme North Cameroon are reported. The aim of which was to investigate mineralogical evolution and element mobilization and redistribution during weathering under dry tropical climate. The weathering profile consists of four main horizons: (1) a spheroidal weathering zone constituted by a corestone–shell complex, (2) a C horizon, (3) a Bw horizon and an Ah horizon. The results indicate that nontronite, a Fe-rich smectite, is the exclusive clay mineral formed in the exfoliated shells and the C horizon. It is associated with kaolinite in the upper horizons. The coexistence of these two clay minerals induced a decrease of CEC and pH which becomes neutral. The weathering index (WI) values reveal that weathering becomes more and more intensive from the corestone up to Bw horizon, which is the most weathered horizon in the weathering profile. Mass balance calculations, using Th as immobile element, indicate that Ti is quite mobile and that Al and Fe are relatively enriched at the bottom and strongly leached at the top of the profile. Alkalis and alkaline earth elements are strong leached through out the profile, except Ca which displays similar trend as Al and Fe. The same goes for LILE (Cs, Sr), TTE (Cr, Co, Ni) and HSFE (Y, Nb, Hf). In opposite, REE are depleted at the bottom and enriched in the upper horizons, with more enrichment for LREE than for HREE. It appears that weathering of greenstone belt causes a fractionation of HREE and induces a concentration of LREEs. Ce and Eu anomalies display opposite behaviour.  相似文献   

Bandwidth Effects in the 3G Photometric System     

Jokūbas Sūdžius  Vladas Vansevičius 《Astrophysics and Space Science》2002,280(1-2):63-66

Bandwidth effects in the GAIA photometric system 3G are discussed. It is demonstrated that careful account for the bandwidth effects in any proposed GAIA photometric system has to be made, in order to determine the fundamental parameters of heavily reddened stars. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Diffuse Interstellar Band at 862 nm as a Reddening Tracer for GAIA     

Arūnas Kučinskas  Vladas Vansevičius 《Astrophysics and Space Science》2002,280(1-2):119-124

We investigate the plausibility of using diffuse interstellar band at862 nm for tracing interstellar extinction with the ESA's astrometric space mission GAIA. For this purpose we perform numerical tests to simulate the conditions of real observations, covering a wide range of stellar parameters and different amounts of interstellar extinction. Our simulations indicate that with the present Radial Velocity Spectrometer setup the uncertainty in color excess of σ_E(B-V)≤ 0.05 can be achieved only for the interstellar reddening tracers brighter than V ∼ 13. None of the plausible tracers can provide accurate color excesses (σ _E(B-V) ≤ 0.05) at the distances beyond 2 kpc. We therefore conclude that with the currently planned instrumentation onboard GAIA this method can not be used as a stand-alone approach for probing interstellar extinction on the Galactic distance scales within the framework of the GAIA mission. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Surface area, porosity and water adsorption properties of fine volcanic ash particles   总被引：1，自引：1，他引：0  

Pierre Delmelle  Frédéric Villiéras  Manuel Pelletier 《Bulletin of Volcanology》2005,67(2):160-169

Our understanding on how ash particles in volcanic plumes react with coexisting gases and aerosols is still rudimentary, despite the importance of these reactions in influencing the chemistry and dynamics of a plume. In this study, six samples of fine ash (<100 m) from different volcanoes were measured for their specific surface area, a_s, porosity and water adsorption properties with the aim to provide insights into the capacity of silicate ash particles to react with gases, including water vapour. To do so, we performed high-resolution nitrogen and water vapour adsorption/desorption experiments at 77 K and 303 K, respectively. The nitrogen data indicated a_s values in the range 1.1–2.1 m²/g, except in one case where a a_s of 10 m²/g was measured. This high value is attributed to incorporation of hydrothermal phases, such as clay minerals, in the ash surface composition. The data also revealed that the ash samples are essentially non-porous, or have a porosity dominated by macropores with widths >500 Å. All the specimens had similar pore size distributions, with a small peak centered around 50 Å. These findings suggest that fine ash particles have relatively undifferentiated surface textures, irrespective of the chemical composition and eruption type. Adsorption isotherms for water vapour revealed that the capacity of the ash samples for water adsorption is systematically larger than predicted from the nitrogen adsorption a_s values. Enhanced reactivity of the ash surface towards water may result from (i) hydration of bulk ash constituents; (ii) hydration of surface compounds; and/or (iii) hydroxylation of the surface of the ash. The later mechanism may lead to irreversible retention of water. Based on these experiments, we predict that volcanic ash is covered by a complete monolayer of water under ambient atmospheric conditions. In addition, capillary condensation within ash pores should allow for deposition of condensed water on to ash particles before water reaches saturation in the plume. The total mass of water vapour retained by 1 g of fine ash at 0.95 relative water vapour pressure is calculated to be ~10^–2 g. Some volcanic implications of this study are discussed.Editorial responsibility: J. Gilbert  相似文献   

An experimental study of the solubility and speciation of the Rare Earth Elements (III) in fluoride- and chloride-bearing aqueous solutions at temperatures up to 300 °C     

Art. A. Migdisov  A.E. Williams-Jones  T. Wagner 《Geochimica et cosmochimica acta》2009,73(23):7087-7109

The solubility of REE(III) fluoride solids was determined in fluoride- and chloride-bearing solutions at 150, 200 and 250 °C and saturated water vapor pressure. These experimental data, together with experimental data from previously published studies, were used to evaluate formation constants for chloride- and fluoride-bearing aqueous species of the entire REE(III) group at temperatures up to 300 °C. The data show that the stability of these species differs significantly from that predicted theoretically. For example, contrary to the theoretical predictions, LREEF²⁺ species are more stable than HREEF²⁺ species at elevated temperature. The behavior of the chloride-bearing species is similar. Parameters for the Helgeson–Kirkham–Flowers (HKF) equation of state were determined for REEF²⁺, REECl²⁺ and REECl₂⁺ complexes using these experimental data and permit calculation of formation constants of these species at conditions not investigated experimentally. These data now permit the mobility of all REE in fluoride- and chloride-bearing hydrothermal systems to be reliably evaluated at intermediate temperatures and pressures.  相似文献