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Cécile Fabre Marie-Christine BoironJean Dubessy Aliouka ChabironBernard Charoy Tomas Martin Crespo 《Geochimica et cosmochimica acta》2002,66(8):1401-1407
Lithium is an important geochemical tracer for fluids or solids. However, because the electron microprobe cannot detect Li, variations of Li abundance at the micrometric scale are most often estimated from bulk analyses. In this study, the Li intense emission line at 670.706 nm in optical emission spectroscopy was used to perfect the analysis of Li at the micrometric scale by means of laser-induced breakdown spectroscopy (LIBS). To estimate lithium content for different geological materials, LIBS calibration of the emission line at 670.706 nm was achieved by use of synthetic glasses and natural minerals. The detection limit for this method is ∼5 ppm Li. Three applications to geological materials show the potential of LIBS for lithium determination, namely for Li-bearing minerals, melt inclusions, quartz, and associated fluid inclusions.For spodumene and petalite from granite pegmatite dikes (Portugal), the Li2O concentrations are 7.6 ± 1.6 wt% and 6.3 ± 1.3 wt%, respectively, by use of LIBS. These values agree with ion microprobe analyses, bulk analyses, or both. For eucryptite crystals, the Li concentrations are scattered because grain size is smaller than the LIBS spatial resolution (6 to 8 μm). Lithium concentrations of melt inclusions from the Streltsovka U deposit (Siberia) are in the range of 2 to 6.2 wt% (Li2O) for Li-rich daughter minerals. Lithium estimations on silicate glasses display values between 90 and 400 ppm.Lithium was also analyzed as a trace element in quartz. Transverse profiles were performed in hydrothermal barren quartz veins from the Spanish Central System (Sierra de Guadarrama). The highest Li concentrations (250 to 370 ppm) were found in specific growth bands in conjunction with the observed variation in optical cathodoluminescence intensity. Considering the fluid inclusion analysis, the source of fluid responsible to the Li enrichment in quartz is probably high-salinity fluids derived from sedimentary basins. 相似文献
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Sensitivity experiments are conducted to test the influence of poorly known model parameters on the simulation of the Greenland
ice sheet by means of a three dimensional numerical model including the mechanical and thermal processes within the ice. Two
types of experiments are performed: steady-state climatic conditions and simulations over the last climatic cycle with a climatic
forcing derived from the GRIP record. The experiments show that the maximum altitude of the ice sheet depends on the ice flow
parameters (deformation and sliding law coefficients, geothermal flux) and that it is low when the ice flow is fast. On the
other hand, the maximum altitude is not sensitive to the ablation strength and consequently during the climatic cycle it is
driven by changes in accumulation rate. The ice sheet extension shows the opposite sensitivity: it is barely affected by ice
flow velocity and the ice covered area is smaller for large ablation coefficients. For colder climates, when there is no ablation,
the ice sheet extension depends on the sea level. An interesting result is that the variations with time of the altitude at
the ice divide (Summit) do not depend on the parameters we tested. The present modelled ice sheets resulting from the climatic
cycle experiments are compared with the present measured ice sheet in order to find the set of parameters that gives the best
fit between modelled and measured geometry. It seems that, compared to the parameter set most commonly used, higher ablation
rate coefficents must be used.
