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A. Hynes 《Contributions to Mineralogy and Petrology》1982,81(2):119-125
A comparison of published metabasite amphibole analyses from medium and low-pressure metamorphic terrains reveals that there is no systematic variation in Na, NaM4, Al or AlVI as a function of pressure. This may be due to blurring of the differences by variation in oxidation state, or by analytical differences between laboratories. It is not due to variable Mg/Fe in whole rocks. Differences that can be recognised are generally higher Ti/Al ratios in the low-pressure amphiboles, and a very poorly developed compositional gap between actinolite and hornblende compared with a well-developed gap at medium pressures. These features, together with the relatively low-grade appearance of calcic plagioclase at low pressures, provide the best means of distinguishing metabasites from the two facies series.All three features can be explained by the configuration of cation-exchange equilibria at the greenschist/amphibolite facies boundary. Enrichment in Ti at low-pressures is due to the positive slope of reactions partitioning Ti into the amphibole. The composition gap in amphiboles at medium-pressure is due to overstepping of the tschermakite-enriching equilibrium. At low pressures this overstepping still occurs, but the equilibrium tschermakite-content in the amphibole is much lower for a given amount of overstepping. The relatively low-grade appearance of oligoclase at low pressures is due to convergence of the tschermakite and anorthite-enriching equilibria with decreasing pressure. 相似文献
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D. M. Francis A. J. Hynes J. N. Ludden J. Bédard 《Contributions to Mineralogy and Petrology》1981,78(1):27-36
There is little concensus on the relative importance of crystal fractionation and differential partial melting to the chemical diversity observed within most types of volcanic suites. A resolution to this controversy is best sought in suites containing high MgO lavas such as the Chukotat volcanics of the Proterozoic Cape Smith foldbelt, Ungava, Quebec. The succession of this volcanic suite consists of repetitive sequences, each beginning with olivine-phyric basalt (19-12 wt% MgO), grading upwards to pyroxene-phyric basalt (12-8 wt% MgO) and then, in later sequences, to plagioclase-phyric basalt (7-4 wt% MgO). Only the olivine-phyric basalts have compositions capable of equilibrating with the upper mantle and are believed to represent parental magmas for the suite. The pyroxene-phyric and plagioclase-phyric basalts represent magmas derived from these parents by the crystal fractionation of olivine, with minor chromite, clinopyroxene and plagioclase. The order of extrusion in each volcanic sequence is interpreted to reflect a density effect in which successively lighter, more evolved magmas are erupted as hydrostatic pressure wanes. The pyroxene-phyric basalts appear to have evolved at high levels in the active part of the conduit system as the eruption of their parents was in progress. The plagioclase-phyric basalts may represent residual liquids expelled from isolated reservoirs along the crust-mantle interface during the late stages of volcanic activity.A positive correlation between FeO and MgO in the early, most basic olivine-phyric basalts is interpreted to reflect progressive adiabatic partial melting in the upper mantle. Although this complicates the chemistry, it is not a significant factor in the compositional diversification of the volcanic suite. The preservation of such compositional melting effects, however, suggests that the most basic olivine-phyric basalts represent primitive magmas. The trace element characteristics of these magmas, and their derivatives, indicate that the mantle source for the Chukotat volcanics had experienced a previous melting event. 相似文献
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Carbonatization and mobility of Ti,Y, and Zr in Ascot Formation metabasalts,SE Quebec 总被引：3，自引：0，他引：3
Andrew Hynes 《Contributions to Mineralogy and Petrology》1980,75(1):79-87
The middle Ordovician Ascot Formation of southeastern Quebec consists of greenschist facies metamorphosed silicic to mafic pyroclastic rocks and lava flows and associated metasediments. Chemical analyses of lavas reveal a preponderance of metarhyolites and metabasalts, together with some porphyritic rocks with intermediate SiO2 contents. The metabasalts exhibit wide ranges in concentrations of TiO2 (0.25–2.0 wt.°), Y (9–46 ppm), and Zr (5–135 ppm). The extent of the ranges, and unusual interelement ratios, suggest that the concentrations of these normally immobile elements have been affected by secondary processes.There is a strong correlation between trace-element concentrations and the degree of carbonatization of the metabasalts. Low carbonate rocks are severely depleted in Ti, Y, and Zr whereas high carbonate rocks are depleted in Y and Zr and enriched in Ti. The differing movement of Ti can be explained in terms of variable chemical potential due to the various carbonatization reactions affecting titaniferous phases. Overall mobility of these generally immobile/rd elements is attributed to high CO2 levels in the fluid phase during metamorphism.Extrapolation of the two alteration trends to a common origin enables one to infer primary concentrations of the trace-elements. Primary inter-element ratios arrived at in this way are compatible with an island-arc origin for the Ascot Formation although TiO2 concentrations are a little high (1.5 wt/%). 相似文献
