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1.
Hydrodynamic modeling can be used to spatially characterize water renewal rates in coastal ecosystems. Using a hydrodynamic model implemented over the semi-enclosed Southwest coral lagoon of New Caledonia, a recent study computed the flushing lag as the minimum time required for a particle coming from outside the lagoon (open ocean) to reach a specific station [Jouon, A., Douillet, P., Ouillon, S., Fraunié, P., 2006. Calculations of hydrodynamic time parameters in a semi-opened coastal zone using a 3D hydrodynamic model. Continental Shelf Research 26, 1395–1415]. Local e-flushing time was calculated as the time requested to reach a local grid mesh concentration of 1/e from the precedent step. Here we present an attempt to connect physical forcing to biogeochemical functioning of this coastal ecosystem. An array of stations, located in the lagoonal channel as well as in several bays under anthropogenic influence, was sampled during three cruises. We then tested the statistical relationships between the distribution of flushing indices and those of biological and chemical variables. Among the variables tested, silicate, chlorophyll a and bacterial biomass production present the highest correlations with flushing indices. Correlations are higher with local e-flushing times than with flushing lags or the sum of these two indices. In the bays, these variables often deviate from the relationships determined in the main lagoon channel. In the three bays receiving significant riverine inputs, silicate is well above the regression line, whereas data from the bay receiving almost insignificant freshwater inputs generally fit the lagoon channel regressions. Moreover, in the three bays receiving important urban and industrial effluents, chlorophyll a and bacterial production of biomass generally display values exceeding the lagoon channel regression trends whereas in the bay under moderate anthropogenic influence values follow the regressions obtained in the lagoon channel. The South West lagoon of New Caledonia can hence be viewed as a coastal mesotrophic ecosystem that is flushed by oligotrophic oceanic waters which subsequently replace the lagoonal waters with water considerably impoverished in resources for microbial growth. This flushing was high enough during the periods of study to influence the distribution of phytoplankton biomass, bacterial production of biomass and silicate concentrations in the lagoon channel as well as in some of the bay areas.  相似文献   
2.
This study reports on the behavior of two redox-sensitive elements, As and Sb, along the turbidity gradient in the freshwater reaches of the turbid Gironde Estuary. During a 17-month survey, surface water and suspended particulate matter (SPM) were sampled monthly at six sites representing both fluvial branches of the Gironde Estuary. Additionally, two longitudinal high resolution profiles were sampled along the fluvial estuary of the Garonne Branch during two contrasted seasons, i.e. with and without the presence of the maximum turbidity zone (MTZ). Seasonal variability and spatial distribution of dissolved (<0.2 μm; <0.02 μm) and particulate As, Sb and Fe were measured and combined with SPM data to understand metalloid behavior in the estuarine freshwater turbidity gradient.At the two main fluvial entries of the Gironde Estuary, dissolved As and Sb concentrations showed strong (by a factor of 2–4) seasonal variations, that were only partly controlled by discharge-related dilution. Seasonal addition of dissolved As and Sb was attributed to the degradation of particulate As and Sb carrier phases in bottom sediment and/or in the adjacent aquifers, rather than release from SPM. In the surface freshwater reaches of the Gironde Estuary, Sb behaved conservatively under all hydrological conditions. In contrast, As was strongly reactive in the presence of the MTZ, with opposite behaviors in the two fluvial branches of the estuary: in the Garonne Branch As was removed from the dissolved phase, whereas in the Dordogne Branch As was added. Redistribution of As between the dissolved and the particulate phases along the turbidity gradient in estuarine freshwater only affected the <0.02 μm fraction, as the 0.02–0.2 μm fraction remained constant (300 ng L−1 in September 2005). Accordingly, As removal seemed to be decoupled from concomitant “colloidal” (0.02–0.2 μm) Fe flocculation in the turbidity gradient. The contrasting behavior of dissolved As in the fluvial estuaries of the Garonne and Dordogne Branches was attributed to sorption processes during equilibration of river-borne dissolved As with estuarine SPM forming the MTZ. This equilibrium, described by a distinct distribution coefficient Kd(As)  11,000 L kg−1 in the MTZ, resulted in either As release (desorption; Dordogne Branch) or removal (adsorption; Garonne Branch) in the respective fluvial estuaries. A mixing experiment under controlled laboratory conditions tended to support that equilibration between the dissolved phase and MTZ particles may induce both As release and removal in the estuarine freshwater reaches, with As distribution evolving towards a distinct Kd value for increasing SPM concentrations. The long-term survey allowed estimating annual (2004) dissolved fluxes of As and, for the first time Sb, at the main fluvial entries of the Gironde Estuary at 30.7 t a−1 and 3.2 t a−1 (Garonne River) and at 8.0 t a−1 and 2.3 t a−1 (Dordogne River), respectively.  相似文献   
3.
