Ultrahigh pressure macro diamonds from Copeton (New South Wales, Australia), based on Raman spectroscopy of inclusions   总被引：1，自引：0，他引：1  

L.M. Barron  B.J. Barron  T.P. Mernagh  W.D. Birch 《Ore Geology Reviews》2008,34(1-2):76

Mining of Cenozoic alluvial deposits at Copeton and Bingara (Eastern Australia) has produced two million macrodiamonds (0.25 ct median size). Raman spectroscopy is used to identify included minerals within uncut Copeton diamonds, with sealed chamber remnant pressures of 31.7 to 35.6 kbar for coesite, 13.6 and 22.7 kbar for clinopyroxene, and 7.6 kbar for grossular garnet. Assuming elastic behaviour, these values generate inclusion entrapment PT loci which intersect, restricting diamond formation conditions: from 250 °C, 43 kbar to 800 °C, 52 kbar. Larger than error (± 100 °C and ± 4 kbar), this range shows a systematic variation in inclusion composition with diamond zoning and N properties. Published research shows 1) Copeton and Bingara diamonds are unique, and 2) modern alluvium in the Bingara district carries mantle-formed garnet, captured by post-tectonic alkali basalt from an extensive diamondiferous ultrahigh pressure (UHP) terrane that stalled at depth because it is dominated by mafic eclogite. The combined Raman and geological results indicate two sets of subduction UHP diamond formation conditions/protolith are required, firstly cooler oceanic slab and secondly including higher temperature continental crust. The Copeton and Bingara stones are UHP macrodiamonds, and Carboniferous ⁴⁰Ar/³⁹Ar age dates on clinopyroxene inclusions should be interpreted as ages of crystallisation, representing the termination of subduction. The characteristic features of ruptured inclusions and etched percussion marks on Copeton and Bingara diamond indicate volcanic delivery to the earth's surface. Alluvial deposits elsewhere in Eastern Australia may carry similar diamond along with diamond of different origin.  相似文献   

Anthropogenic trace metals in sediment and settling particulate matter on a high-energy continental shelf (Sydney,Australia)     

Matthai C  Birch GF  Bickford GP 《Marine environmental research》2002,54(2):99-127

The anthropogenic contribution of trace metals to settling particulate matter (SPM) and surficial sediments was determined on the high-energy continental shelf adjacent to Sydney, Australia. Settling particulate matter and surficial sediment was collected in the vicinity of a major sewage outfall and at five control sites on the middle shelf (80-100 m water depth). Sediment traps were deployed on 10 occasions for up to 2 weeks during the summer and winter of 1995 and SPM was analyzed for Ag, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn. Cobalt, Fe, Mn and Ni act conservatively in SPM and in sediments regionally and are used as normalizing elements to determine anthropogenic enrichment. Surficial sediments and SPM are enriched in Ag, Cr, Cu, Pb and Zn near a major ocean outfall and at four of the five control sites, although sewage particles contribute < 5% of trace metals in the total sample. Silver is the most sensitive trace metal tracer for establishing the presence of sewage particulate matter. Sewage particulate matter flux near the outfall was estimated using a two end-member mixing model and is below 0.5 g m(-2) day(-1) during all deployment periods. The mean sewage particulate matter flux at sampling locations 30 km and 60 km north of the outfall are <0.13 g m(-2) day(-1) and <0.01 g m(-2) day(-1), respectively, indicating an efficient dispersal of anthropogenic material on this high energy continental shelf.  相似文献   

Distribution and possible sources of organochlorine residues in sediments of a large urban estuary,Port Jackson,Sydney     

G. F. Birch  S. E. Taylor 《Australian Journal of Earth Sciences》2013,60(4):749-756

Sydney Harbour is surrounded by a large capital city of about four million people and its highly urbanised (86%) catchment supports a substantial industrial base and an extensive transport infrastructure. Large commercial and naval ports occupy the waterway and the harbour is an important recreational area. Surficial sediment in Sydney Harbour contains high concentrations of PCBs, HCB, total chlordane, total DDT, aldrin, dieldrin, heptachlor and heptachlor‐epoxide, but low concentrations of lindane. PCBs, total chlordane, and to a lesser extent dieldrin, are most elevated in sediment in creeks on the southern shores of the harbour suggesting sources within older, highly urbanised/industrialised catchments of western‐central Sydney. There are high concentrations of total DDT and HCB in sediments of the upper harbour and Homebush Bay suggesting that chemical industries on the shores of the estuary in this area are sources of these contaminants. Although no sediment quality guidelines apply in Australia, empirically derived biological effects criteria suggest that sediment over extensive areas of Sydney Harbour may have an adverse impact on biota. Especially of concern are sediments containing high concentrations of chlordane and DDT.  相似文献   