Received: 19 September 1995 / Accepted: 30 May 1996 相似文献
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R. Black H. Ba E. Ball J. M. Bertrand A. M. Boullier R. Caby I. Davison J. Fabre M. Leblanc L. I. Wright 《International Journal of Earth Sciences》1979,68(2):543-564
The Iforas (60 000 km2) falls within the Pan-African mobile belt bordering the West-African craton in north-eastern Mali Republic. It is characterized by major N-S shear belts parallel to the edge of the craton which delimit longitudinal blocks some of which have undergone considerable horizontal displacements. The central core of the Iforas which consists largely of reactivated pre-Pan-African basement injected by Pan-African syn- and post-tectonic intermediate and acid plutonic rocks, has behaved as a relatively rigid blocks during the Pan-African dividing the orogenic belt into a western Iforas and an eastern Iforas.Western Iforas displays W to E zonation: an ophiolitic suture (Timetrine); trench volcano-sedimentary deposits cut by gabbros diorites and acid granitoids (Tilemsi); and a late orogenic composite »coastal range batholith intruding the pre-Pan-African basement of Central Iforas and its overlying volcano-sedimentary deposits which here display a littoral facies and a tillite.Central Iforas consists of two major units: a polycyclic pre-Pan-African basement metamorphosed under high amphibolite facies conditions of presumed Eburnean age and the Iforas granulite block bound to the W, N and E by shear zones.Eastern Iforas was totally separated during metamorphism and deformation from the Iforas granulite block. From West to East, three lithological assemblages have been recognised separed by shear belts: a Quartzite Group, a Gneissic Group and a Pelitic Group the latter representing the southern prolongation of the central Hoggar Pharusian province.Shear zones are an essential feature of Pan-African tectonism East of the West-African craton. The superimposed stress fields have been recognised producing: early N20° trending sinistral shear zones, a north-south dextral shear zone (Andjour-Tamaradant shear zone) and late conjugating sinistral NNW and dextral ENE wrench faults.Late Pan-African events reflect the uplift and unroofing of the Pan-African composite batholith, the intrusion of circular granite plutons often located close to shear zones and alternating episodes of distension and compression.Lastly the simple model proposed for the closing stages of the Pan-African in the Iforas is that of an active continental plate margin separated from the West African craton by an oceanic domain. Subsequent continental collision to the South with a promotory of the West African craton led to the formation of the Dahomeyan thrust front and modified the stress field. Closure of the oceanic domain of western Iforas is thought to have taken place by continued eastward subduction of the oceanic plate and sinistral movement along an inferred north westerly trending transform fault coinciding with the future Cretaceous Gao trough and an alignement of strong positive gravity anomalies. It was accompanied by the northerly migration of central and western Iforas along the conjugating dextral N-S Andjour-Tamaradant shear zone. Further shortening led to folding of the arcuate Timetrine-Ydouban-Gourma fold belt overlying the deformed margin of the West African craton.
Zusammenfassung Das Iforas-Gebiet (60 000 km2) gehört zur pan-afrikanischen Bewegungszone, die in Mali an das westafrikanische Kraton grenzt. Diese Zone wird von N-S Scherbewegungen parallel zum Kraton durchzogen, wobei größere horizontale Versetzungsbeträge langgestreckte Blöcke herausgetrennt haben. Der zentrale Teil von Iforas besteht im wesentlichen aus reaktiviertem prae-panafrikanischem Basement, das in pan-afrikanischer Zeit von syn- und posttektonischen, intermediären und sauren Plutoniten intrudiert wurde. Dieses Gebiet wirkt als relativ starrer Block, der während der pan-afrikanischen Orogenese den Orogengürtel in einen westlichen und einen östlichen Ast teilt. Das westliche Iforas-Gebiet zeigt eine E-W Zonierung: eine Ophiolith-Sutur, einen vulkano-sedimentären Gürtel und einen Rand-Batholithen.Zentral-Iforas wird aus zwei Einheiten aufgebaut: ein mehrfach metamorphisiertes Basement und einen Granitblock.In den überregionalen Scherzonen lassen sich drei Stress-Felder erkennen: eine ältere 20° streichende sinistrale Scherzone, eine N-S dextrale Scherzone und jüngere NNW und dextrale ENE Bruchzonen.Spät-pan-afrikanische Ereignisse sind durch Heraushebung und Abtrag, Granitintrusionen und wechselnden Dehnungs- und Kompressionsbewegungen gekennzeichnet.