Different missions have observed mesospheric clouds on Mars in the last years. The presence of these clouds implies, among other conditions, mesospheric temperatures below CO2 condensation temperature. We use a General Circulation Model to study the mesospheric temperatures and compare the observed distribution of the mesospheric clouds and the predicted climatology of mesospheric temperatures. Although the model does not usually predict temperatures below condensation for daytime conditions, in some regions the predicted temperatures are close enough to condensation that perturbations caused by small scale processes could produce local excursions below condensation. The location and time of the lowest temperatures predicted by the GCM correspond to a first order with the two observed populations of mesospheric clouds: equatorial clouds observed before and after the Northern summer solstice, and mid-latitude clouds observed around the Northern winter solstice. For the equatorial clouds season, the model predicts temperatures close to condensation at the longitude, latitude, altitude and local time where they have been observed. We find that the diurnal migrating thermal tide and non-migrating tides are at the root of the spatial confinement of the equatorial clouds. For the mid-latitude clouds season, the temperatures predicted by the model at the location of the observed clouds is too high. Stereo observations by two different instruments allow for the determination of the zonal speed of these clouds producing a rare dataset of mesospheric winds. We compare the mesospheric zonal winds predicted by the model with these observations, finding a good agreement, although in some cases the observed variability exceeds that predicted by the model.  相似文献   
4.
The 8-km2 Morcille catchment, which is a sub-catchment of the 150-km2 Ardières catchment in the Beaujolais region of France, is one of the first sites in Europe where research has been conducted on surface water contamination by pesticides. A consolidated hydrological and chemical dataset has been set up with data collected since 2002 on the Morcille River and since 2011 on the Ardières River. Additional data on the ecotoxicological and ecological impacts of pesticides on aquatic microbial communities and macroinvertebrates has also been recorded in both rivers since 2005. The ‘Site Atelier Ardières-Morcille Dataset’ described here combines rainfall and stream water height measurements at gauged stations with concentrations of two trace elements and nine pesticides (mainly herbicides, fungicides and some of their metabolites) in both the Ardières and Morcille rivers. All contaminant concentration data showed spatial and temporal variability in water quality associated with pesticide use and rainfall patterns. This long-term monitoring framework made it possible to estimate the persistence of two herbicides (diuron and norflurazon) after legislation banning them. It took 4 years for diuron and more than 10 years for norflurazon concentrations to fall below 0.1 μg/L. Concurrent biological data showed a gradient of impacts consistent with chemical anthropogenic pressure, and rapid recovery of phototrophic microbial communities after the diuron ban. Finally, monitoring data on pesticide transport in a grassed strip set on a slope of the Morcille catchment confirmed that vegetative filter strips can effectively reduce diuron fluxes in surface runoff (>80% abatement) and infiltration water (>70% abatement). The full dataset offers a valuable resource for the validation of hydrological models and the development of global approaches to better understand the pressure–transport–exposure–impact chain and aquatic community resilience at the small catchment scale.  相似文献   
5.
