Stable nonlinear methods for sensor array processing;     

Byrne  C. Steele  A. 《Oceanic Engineering, IEEE Journal of》1985,10(3):255-259

Most nonlinear high-resolution bearing estimators are unstable in the presence of correlated noise, system phase errors, and multipath arrivals because they inadvertently place too much emphasis on unstable eigenvectors of the cross-sensor correlation matrix. For moderately correlated noise there will be sufficiently many stable eigenvectors to resolve and localize discrete sources. A method is given (the "stable nonlinear method" or SNLM) whereby reweighting of the eigenvectors is achieved implicitly, without actual calculation of the eigenvectors. This SNLM is compared with Capon's maximum likelihood method (MLM) in simulations of correlated noise, partially correlated signals, and phase errors, and is shown to provide good stability in the cases considered.  相似文献   

Solubility of hydrous ferric oxide and iron speciation in seawater     

Robert H. Byrne  Dana R. Kester 《Marine Chemistry》1976,4(3):255-274

Iron solubility equilibria were investigated in seawater at 36.22‰ salinity and 25°C using several filtration and dialysis techniques. In simple filtration experiments with 0.05 μm filters and Millipore ultra-filters, ferric chlorides fluorides, sulfates, and FeOH²⁺ species were found to be insignificant relative to Fe(OH)₂⁺ at p[H⁺] = ?log [H⁺] greater than 6.0. Hydrous ferric oxide freshly precipitated from seawater yielded a solubility product of ${}^1\text{K}{}_{\mathrm{<mtext>so</mtext>}}\text{=}\text{[Fe}{}^{\mathrm{3+}}\text{][H}{}^{\mathrm{+}}\text{]}{}^{\mathrm{?3}}\text{= 4.7 · 10}{}^5$. Solubility studies based on the rates of dialysis of various seawater solutions and on the filtration of acidified seawater solutions indicated the existence of the Fe(OH)₃⁰ species. The formation constant for this species can be calculated as ${}^1\text{β}{}_3\text{=}\text{[Fe(OH)}{}_3{}^0\text{] [H}{}^{\mathrm{+}}\text{]}{}^3\text{/[Fe}{}^{\mathrm{3+}}\text{] = 2.4 · 10}{}^{\mathrm{?14}}$. The Fe(OH)₄^? species is present at concentrations which are negligible compared to Fe(OH)₂⁺ and Fe(OH)₃⁰ in the normal pH range of seawater. However, there is at least one other significant ferric complex in seawater above p[H⁺] = 8.0 (possibly with bicarbonate, carbonate, or borate ions) in addition to the Fe(OH)₂⁺ and Fe(OH)₃⁰ species.  相似文献   

A permanent seismic station beneath the Ocean Bottom     

David Harris  Robert K. Cessaro  Fred K. Duennebier  David A. Byrne 《Marine Geophysical Researches》1987,9(1):67-94

The Hawaii Institute of Geophysics began development of the Ocean Subbottom Seisometer (OSS) system in 1978, and OSS systems were installed in four locations between 1979 and 1982. The OSS system is a permanent, deep ocean borehole seismic recording system composed of a borehole sensor package (tool), an electromechanical cable, recorder package, and recovery system. Installed near the bottom of a borehole (drilled by the D/V Glomar Challenger), the tool contains three orthogonal, 4.5-Hz geophones, two orthogonal tilt meters; and a temperature sensor. Signals from these sensors are multiplexed, digitized (with a floating point technique), and telemetered through approximately 10 km of electromechanical cable to a recorder package located near the ocean bottom. Electrical power for the tool is supplied from the recorder package. The digital seismic signals are demultiplexed, converted back to analog form, processed through an automatic gain control (AGC) circuit, and recorded along with a time code on magnetic tape cassettes in the recorder package. Data may be recorded continuously for up to two months in the self-contained recorder package. Data may also be recorded in real time (digital formal) during the installation and subsequent recorder package servicing. The recorder package is connected to a submerged recovery buoy by a length of bouyant polypropylene rope. The anchor on the recovery buoy is released by activating either of the acoustical command releases. The polypropylene rope may also be seized with a grappling hook to effect recovery. The recorder package may be repeatedly serviced as long as the tool remains functionalA wide range of data has been recovered from the OSS system. Recovered analog records include signals from natural seismic sources such as earthquakes (teleseismic and local), man-made seismic sources such as refraction seismic shooting (explosives and air cannons), and nuclear tests. Lengthy continuous recording has permitted analysis of wideband noise levels, and the slowly varying parameters, temperature and tilt.Hawaii Institute of Geophysics Contribution 1909.  相似文献   

A simple shaker table for seismometer calibration   总被引：1，自引：0，他引：1  

Frederick K. Duennebier  George H. Sutton  David Harris  David A. Byrne 《Marine Geophysical Researches》1984,6(3):311-328

