An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting   总被引：1，自引：0，他引：1  

Mauro Lo Cascio  Yan Liang  Nobumichi Shimizu  Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

The soilmodels.info project   总被引：1，自引：0，他引：1  

Gerd Gudehus  Angelo Amorosi  Antonio Gens  Ivo Herle  Dimitrios Kolymbas  David Mašín  David Muir Wood  Andrzej Niemunis  Roberto Nova  Manuel Pastor  Claudio Tamagnini  Gioacchino Viggiani 《国际地质力学数值与分析法杂志》2008,32(12):1571-1572

  相似文献   

Southern elephant seal trajectories, fronts and eddies in the Brazil/Malvinas Confluence     

Claudio Campagna  Alberto R. Piola  Maria Rosa Marin  Mirtha Lewis  Teresita Fernndez 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1907-1924

This study describes the association between transient, mesoscale hydrographic features along the axis of the Brazil–Malvinas Confluence, in the SW Atlantic, and the foraging behavior of 2–3-year-old (focal) juvenile southern elephant seals, Mirounga leonina, from Península Valdés, Argentina. Departing from the dominant pattern of foraging on predictable bathymetric fronts on the Patagonian shelf and slope, three females out of 12 satellite-tracked juveniles remained at the edge of young warm-core eddies and near the outer core of cold-core eddies, coinciding with the most productive areas of these temperature fronts. Seal trajectories along high-temperature gradients were always consistent with the speed and direction of surface currents inferred from the temperature distribution and confirmed by surface drifters. Movements of foraging seals were compared with those of surface drifters, coinciding in time and space and yielding independent and consistent data on regional water circulation parameters. The diving pattern recorded for one focal seal yielded shallower dives and a loose diel pattern in the eddy, and a marked diurnal cycle compatible with foraging on vertically migrating prey in the cold waters of the Malvinas Current. Pre-reproductive females that use the mesoscale fronts of the Argentine Basin as an alternative foraging area would benefit from lower competition with more experienced seals and with other top predators that reproduce along the coast of Patagonia.  相似文献   

Estimation of winds over the sea from land-based measurements     

Jen-Men Lo  N. Al-Madani  M. A. Tayfun  D. Al-Ajmi 《Ocean Engineering》1994,21(7)

Simultaneous measurements of wind velocities at two different sites, one over the sea and the other over land, can differ substantially and therefore cannot be interchanged. In situations where the wind data at an offshore site are missing while simultaneous measurements from a land-based station exist, a linear mean-square estimation (LMSE) technique can be used to estimate the missing data. This technique relies on past wind data gathered simultaneously at the two locations, and it generates from the associated correlation a set of four transfer functions capable of predicting one data set from the other. In the present case, the LMSE technique is outlined briefly, and is then applied to construct seasonal transfer functions between a land-based station and two coastal/offshore sites in Kuwait. Comparisons between the actually observed wind characteristics and those predicted by the LMSE technique are favorable, and thus tend to confirm the applicability of the technique under appropriate conditions.  相似文献   

Effect of shallow and narrow water on added mass of cylinders with various cross-sectional shapes     

Z.X. Zhou  Edmond Y.M. Lo  S.K. Tan 《Ocean Engineering》2005,32(10):1199-1215

The sway, heave and roll added masses of three uniform cylinders with semi-circular, rectangular and triangular cross-sectional shapes in shallow and narrow water are numerically analysed. The method is based on simulation of the potential flow induced by the cylinder's mode of motion. The effects of shallow and narrow water on added mass are analysed and presented. It is concluded that the shallow and narrow water effects on added mass depend on the different cross-section shapes of the cylinders. In particular, the water depth effect on sway added mass is stronger than that on heave added mass while the narrow water effect on sway is weaker than that on heave. The shallow water effect on added mass tends to weaken the narrow water effect. Lastly the effect of shallow and narrow water on added mass on a rectangular cylinder is the strongest while that on a triangular cylinder is the weakest.  相似文献   

Assumption and elimination of trace elements in Adélie penguins from Antarctica: a preliminary study     

Ancora S  Volpi V  Olmastroni S  Focardi S  Leonzio C 《Marine environmental research》2002,54(3-5):341-344

The concentration and distribution of some trace elements were determined in stomach contents, excreta and feathers of Adélie penguins (Pygoscelis adeliae) breeding at Edmonson Point (Terra Nova Bay-Antarctica). In these materials obtained by non-destructive methods, concentrations of mercury, cadmium and lead measured were used to establish natural levels of these metals in the penguins' diet. An intake-excretion hypothesis was formulated.  相似文献   

Effects of crab–halophytic plant interactions on creek growth in a S.W. Atlantic salt marsh: A Cellular Automata model     

Darío R. Minkoff  Mauricio Escapa  Flix E. Ferramola  Silvio D. Maraschín  Jorge O. Pierini  Gerardo M.E. Perillo  Claudio Delrieux 《Estuarine, Coastal and Shelf Science》2006,69(3-4):403

