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Various Oligocene formations from NE Greece (ignimbrites from the Medousa area, rhyolites from Zagradenia, granodiorites from Elatia) show discordant paleomagnetic signatures, in each case indicating small cw (clockwise) rotation and also inclination flattening. Marls from Pithion were partly remagnetized in a present-day field. Samples that contain ancient magnetization components also indicate small cw rotation and inclination flattening. However, the magnetization of andesites from Peplos reflects a considerably larger rotation, likely owing to local tectonics. In the context of previous work in the area, these results are used to propose a subdivision of NE Greece into four structural zones of distinctive rotational behaviour (from east to west): sites in zone 1, east of the Kavala-Xanthi-Komotini fault (KXK), show various cw and ccw (counterclockwise) rotation angles owing to complex kinematics resulting from the interaction of the KXK and the north-Anatolian fault zone. However, zone 2, between the KXK and the Strymon valley, is structurally homogeneous ( 10° cw rotation). The paleomagnetic signature of the Vertiskos massif (zone 3) implies a larger (> 30°) cw rotation, whereas sites in the Vardar basin (zone 4) contain a paleomagnetic signature similar to that of zone 2. This suggests a motion of the Vertiscos massif, a meta-ophiolitic nappe, relative to underlying strata. Indeed, zones 2 and 4 may be parts of the same structural unit which underlies this nappe.  相似文献   
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Summary A garnet peridotite lens from Monte Duria (Adula nappe, Central Alps, Northern Italy) contains porphyroblastic garnet and pargasitic amphibole and reached peak metamorphic conditions of ∼830 C, ∼2.8 GPa. A first stage of near isothermal decompression to pressures <2.0 GPa is characterised by domains where fine grained spinel, clinopyroxene, orthopyroxene and amphibole form. The newly formed amphibole contains elevated levels of fluid mobile elements such as Rb, Ba and Pb indicating that recrystallization was assisted by infiltration of a crustal-derived fluid. Further decompression and cooling to ∼720 °C, 0.7–1.0 GPa associated with limited fluid influx is documented by the formation of orthopyroxene-spinel-amphibole symplectites around garnet. Zircon separated from this garnet peridotite exhibits two distinct zones. Domain 1 displays polygonal oscillatory zoning and high trace element contents. It contains clinopyroxene and amphibole inclusions with the same composition as the same minerals formed during the spinel peridotite equilibration, indicating that this domain formed under sub-solidus conditions during decompression and influx of crustal fluids. Domain 2 has no zoning and much lower trace element contents. It replaces domain 1 and is likely related to zircon recrystallization during the formation of the symplectites. SHRIMP dating of the two domains yielded ages of 34.2 ± 0.2 and 32.9 ± 0.3 Ma, respectively, indicating fast exhumation of the peridotite within the spinel stability field. We suggest that the Duria garnet peridotite originates from the mantle wedge above the tertiary subduction of the European continental margin and that it was assembled to the country rock gneisses between 34 and 33 Ma. Third author was Deceased  相似文献   
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High-resolution space-borne remote sensing data are investigated for their potential to extract relevant parameters for a vulnerability analysis of buildings in European countries. For an evaluation of large earthquake scenarios, the number of parameters in models for vulnerability is reduced to a minimum of relevant information such as the type of building (age, material, number of storeys) and the geological and spatial context. Building-related parameters can be derived from remote sensing data either directly (e.g. height) or indirectly based on the recognition of the urban structure type in which the buildings are located. With the potential of a fully- or semi-automatic inventory of the buildings and their parameters, high-resolution satellite data and techniques for their processing are a useful supporting tool for the assessment of vulnerability.  相似文献   
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Jrg Hermann 《Lithos》2003,70(3-4):163-182
The peak metamorphic conditions of subducted continental crust in the Dora-Maira massif (Western Alps) have been revised by combining experimental results in the KCMASH system with petrologic information from whiteschists. Textural observations in whiteschists suggest that the peak metamorphic assemblage garnet+phengite+kyanite+coesite±talc originates from the reaction kyanite+talc↔garnet+coesite+liquid. In the experimentally determined petrogenetic grid, this reaction occurs above 45 kbar at 730 °C. At lower pressures, talc reacts either to orthopyroxene and coesite or, together with phengite, to biotite, coesite and kyanite. The liberated liquid contains probably similar amounts of H2O and dissolved granitic components. The composition of the liquid in the whiteschists at peak metamorphic conditions, a major unknown in earlier studies, was probably very similar to the liquid composition produced in the experiments. Therefore, the experimentally determined petrogenetic grid represents a good model for the estimation of the peak metamorphic conditions in whiteschists. Experimentally determined Si-isopleths for phengite further constrain peak pressures to 43 kbar for the measured Si=3.60 of phengite in the natural whiteschists. All these data provide evidence that the whiteschists reached diamond-facies conditions.