A unique and simple shaker table (shake table or shaking table), designed, constructed, and installed at the Hawaii Institute of Geophysics, has proven to be a valuable aid in testing and calibrating short period seismometers, as well as ocean bottom and ocean sub-bottom seismometer/tilt meter packages. It consists of a platform suspended in a stairwell by a single elastic cord (10 m extended length) driven by GeoSpace HS-10 geophones. Platform motion is monitored by orthogonal reference geophones and tilt meters. The relatively low natural periods of the platform, about 1.9 sec vertical and 6.5 sec horizontal, provide sufficient isolation from local vibrations that calibration can be made near operational amplitudes. Vertical or horizontal driver geophones can be driven by a commercial signal generator or white noise generator, or from magnetic tape output. The table can also be tilted with respect to the drivers to determine tilt tolerances and to calibrate tilt meters. A Hewlett-Packard 3582-A spectrum analyzer, used to analyze both reference and output signals, provides near real-time system cabibration and is an efficient means for investigating parasitic system resonances. The analyzer can also provide a white noise signal source to the driver geophones.Hawaii Institute of Geophysics Contribution 1443.  相似文献   

Inorganic speciation of dissolved elements in seawater: the influence of pH on concentration ratios     

Robert H Byrne 《Geochemical transactions》2002,3(1):11-6

Assessments of inorganic elemental speciation in seawater span the past four decades. Experimentation, compilation and critical review of equilibrium data over the past forty years have, in particular, considerably improved our understanding of cation hydrolysis and the complexation of cations by carbonate ions in solution. Through experimental investigations and critical evaluation it is now known that more than forty elements have seawater speciation schemes that are strongly influenced by pH. In the present work, the speciation of the elements in seawater is summarized in a manner that highlights the significance of pH variations. For elements that have pH-dependent species concentration ratios, this work summarizes equilibrium data (S = 35, t = 25°C) that can be used to assess regions of dominance and relative species concentrations. Concentration ratios of complex species are expressed in the form log[A]/[B] = pH - C where brackets denote species concentrations in solution, A and B are species important at higher (A) and lower (B) solution pH, and C is a constant dependent on salinity, temperature and pressure. In the case of equilibria involving complex oxy-anions (MO _x (OH) _y ) or hydroxy complexes (M(OH) _n ), C is written as pK _n = -log K _n or pK _n * = -log K _n * respectively, where K _n and K _n * are equilibrium constants. For equilibria involving carbonate complexation, the constant C is written as pQ = -log(K ₂ ^l K _n [HCO₃ ^-]) where K ₂ ^l is the HCO₃ ^- dissociation constant, K _n is a cation complexation constant and [HCO₃ ^-] is approximated as 1.9 × 10^-3 molar. Equilibrium data expressed in this manner clearly show dominant species transitions, ranges of dominance, and relative concentrations at any pH.  相似文献   

Determination of _SO4β₁ for yttrium and the rare earth elements at I = 0.66 m and t = 25°C—implications for YREE solution speciation in sulfate-rich waters     

Johan Schijf  Robert H. Byrne 《Geochimica et cosmochimica acta》2004,68(13):2825-2837

We present a complete set of stability constants (_SO4β₁) for the monosulfato-complexes of yttrium and the rare earth elements (YREE), except Pm, at I = 0.66 m and t = 25°C, where _SO4β₁ = [MSO₄⁺] × [M³⁺]⁻¹[SO₄²⁻]⁻¹ (M ≡ YREE and brackets indicate free ion concentrations on the molal scale). Stability constants were determined by investigating the solubility of BaSO₄ in concentrated aqueous solutions of MCl₃. This is the first complete set to be published in more than 30 years.The resulting _SO4β₁ pattern is very similar in shape to one reported by de Carvalho and Choppin (1967a) (I = 2 mol/L; t = 25°C) that has been largely ignored. Stability constants vary little between La and Sm, but display a weak maximum at Eu. Between Eu and Lu, _SO4β₁ decreases by 0.2 log units, substantially exceeding the ±0.02 log unit average analytical precision. The stability constant for Y is approximately equal to that for Er. Our _SO4β₁ pattern is consequently distinctly different from the consensus pattern, based on a single data set from 1954, which is essentially flat, with a range of only 0.07 log units between the lowest and highest _SO4β₁ values within the lanthanide series (excluding Y).Values of _SO4β₁ obtained in this work, in conjunction with the ion-pairing model of Millero and Schreiber (1982), allow prediction of _SO4β₁ between 0 and 1 m ionic strength. These results are used to assess both the absolute and relative extent of YREE sulfate complexation in acidic, sulfate-rich waters.  相似文献   

Copper(II) carbonate complexation in seawater     

Robert H. Byrne  William L. Miller 《Geochimica et cosmochimica acta》1985,49(8):1837-1844