The Bahía Blanca Estuary (38° 50′ S, and 62° 30′ W) presents salt marshes where interactions between the local flora (Sarcocornia perennis) and fauna (Chasmagnathus granulatus) generate some kind of salt pans that alter the normal water circulation and condition its flow and course towards tidal creeks. The crab–vegetation dynamics in the salt marsh presents variations that cannot be quantified in a reasonable period of time. The interaction between S. perennis plant and C. granulatus crab is based on simple laws, but its result is a complex biological mechanism that causes an erosive process on the salt marsh and favors the formation of tidal creeks. To study it, a Cellular Automata model is proposed, based on the laws deduced from the observation of these phenomena in the field, and then verified with measurable data within macroscale time units. Therefore, the objective of this article is to model how the interaction between C. granulatus and S. perennis modifies the landscape of the salt marsh and influences the path of tidal creeks. The model copies the basic laws that rule the problem based on purely biological factors.The Cellular Automata model proved capable of reproducing the effects of the interaction between plants and crabs in the salt marsh. A study of the water drainage of the basins showed that this interaction does indeed modify the development of tidal creeks. Model dynamics would likewise follow different laws, which would provide a different formula for the probability of patch dilation. The patch shape can be obtained changing the pattern that dilates.  相似文献   

Strain-softening behaviour of sand in strain path testing under plane-strain conditions     

D. Wanatowski  J. Chu  R. S.-C. Lo 《Acta Geotechnica》2008,3(2):99-114

Experimental data are presented in this paper to study the strain-softening behaviour of sand under plane-strain conditions. K ₀ consolidated strain path tests were conducted using a new plane-strain apparatus. The stress–strain behaviour of medium dense sand under plane-strain conditions was characterized. The test results show that the occurrence of pre-failure strain softening under plane-strain conditions is affected by the void ratio, the strain increment ratio and the initial effective confining stress. This is consistent with previous findings established under axisymmetric conditions. However, a pre-failure strain-softening behaviour in plane-strain tests conducted under high-confining stresses may consist of three stages, namely, material softening, banding softening, and ultimate state. This observation is different from that in triaxial tests where banding softening does not normally occur.  相似文献   

Evidence of magmatic CO2-rich fluids in peraluminous graphite-bearing leucogranites from Deep Freeze Range (northern Victoria Land,Antarctica)     

Maria Luce Frezzotti  Gianfranco Di Vincenzo  Claudio Ghezzo  Ernst A. J. Burke 《Contributions to Mineralogy and Petrology》1994,117(2):111-123

Fine-grained peraluminous synkinematic leuco-monzogranites (SKG), of Cambro-Ordovician age, occur as veins and sills (up to 20–30 m thick) in the Deep Freeze Range, within the medium to high-grade metamorphics of the Wilson Terrane. Secondary fibrolite + graphite intergrowths occur in feldspars and subordinately in quartz. Four main solid and fluid inclusion populations are observed: primary mixed CO₂+H₂O inclusions + Al₂SiO₅ ± brines in garnet (type 1); early CO₂-rich inclusions (± brines) in quartz (type 2); early CO₂+CH₄ (up to 4 mol%)±H₂O inclusions + graphite + fibrolite in quartz (type 3); late CH₄+CO₂+N₂ inclusions and H₂O inclusions in quartz (type 4). Densities of type 1 inclusions are consistent with the crystallization conditions of SKG (750°C and 3 kbar). The other types are post-magmatic: densities of type 2 and 3 inclusions suggest isobaric cooling at high temperature (700–550°C). Type 4 inclusions were trapped below 500°C. The SKG crystallized from a magma that was at some stage vapour-saturated; fluids were CO₂-rich, possibly with immiscible brines. CO₂-rich fluids (±brines) characterize the transition from magmatic to post-magmatic stages; progressive isobaric cooling (T<670°C) led to a continuous decrease off _{O 2} can entering in the graphite stability field; at the same time, the feldspars reacted with CO₂-rich fluids to give secondary fibrolite + graphite. Decrease ofT andf _{O 2} can explain the progressive variation in the fluid composition from CO₂-rich to CH₄ and water dominated in a closed system (in situ evolution). The presence of N₂ the late stages indicates interaction with external metamorphic fluids.Contribution within the network Hydrothermal/metamorphic water-rock interactions in crystalline rocks: a multidisciplinary approach on paleofluid analysis. CEC program: Human Capital and Mobility  相似文献   

Palaeolimnological studies of the eutrophication of volcanic Lake Albano (Central Italy)     

Andrea Lami  Frank Niessen  Piero Guilizzoni  Julieta Masaferro  Claudio A. Belis 《Journal of Paleolimnology》1994,10(3):181-197

We use palaeolimnological techniques to reconstruct the eutrophication history of a volcanic lake (Lake Albano, central Italy) over the past three centuries. The presence of annual varves down to the bottom of the core (c. 1700 A.D.) indicated the lack of bioturbation and likely long-term meromixis. Sedimentation rates were estimated by varve counts (calcite/diatom couplets), indicating a mean rate of 0.15 cm yr^–1. The reconstruction of eutrophication was traced using past populations of algal and photosynthetic bacteria (through their fossil pigment), and geochemistry, as well as fossil remains of chironomids. Phaeophorbidea and the red carotenoid astaxanthin were used to detect past zooplankton development.The first sign of trophic change related to human activities is datedc. 1870 A.D. From that period onward a sharp increase of authigenic CaCO₃, nitrogen, N:P ratio, and dinoxanthin, a characteristic carotenoid of Chrysophyceae and Dinophyceae, is observed.Chironomid analyses showed the near absence of a deep water fauna throughout the core length. The populations of chironomid larvae are restricted to oxygenated littoral zones. In fact, the few fossil remains found are primarily of littoral origin, representing shallow water midges that were transported to profundal waters. The reduction of total chironomid in the uppermost layers of the core is to be related to human land uses.  相似文献