The fluid-absent equilibrium 4 kyanite+3 CELADONITE=4 coesite+3 muscovite+pyrope has been calibrated on the basis of garnet and phengite compositions in the experiments and serves as a geothermobarometer for ultra-high-pressure (UHP) metapelites. For graphite-bearing metapelites and kyanite–phengite eclogites, forming the country rocks of the whiteschists, peak metamorphic pressures of about 44±3 kbar were calculated from this barometer for temperatures of 750 °C estimated from garnet–phengite thermometry. Therefore, the whole ultra-high-pressure unit of the Dora-Maira massif most likely experienced peak metamorphic conditions in the diamond stability field. While graphite is common in the metapelites, diamond has not been found so far. The absence of metamorphic microdiamonds might be explained by the low temperature of metamorphism, the absence of a free fluid phase in the metapelites and a short residence time in diamond-facies conditions resulting in kinetic problems in the conversion of graphite to diamond.  相似文献   

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The zircons from an eclogite and an enclosed eclogite-facies vein from the Monviso ophiolite (Western Alps) display contrasting chemical and morphologic features and document different stages of the evolution of the ophiolite. The zircons from the eclogite show a typical magmatic zoning and are enriched in heavy rare earth elements (HREEs) over middle rare earth elements (MREEs) and have an accentuated negative Eu anomaly, which indicates that the grains co-crystallised with plagioclase. These magmatic zircons document the formation of oceanic crust at 163 ± 2 Ma. In contrast, zircons from the vein contain inclusions of garnet, omphacite, and rutile, which indicate that they crystallised under eclogite-facies conditions. The vein zircons have Th/U ratios < 0.09, lack Eu anomalies, and are only weakly enriched in HREE with respect to MREE. These features are consistent with a garnet-bearing, plagioclase-free, i.e., eclogite-facies paragenesis. Vein zircons yield an age of 45 ± 1 Ma, which is evidence for Eocene subduction-zone metamorphism of the Monviso ophiolite.In the vein, the apparent coexistence of zircon, omphacite, and garnet permits the determination of a set of trace element distribution coefficients among these minerals at high pressure. This set of partitioning can demonstrate chemical equilibrium among these phases in rocks that show less clear evidence of textural equilibrium. In addition, zircon age can now be linked to sensors of metamorphic pressure-temperature conditions. The presence of zircon and rutile in the vein is another example of high field strength element (HFSE) mobility over short distances in aqueous fluids at eclogite-facies conditions. However, the concentrations of Zr and Hf in the aqueous fluid are estimated to be at least a factor of 10 less than primitive mantle values.Mass balance calculations demonstrate that zircon hosts > 95% of the bulk Zr, 90% of Hf, and ∼25% of U in the vein. Zircon is a residual phase in subducted basalts and sediments up to temperatures of at least 800 to 900 °C. Therefore, residual zircon in subducted crust, together with rutile, control the HFSE in liberated subduction zone fluids/melts and might be partly responsible for negative Zr and Hf anomalies in subduction zone magmas.  相似文献   
10.
A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process.  相似文献   
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