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R. Cornelisse D. Steeghs J. Casares P. A. Charles I. C. Shih R. I. Hynes K. O'Brien 《Monthly notices of the Royal Astronomical Society》2007,381(1):194-200
Two nights of phase-resolved medium-resolution Very Large Telescope spectroscopy of the extra-galactic low-mass X-ray binary LMC X−2 have revealed a 0.32 ± 0.02 d spectroscopic period in the radial velocity curve of the He ii λ4686 emission line that we interpret as the orbital period. However, similar to previous findings, this radial velocity curve shows a longer term variation that is most likely due to the presence of a precessing accretion disc in LMC X−2. This is strengthened by He ii λ4686 Doppler maps that show a bright spot that is moving from night to night. Furthermore, we detect narrow emission lines in the Bowen region of LMC X−2, with a velocity of K em = 351 ± 28 km s−1 , that we tentatively interpret as coming from the irradiated side of the donor star. Since K em must be smaller than K 2 , this leads to the first upper limit on the mass function of LMC X−2 of f ( M 1 ) ≥ 0.86 M⊙ (95 per cent confidence), and the first constraints on its system parameters. 相似文献
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C. A. Haswell R. I. Hynes A. R. King K. Schenker 《Monthly notices of the Royal Astronomical Society》2002,332(4):928-932
We compare ultraviolet (UV) spectra of the recent soft X-ray transients XTE J1118+480 and XTE J1859+226. The emission line strengths in XTE J1118+480 strongly suggest that the accreting material has been CNO processed. We show that this system must have come into contact with a secondary star of about 1.5 M⊙ , and an orbital period ∼15 h, very close to the bifurcation value at which the nuclear and angular momentum loss time-scales are similar. Subsequent evolution to the current period of 4.1 h was driven by angular momentum loss. In passing through a period of 7.75 h the secondary star would have shown essentially normal surface abundances. XTE J1118+480 could thus represent a slightly later evolutionary stage of A0620-00. We briefly discuss the broad Ly α absorption wings in XTE J1118+480. 相似文献
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Sarah U. Wisseman Duane M. Moore Randall E. Hughes Mary R. Hynes Thomas E. Emerson 《Geoarchaeology》2002,17(7):689-715
Provenance studies of stone artifacts often rely heavily upon chemical techniques such as neutron activation analysis. However, stone specimens with very similar chemical composition can have different mineralogies (distinctive crystalline structures as well as variations within the same mineral) that are not revealed by multielemental techniques. Because mineralogical techniques are often cheap and usually nondestructive, beginning with mineralogy allows the researcher to gain valuable information and then to be selective about how many samples are submitted for expensive and somewhat destructive chemical analysis, thus conserving both valuable samples and funds. Our University of Illinois team of archaeologists and geologists employs Portable Infrared Mineral Analyzer (PIMA) spectroscopy, X‐ray diffraction (XRD), and Sequential acid dissolution/XRD/Inductively coupled plasma (SAD‐XRD‐ICP) analyses. Two case studies of Hopewellian pipes and Mississippian figurines illustrate this mineralogical approach. The results for both studies identify sources relatively close to the sites where the artifacts were recovered: Sterling, Illinois (rather than Ohio) for the (Hopewell) pipes and Missouri (rather than Arkansas or Oklahoma) for the Cahokia figurines. © 2002 Wiley Periodicals, Inc. 相似文献
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Karyn Morrissey Graham Clarke Dimitris Ballas Stephen Hynes Cathal O'Donoghue 《Area》2008,40(3):354-364
This paper analyses the effect accessibility has on General Practitioner (GP) utilisation rates at the sub-national level for Ireland. Specifically, the aim of this paper is to estimate whether there is an urban–rural differential in GP utilisation rates. We do this by simulating micro-level healthcare data. Using this synthetic data, simple logit models are employed to estimate the likelihood that individuals in different jurisdictions will attend a GP surgery. These individual logit estimates are then inputted into a spatial interaction model to highlight areas with low GP accessibility given their health status. The policy implications of these results are discussed in relation to both the healthcare literature and current Irish healthcare policy. 相似文献