Cupric carbonate and cupric bicarbonate complexation constants were determined in natural seawater and in a variety of synthetic media. The formation constants of CuHCO₃⁺, CuCO₃⁰ and Cu(CO₃)₂^2? at 25°C and zero ionic strength are: log β_H⁰ = 1.8, log β₁⁰ = 6.82 and log β⁰₂ = 10.6. Formation constants of these species appropriate to 0.7 molar ionic strength and 25°C are log β_H ～- 1, log β₁ = 5.73, log β₂ = 9.3. Our results indicate that the inorganic speciation scheme of Cu(II) in seawater is dominated by CuCO₃⁰ and that the ternary species, CuCO₃OH^?, is of substantial importance.  相似文献   

Use of Pitzer's equations to determine the media effect on the formation of lead chloro complexes     

Frank.J. Millero  Robert H. Byrne 《Geochimica et cosmochimica acta》1984,48(5):1145-1150

The spectrophotometric measurements of chloro complexes of lead in aqueous HCl, NaCl, MgCl₂ and CaCl₂ solutions at 25°C have been analyzed using Pitzer's specific interaction equations. Parameters for activity coefficients of the complexes PbCl⁺, PbCl₂⁰ and PbCl₃^? have been determined for the various media. Values of $\text{K}{}_1\text{= 30.0 ± 0.6}$, $\text{K}{}_2\text{= 106.7 ± 2.1}$ and $\text{K}{}_3\text{= 73.0 ± 1.5}$ were obtained for the cumulative formation constants. [$\text{Pb}{}^{\mathrm{2+}}\text{+ nCl}{}^{\mathrm{?}}\text{→ PbCl}{}_{\mathrm{n}}{}^{\mathrm{2?n}}\text{)}$]. These values are in reasonable agreement with literature data. The Pitzer parameters for the PbCl ion pairs in various media were used to calculate the speciation of Pb²⁺ in an artificial seawater solution.  相似文献   

Thermal evolution of the Tertiary Shimanto Belt, Muroto Peninsula, Shikoku, Japan     

Michael B.  Underwood  Matthew M.  Laughland  Tim  Byrne  J. P. Hibbard  Lee  DiTullio 《Island Arc》1992,1(1):116-132

Abstract The Shimanto accretionary complex on the Muroto Peninsula of Shikoku comprises two major units of Tertiary strata: the Murotohanto Sub-belt (Eocene-Oligocene) and the Nabae Sub-belt (Oligocene-Miocene). Both sub-belts have been affected by thermal overprints following the peak of accretion-related deformation. Palaeotemperatures for the entire Tertiary section range from ～ 140 to 315°C, based upon mean vitrinite reflectance values of 0.9–5.0%R_m. Values of illite crystallinity index are consistent with conditions of advanced diagenesis and anchimetamorphism. Illite/mica b₀ lattice dimensions indicate that burial pressures were probably no greater than 2.5kbar. In general, levels of thermal maturity are higher for the Murotohanto Sub-belt than for the Nabae Sub-belt. The Eocene-Oligocene strata also display a spatial decrease in thermal maturity from south to north and this pattern probably was caused by regional-scale differential uplift following peak heating. Conversely, the palaeothermal structure within the Nabae Sub-belt is fairly uniform, except for the local effects of mafic intrusions at the tip of Cape Muroto. There is a paleotemperature difference of ～ 90°C across the boundary between the Murotohanto and Nabae Sub-belts (Shiina-Narashi fault), and this contrast is consistent with approximately 1200 m of post-metamorphic vertical offset. Subduction prior to Middle Miocene probably involved the Kula or fused Kula-Pacific plate and the background geothermal gradient during the Eocene-Oligocene phase of accretion was ～ 30–35°C/km. Rapid heating of the Shimanto Belt evidently occurred immediately after a Middle Miocene reorganization of the subduction boundary. Hot oceanic lithosphere from the Shikoku Basin first entered the subduction zone at ～ 15 Ma; this event also coincided with the opening of the Sea of Japan and the rapid clockwise rotation of southwest Japan. The background geothermal gradient at that time was ～ 70°C/km. Whether or not all portions of the inherited (Eocene-Oligocene) palaeothermal structure were overprinted during the Middle Miocene remains controversial.  相似文献   

A Coupled Riverine-Marine Fractionation Model for Dissolved Rare Earths and Yttrium     

Robert H. Byrne  Xuewu Liu 《Aquatic Geochemistry》1998,4(1):103-121

Fractionation of yttrium (Y) and the rare earth elements (REEs) begins in riverine systems and continues in estuaries and the ocean. Models of yttrium and rare earth (YREE) distributions in seawater must therefore consider the fractionation of these elements in both marine and riverine systems. In this work we develop a coupled riverine/marine fractionation model for dissolved rare earths and yttrium, and apply this model to calculations of marine YREE fractionation for a simple two-box (riverine/marine) geochemical system. Shale-normalized YREE concentrations in seawater can be expressed in terms of fractionation factors ( _ij ) appropriate to riverine environments ( ) and seawater ( ): where and are input-normalized total metal concentrations in seawater and is the ratio of total dissolved Y in riverwater before and after commencement of riverine metal scavenging processes. The fractionation factors ( _ij ) are calculated relative to the reference element, yttrium, and reflect a balance between solution and surface complexation of the rare earths and yttrium.  相似文献