Radiative control of surface temperature is a key characteristic of the martian environment and its low-density atmosphere. Here we show through meteorological modeling that surface temperature can be far from radiative equilibrium over numerous sloping terrains on Mars, where nighttime mesoscale katabatic winds impact the surface energy budget. Katabatic circulations induce both adiabatic atmospheric heating and enhancement of downward sensible heat flux, which then becomes comparable to radiative flux and acts to warm the ground. Through this mechanism, surface temperature can increase up to 20 K. One consequence is that warm signatures of surface temperature over slopes, observed through infrared spectrometry, cannot be systematically associated with contrasts of intrinsic soil thermal inertia. Apparent thermal inertia maps retrieved thus far possibly contain wind-induced structures. Another consequence is that surface temperature observations close to sloping terrains could allow the validation of model predictions for martian katabatic winds, provided contrasts in intrinsic thermal inertia can be ruled out. The thermal impact of winds is mostly discussed in this paper in the particular cases of Olympus Mons/Lycus Sulci and Terra Meridiani but is generally significant over any sloped terrains in low thermal inertia areas. It is even general enough to apply under daytime conditions, thereby providing a possible explanation for observed afternoon surface cooling, and to ice-covered terrains, thereby providing new insights on how winds could have shaped the present surface of Mars.  相似文献   
6.
The south-west reef lagoon of New Caledonia is a semi-enclosed basin where, on first approximation, dominating sea state component corresponds to locally generated wind waves. This study aims to evaluate the ability of the wave model WAVEWATCH III to simulate wind wave distribution in this particular fetch-limited context, with a given parameterisation. In order to evaluate the consistency of the simulation results, wave parameters were measured in situ by a wave and tide recorder (WTR9 Aanderaa) and by an acoustic Doppler velocimeter (ADV Sontek). This study underlines specific constrains for the deployment of instruments to assess the characteristic parameters of low amplitude and high frequency wind-waves. Special care was taken in the comparison step as, on one hand the wave model did not simulate the propagation of low-frequency oceanic waves inside the lagoon, and on the other hand the measured spectra bear an intrinsic limitation for high frequencies. The approximation of a sea state dominated by wind waves is verified on the study site. The accuracy of the simulation results is discussed with regards to the wind forcing applied to the model.  相似文献   
7.
Understanding trace metal behaviour in estuarine environments requires sampling strategies and analytical methods adapted to strong physical and geochemical gradients. In this study, we present a specific sampling strategy covering a wide range of hydrological conditions during nine cruises in 2003–2007 to characterise the behaviour of three dissolved metals (uranium, vanadium and molybdenum) in surface and bottom water along the salinity gradient of the highly turbid macrotidal Gironde Estuary using a solid–liquid extraction. Uranium behaved conservatively whatever the water discharges observed. The slight dissolved U depletion compared to the theoretical dilution line between the fluvial and marine end-members occasionally observed in the low salinity range (0–3) was attributed to the mixing of different water bodies of the Gironde tributaries. In contrast, dissolved V behaviour was largely influenced by the hydrological conditions, showing increasingly pronounced addition with decreasing freshwater discharges, (i.e. increasing residence times of water and particles in the estuary). This addition of dissolved V in the low- to mid-salinity range was attributed to desorption processes observed in the Maximum Turbidity Zone (MTZ). The distribution of dissolved Mo concentrations along the salinity gradient was highly variable. Apparent conservative, and non-conservative behaviours were observed and were related to the concomitance of desorption from SPM, inputs from sediments for additive distribution and biological uptake and removal into sediments for subtractive distribution. Based on the whole database (2003–2007), annual net fluxes to the coastal ocean were estimated for dissolved U (15.5–16.6 t yr−1) and V (31.3–36.7 t yr−1).  相似文献   
8.
