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ICES baseline survey of trace metals in European shelf waters 总被引：1，自引：0，他引：1
Balls P.; Cofino W.; Schmidt D.; Topping G.; Wilson S.; Yeats P. 《ICES Journal of Marine Science》1993,50(4):435-444
2.
P.W. Balls 《Marine Chemistry》1985,15(4)
Cadmium, lead and copper have been determined in both dissolved and particulate phases for 130 surface-water samples from the coastal zone of Scotland and England in the western North Sea. The concentrations reported are, in general, lower than those published previously for the same area.The distribution of total metal concentration between the dissolved and particulate phases varies for the three elements. The lead distribution is dominated by its associations with particulate material while cadmium shows the reverse behaviour, existing almost totally in the dissolved phase. Copper is intermediate in behaviour, with the dissolved phase generally being dominant.An inverse relationship between salinity and dissolved copper concentration suggests a freshwater origin for this element. It is suggested that sedimentary and/or anthropogenic sources affect dissolved copper concentrations in coastal waters. The dissolved lead distribution reveals plumes of contaminated coastal water. The lead distribution is, however, dominated by associations with particulate material and sediments which produce a sharp concentration gradient close to the coast. The Humber estuary is identified as a significant source of cadmium to the North Sea. 相似文献
3.
P. W. Balls 《Estuarine, Coastal and Shelf Science》1985,20(6):717-728
Dissolved cadmium and copper concentrations have been determined in 76 surface water samples in coastal and ocean waters around Scotland by anodic stripping voltammetry (ASV). A trace metal/salinity ‘front’ is observed to the west, north and north-east of Scotland separating high salinity ocean water (>35 × 10−3) with low concentrations of dissolved Cd and Cu from lower salinity (<35 × 10−3) coastal water containing higher concentrations of Cd and Cu. Mean Cd concentrations in ocean and coastal waters are 7 ng dm−3 (0·06 n
) and 11 ng dm−3 (0·10 n
) respectively; for Cu the respective levels are 60 ng dm−3 (0·95 n
) and 170 ng dm−3 (2·68 n
). The observed distribution is attributed principally to freshwater runoff and the advection of contaminated Irish Sea water into the study area. 相似文献
4.
The differences and similarities between near-pristine estuaries of different latitudinal regions were examined by selecting three tropical systems from North Queensland, Australia (Jardine, Annan, Daintree) and three temperate systems from Scotland, United Kingdom (Inverness, Cromarty, Dornoch Firths) for comparison. Although estuaries from the different regions have a number of unifying features, such as salinity gradients, tidal variations and terrestrial inputs they also have a number of important differences. The most distinct of these is the timing and variability of the major physical forcings on the estuary (e.g., river flow, insolation). The three tropical estuaries were much more episodic than their temperate counterparts, with a much more dynamic salinity structure and more variable riverwater concentrations, so that delivery of material to the estuary is dominated by short-lived flood events. In contrast, seawater concentrations were more stable in the tropical estuaries due to a more constant input of insolation, resulting in year round biological activity. There was biological removal of dissolved inorganic phosphorus in the low salinity region of the tropical Jardine and Daintree estuaries and a low salinity input of nitrate in the tropical Annan estuary most likely due to nitrification in the bottom sediments, and the biological reaction zone in the tropical Annan Estuary was flushed out of the estuarine basin to the edge of the offshore plume during a flood. Similar effects were not seen in the temperate Inverness, Cromarty, and Dornoch Firths. Similarities between estuaries include mid-estuary inputs of ammonium which were seen in both the temperate and tropical estuaries, although they occur under vastly contrasting conditions of low river discharge and periods of flood, respectively. Five of the estuaries show a general increase in dissolved inorganic phosphorus concentrations towards the sea during low flows, reflecting their pristine condition, and all six estuaries had low salinity silicate maxima probably sourced from the dissolution of freshwater biogenic silicate that has been carried seaward, except in the tropical estuaries during the dry season when a benthic source is proposed. 相似文献
5.
P.W. Balls 《Marine pollution bulletin》1985,16(5):203-207
Cadmium, lead and copper have been determined in the dissolved and particulate phase for surface waters of the northern North Sea. Dissolved cadmium and copper show concentration gradients associated with salinity fronts which mark the boundary between coastal and ocean waters; lead does not. The particulate phase is shown to represent only a small fraction of the total metal concentration. Processes likely to be responsible for the observed distribution are discussed. 相似文献
6.
A one-dimensional salt intrusion model is used to investigate the hydrography of the Ythan estuary, a small shallow macrotidal estuary in the north-east of Scotland. The model simulates the longitudinal distributions of water level, salinity and total oxidized nitrogen (TON) in the estuary. The model employs upstream differencing and the Smolarkiewicz anti-diffusion scheme to avoid the numerical difficulties typically encountered when modelling strong tidal flows using centred differences. The physical mechanisms driving the simulations are the tide at the entrance to the estuary and freshwater discharge at the head. The model was calibrated against measurements of water level made at three locations in the estuary, salinity observations made at a central platform and axial salinity distributions. At both spring and neap tides, the full range of salinity observed at the central platform was simulated. However, at the midway stage between springs and neaps, the simulated peak salinity was less than that observed. This was probably due to the sensitivity of the model to the digitisation of the estuarine bathymetry.The model successfully simulated salinity distributions for periods of high and low river flow, and was used to illustrate how TON concentrations fluctuated in response to variations in river flow. The potential implications of variations in the bathymetry of the estuary on salinity and nutrient distributions were predicted to be slight. However, the four fold increase in riverine TON concentrations that has occurred over the past 30 years was shown to increase TON distributions along the entire length of the estuary. The calculated estuary flushing time was strongly dependent on river flow and varied between 11–60 h. 相似文献
7.
P.W. Balls 《Marine Chemistry》1985,17(4):363-378
Cadmium, lead and copper have been determined in both dissolved and particulate phases for 130 surface-water samples from the coastal zone of Scotland and England in the western North Sea. The concentrations reported are, in general, lower than those published previously for the same area.The distribution of total metal concentration between the dissolved and particulate phases varies for the three elements. The lead distribution is dominated by its associations with particulate material while cadmium shows the reverse behaviour, existing almost totally in the dissolved phase. Copper is intermediate in behaviour, with the dissolved phase generally being dominant.An inverse relationship between salinity and dissolved copper concentration suggests a freshwater origin for this element. It is suggested that sedimentary and/or anthropogenic sources affect dissolved copper concentrations in coastal waters. The dissolved lead distribution reveals plumes of contaminated coastal water. The lead distribution is, however, dominated by associations with particulate material and sediments which produce a sharp concentration gradient close to the coast. The Humber estuary is identified as a significant source of cadmium to the North Sea. 相似文献
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