Résumé L'Adrar des Iforas (60 000 km2) fait partie de la zone mobile pan-africaine en marge du craton ouest-africain au Nord-Est de la République du Mali. La région est caractérisée par d'importants accidents mylonitiques parallèles à la bordure du craton qui délimitent des compartiments longitudinaux dont certains ont subi des déplacements horizontaux considérables. La zone dorsale des Iforas qui consiste essentiellement en un socle pré-pan-africain réactivé et injecté au Pan-Africain par des roches plutoniques intermédiaires et acides, syn- et post-tectoniques, s'est comportée en compartiments relativement rigides au cours du Pan-Africain, divisant la chaîne en un rameau occidental et un rameau oriental.Le rameau occidental présente une zonation d'Ouest en Est: une suture ophiolitique (Timetrine); des dépôts volcano-sédimentaires de fosse recoupés par des gabbros et des diorites; et un vaste batholite composite tardi-orogénique qui recoupe le socle pré-pan-africain de la zone dorsale des Iforas et sa couverture de dépôts volcanosédimentaires ici à faciès littoral.La zone dorsale des Iforas comprend deux unités majeures: un socle prépan-africain polycyclique métamorphisé dans le faciès amphibolite, d'âge éburnéen présumé et le môle granulitique des Iforas, délimité à l'W, au N et à l'E par des accidents mylonitiques.Le rameau oriental était séparé du môle granulitique des Iforas lors du métamorphisme et de la déformation. D'W en E, on trouve trois unités séparées par des zones mylonitiques: un Groupe de Quartzites, un Groupe de Gneiss et un Groupe de Pélites. Ce dernier représente le prolongement vers le Sud de la province pharusienne du centre Hoggar.Les grands accidents de cisaillement sont un fait marquant du tectonisme pan-africain à l'Est du craton ouest-africain. Trois champs de contraintes superposées ont produit des accidents précoces sénestres de direction N20, un accident N-S dextre (Andjour-Tamaradant), et des failles cisaillantes tardives conjuguées d'orientation NNW sénestres et ENE dextres.Les événements pan-africains tardifs sont marqués par la surrection et l'érosion des batholites pan-africains, la mise en place de plutons granitiques souvent à proximité des grands accidents et par des alternances de distensions et de compressions.Enfin un modèle simple est proposé pour les stades ultimes du Pan-Africain dans l'Adrar des Iforas: une marge continentale active séparée du craton ouest-africain par un domaine océanique; suite à une collision au Sud avec un promontoire du craton ouestafricain qui aurait produit le front de chevauchement dahomeyen et modifié le champ de contraintes, la fermeture du domaine océanique de l'Ouest Iforas se serait produite par subduction à l'E de la plaque océanique et une translation sénestre le long d'une faille transformante orientée NW et coincidant avec le fossé crétacé de Gao et un alignement d'anomalies gravimétriques positives. Elle aurait été accompagnée par le déplacement vers le N de l'Iforas occidental et central le long de l'accident cisaillant dextre d'Andjour-Tamaradant. Cette fermeture aurait provoqué les plissements de la chaîne du Timetrine-Ydouban-Gourma qui repose sur la bordure déformée du craton ouestafricain.
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Philippe Besson Jefferson Degboe Benjamin Berge Valérie Chavagnac Sébastien Fabre Gilles Berger 《Geostandards and Geoanalytical Research》2014,38(3):355-362
We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q® water. We obtained an average reference value rK (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg?1)/(g kg?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to rNa, rCa and rMg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids. 相似文献
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This study concerns the laboratory testing of core samples from massive sedimentary rocks from an oil and gas field. The depth of extraction of the samples analysed varies between 1000 and 5000 metres. In all, 65 tests were performed, most of which included systematic measurement of acoustic activity during loading. The aim of the testing was to determine which types of fracture could occur in the rock matrix under field-stress conditions by examining in particular the relationship between confining pressure and the transition from brittle to ductile behaviour. The results of the laboratory tests are used to predict the occurrence of seismic activity resulting from the depletion of the gas reservoir which has been monitored during the last twenty years. 相似文献
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Magali Fabre Christophe Lcuyer Jean-Philip Brugal Romain Amiot Franois Fourel Franois Martineau 《Quaternary Research》2011,75(3):605-613
Oxygen isotope compositions of phosphate in tooth enamel from large mammals (i.e. horse and red deer) were measured to quantify past mean annual air temperatures and seasonal variations between 145 ka and 33 ka in eastern France. The method is based on interdependent relationships between the δ18O of apatite phosphate, environmental waters and air temperatures. Horse (Equus caballus germanicus) and red deer (Cervus elaphus) remains have δ18O values that range from 14.2‰ to 17.2‰, indicating mean air temperatures between 7°C and 13°C. Oxygen isotope time series obtained from two of the six horse teeth show a sinusoidal-like signal that could have been forced by temperature variations of seasonal origin. Intra-tooth oxygen isotope variations reveal that at 145 ka, winters were colder (? 7 ± 2°C) than at present (3 ± 1°C) while summer temperatures were similar. Winter temperatures mark a well-developed West–East thermal gradient in France of about ? 9°C, much stronger than the ?4°C difference recorded presently. Negative winter temperatures were likely responsible for the extent and duration of the snow cover, thus limiting the food resources available for large ungulates with repercussions for Neanderthal predators. 相似文献