Dissolved Cd (CdD) concentrations along the salinity gradient were measured in surface water of the Gironde Estuary during 15 cruises (2001–2007), covering a wide range of contrasting situations in terms of hydrology, turbidity and season. During all situations dissolved Cd concentrations displayed maximum values in the mid-salinity range, reflecting Cd addition by chloride-induced desorption and complexation. The daily net CdD fluxes from the Gironde Estuary to the coastal ocean were estimated using Boyle's method. Extrapolating CdD concentrations in the high salinity range to the freshwater end member using a theoretical dilution line produced 15 theoretical Cd concentrations (CdD0), each representative of one distinct situation. The obtained CdD0 concentrations were relatively similar (201 ± 28 ng L−1) when freshwater discharge Q was >500 m3 s−1 (508 ≤ Q ≤ 2600 m3 s−1), but were highly variable (340 ± 80 ng L−1; 247–490 ng L−1) for low discharge situations (169 ≤ Q ≤ 368 m3 s−1). The respective daily CdD net fluxes were 5–39 kg day−1, mainly depending on freshwater discharge. As this observation invalidates the existing method of estimating annual CdD net fluxes, we proposed an empirical model, using representative CdD0 values and daily freshwater discharges for the 2001–2007 period. Subsequent integration produced reliable CdD net flux estimates for the Gironde Estuary at the annual timescale that ranged between 3.8–5.0 t a−1 in 2005 and 6.0–7.2 t a−1 in 2004, depending on freshwater discharge. Comparing CdD net fluxes with the incoming CdD fluxes suggested that the annual net CdD addition in the Gironde Estuary ranged from 3.5 to 6.7 t a−1, without any clear temporal trend during the past seven years. The annual CdD net fluxes did not show a clearly decreasing trend in spite of an overall decrease by a factor 6 in Cd gross fluxes during the past decade. Furthermore, in six years out of seven (except 2003), the annual CdD net fluxes even exceeded river borne total (dissolved + particulate) gross Cd fluxes into the estuary. These observations were attributed to progressive Cd desorption from both suspended particles and bottom sediment during various sedimentation–resuspension cycles induced by tidal currents and/or continuous dredging (navigation channel) and diverse intra-estuarine sources (wet deposition, urban sources, and agriculture). Provided that gross fluxes remain stable over time, dissolved Cd exportation from the Gironde Estuary to the coastal ocean may remain at the present level for the coming decade and the estuarine sedimentary Cd stock is forecast to decrease slowly.  相似文献   
9.
Incised-valley fills preserved within ancient coastal to shallow-marine successions represent important archives of environmental and sea-level change. Most current knowledge about the origin of incised valleys stems from Quaternary case studies; however, research on pre-Quaternary examples can shed light on valley formation and evolution across longer timespans. This article describes different types of incised-valley fills from Lower to Middle Pennsylvanian fluvio-deltaic successions of the Breathitt Group (eastern Kentucky), accumulated in the Central Appalachian Foreland under prevalent glacioeustatic forcing driven by Gondwanan glaciations. Based on well-established criteria for their recognition, numerous incised-valley fills were identified from outcrop and subsurface data through more than 300 m of clastic successions consisting of fourth-order stratigraphic sequences stacked into third-order composite sequences. Incised-valley fills were categorized into three archetypes based on lateral extent and aspect ratio (relatively wide versus narrow valley fills), nature of infill (fully continental versus mixed marine and continental facies associations) and relationships to underlying coal zones (truncating versus non-truncating). The systematic occurrence of each incised-valley fill type at specific stratigraphic positions within every third-order sequence suggests control by a periodic allogenic factor. Valley-fill archetypes are interpreted in terms of variable accommodation-supply ratios driven by variable duration of formative base-level cycles. For example, relatively wide incised-valley fills with alluvial infill evolved during long-lived cycles whose prolonged base-level drawdown maintained low accommodation/supply ratios. Deeper valleys with low aspect ratios and mixed marine-continental infills were generated by short-lived base-level drawdown that forced higher accommodation/supply ratios. Available chronological data for the studied successions consent to estimate base-level cycles spanning 104–5 years that were likely modulated by interference patterns of orbital parameters (obliquity and eccentricity) via global climate and glacioeustatic fluctuations. This conceptual model, relating incised-valley fill morphometry and internal architecture to orbital forcing patterns, provides a possible approach to predicting and interpreting incised-valley fill variability through successions accumulated during icehouse conditions.  相似文献   
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