The crystal structure of waylandite from Wheal Remfry, Cornwall, United Kingdom     

Stuart J. Mills  Anthony R. Kampf  Mati Raudsepp  William D. Birch 《Mineralogy and Petrology》2010,100(3-4):249-253

Sr- and Ca-rich waylandite, $ {\left( {{\hbox{B}}{{\hbox{i}}_{0.{54}}}{\hbox{S}}{{\hbox{r}}_{0.{31}}}{\hbox{C}}{{\hbox{a}}_{0.{25}}}{{\hbox{K}}_{0.0{1}}}{\hbox{B}}{{\hbox{a}}_{0.0{1}}}} \right)_{\Sigma 1.12}}{{\hbox{H}}_{0.{18}}}{\left( {{\hbox{A}}{{\hbox{l}}_{{2}.{96}}}{\hbox{C}}{{\hbox{u}}_{0.0{2}}}} \right)_{\Sigma 2.98}}{\left[ {{{\left( {{{\hbox{P}}_{0.{97}}}{{\hbox{S}}_{0.0{3}}}{\hbox{S}}{{\hbox{i}}_{0.0{1}}}} \right)}_{\Sigma 1.00}}{{\hbox{O}}_4}} \right]_2}{\left( {\hbox{OH}} \right)_6} $ , from Wheal Remfry, Cornwall, United Kingdom has been investigated by single-crystal X-ray diffraction and electron microprobe analyses. Waylandite crystallises in space group R $ \overline 3 $ ? m, with the cell parameters: a?=?7.0059(7) Å, c?=?16.3431(12) Å and V?=?694.69(11) ų. The crystal structure has been refined to R ₁?=?3.76%. Waylandite has an alunite-type structure comprised of a rhombohedral stacking of (001) composite layers of corner-shared AlO₆ octahedra and PO₄ tetrahedra, with (Bi,Sr,Ca) atoms occupying icosahedrally coordinated sites between the layers.  相似文献   

Propagating Linear Waves in Convectively Unstable Stellar Models: A Perturbative Approach     

E. Papini  L. Gizon  A. C. Birch 《Solar physics》2014,289(6):1919-1929

Linear time-domain simulations of acoustic oscillations are unstable in the stellar convection zone. To overcome this problem it is customary to compute the oscillations of a stabilized background stellar model. The stabilization affects the result, however. Here we propose to use a perturbative approach (running the simulation twice) to approximately recover the acoustic wave field while preserving seismic reciprocity. To test the method we considered a 1D standard solar model. We found that the mode frequencies of the (unstable) standard solar model are well approximated by the perturbative approach within 1 μHz for low-degree modes with frequencies near 3 mHz. We also show that the perturbative approach is appropriate for correcting rotational-frequency kernels. Finally, we comment that the method can be generalized to wave propagation in 3D magnetized stellar interiors because the magnetic fields have stabilizing effects on convection.  相似文献   

Human-induced change in sedimentary trace metals and phosphorus in Chaohu Lake,China, over the past half-millennium     

Enfeng Liu  Ji Shen  Gavin F. Birch  Xiangdong Yang  Yanhong Wu  Bin Xue 《Journal of Paleolimnology》2012,47(4):677-691

We present a sedimentary geochemical record of human perturbation in the watershed and related changes in trace metals (Cr, Ni, Zn and Pb), phosphorus and abundant rock-forming elements (Al, Fe, K, Mg, etc.) in Chaohu Lake over the past 500 years, a period spanning historical agricultural expansion and modern economic development. The record exhibited a stable terrestrial detrital input to Chaohu Lake before ca. 1540 AD, a period with less human perturbation of the watershed, which resulted in low and constant values of trace metals and phosphorus (TP) concentrations as well as Al, Fe, K, Mg, fine silt (<16 μm), the chemical index of alteration (CIA) and K/Na ratio. Two periods of successive marked increases in Al, Fe, K, Mg, fine silt, chemical index of alteration (CIA) and K/Na ratio occurred after ca. 1540 AD and 1950 AD. The former period apparently resulted from enhanced well-weathered topsoil erosion in the watershed related to the expansion of arable land, and the latter resulted from further enhancement of human perturbation in the watershed during the modern period. Concentrations of trace metals and TP were positively correlated with that of the rock-forming elements and fine silt. Trace metal pollution was limited during 1540–1950 AD, according to the low enrichment factors (EFs = 0.8–1.1), when an increase in trace metal concentrations was also linked to changes in detrital input. In addition to detrital regulation, pollution also contributed to an increase in TP concentrations (average EF 1.4) during 1540–1950 AD and the average accumulation rate of anthropogenic phosphorus was 87.3 mg m⁻² a⁻¹. Anthropogenic phosphorus increased further and Pb and Zn pollution also occurred after 1950 AD, reaching maximum values after 1980 AD, when the average accumulation rates of anthropogenic Zn, Pb and phosphorus (mainly in the form of NaOH-P) were 242.2, 43.3 and 811.8 mg m⁻² a⁻¹, respectively. The increase in phosphorus pollution in recent decades is probably from the domestic sewage sources of Hefei City and non-point sources related to agricultural utilization of commercial fertilizer, whereas Zn and Pb pollution is probably derived mainly from industrial sources of Hefei City, as deduced from their spatial variations in the sediments of the river mouths.  相似文献   

High-Resolution Mapping of Flows in the Solar Interior: Fully Consistent OLA Inversion of Helioseismic Travel Times     

J. Jackiewicz  L. Gizon  A. C. Birch 《Solar physics》2008,251(1-2):381-415

To recover the flow information encoded in travel-time data of time?–?distance helioseismology, accurate forward modeling and a robust inversion of the travel times are required. We accomplish this using three-dimensional finite-frequency travel-time sensitivity kernels for flows along with a (2+1)-dimensional (2+1D) optimally localized averaging (OLA) inversion scheme. Travel times are measured by ridge filtering MDI full-disk Doppler data and the corresponding Born sensitivity kernels are computed for these particular travel times. We also utilize the full noise-covariance properties of the travel times, which allow us to accurately estimate the errors for all inversions. The whole procedure is thus fully consistent. Because of ridge filtering, the kernel functions separate in the horizontal and vertical directions, motivating our choice of a 2+1D inversion implementation. The inversion procedure also minimizes cross-talk effects among the three flow components, and the averaging kernels resulting from the inversion show very small amounts of cross-talk. We obtain three-dimensional maps of vector solar flows in the quiet Sun at horizontal spatial resolutions of 7?10 Mm using generally 24 hours of data. For all of the flow maps we provide averaging kernels and the noise estimates. We present examples to test the inferred flows, such as a comparison with Doppler data, in which we find a correlation of 0.9. We also present results for quiet-Sun supergranular flows at different depths in the upper convection zone. Our estimation of the vertical velocity shows good qualitative agreement with the horizontal vector flows. We also show vertical flows measured solely from f-mode travel times. In addition, we demonstrate how to directly invert for the horizontal divergence and flow vorticity. Finally we study inferred flow-map correlations at different depths and find a rapid decrease in this correlation with depth, consistent with other recent local helioseismic analyses.  相似文献   

A search for posteclipse brightening of Io in 1973. I     

R.L. Millis  D.T. Thompson  B.J. Harris  P. Birch  R. Sefton 《Icarus》1974,23(3):425-430

Eight eclipse reappearances of the innermost Galilean satellite, Io, were observed during the fall of 1973. The measurements were made using photometers specially designed to cope with the problem of scattered light from Jupiter. Posteclipse brightening of Io was not detected and, if present, was less than our estimated detection threshold of about 0.02 mag.  相似文献   

Composition of the Earth's Mantle     

Francis Birch 《Geophysical Journal International》1937,4(S1):295-311

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A nephrite deposit in the great serpentine belt of New South Wales     

J. J. Hockley  W. D. Birch  H. K. Worner 《Australian Journal of Earth Sciences》2013,60(5-6):249-254

A nephrite jade deposit within the Great Serpentine Belt of N.S.W., near Tamworth, occurs as several tabular bodies up to 3.5 m thick on the serpentinite country‐rock contact. The occurrence is interpreted as a low‐temperature reaction zone, similar to those observed around Alpine serpentinites elsewhere. The nephrite probably formed as a result of dynamothermal metasomatism associated with the emplacement of serpentinites along the Peel Fault.  相似文献