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Size distribution of colloidal trace metals and organic carbon during a coastal bloom in the Baltic Sea 总被引：1，自引：0，他引：1
Johan Ingri Susanna Nordling Jenny Larsson Jenny Rnnegrd Nina Nilsson Ilia Rodushkin Ralf Dahlqvist Per Andersson
rjan Gustafsson 《Marine Chemistry》2004,91(1-4):117-130
The physico-chemical speciation of organic carbon and selected metals was measured during a coastal bloom in Ekhagen Bay, Baltic Sea, using ultrafiltration.One important objective with the study was to see if any depletion of trace metals could be measured in the directly bioavailable fraction (<1000 Da, the soluble low molecular weight fraction, LMW) during a plankton bloom. Filters with five different cut-offs were used (1 kD (1000 Da), 5 kD, 10 kD, 100 kD and 0.22 μm) in order to delineate the size distribution of colloidal organic carbon (COC) and trace metals.During the bloom in May, LMW Al, Co, Cu, Mn and Ni concentrations decreased although the colloidal and particulate concentrations were relatively high. Data show that desorption of colloidal and particulate bound trace metals to the LMW fraction was slower than the process depleting the LMW fraction.Estimates of the maximum active uptake of Cu, Ni and Mn by the phytoplankton, and the loss of non-bioactive Al from the LMW fraction, indicate that processes other than active uptake by phytoplankton must contribute to the observed depletion of trace metals in the LMW fraction. Hence, in order to estimate the bioavailable pool of trace metals for plankton during bloom conditions, these other processes must be understood and quantified.Transparent Exopolymeric Particles (TEP, reflecting sugar-rich phytoplankton exudates) increased around eight times during the plankton bloom. We hypothesize that the formation of TEP is a process that might be important for the transfer of trace metals from the LMW to the particulate fraction during the phytoplankton bloom, but the significance of TEP for this depletion in Baltic Sea surface water remains to be shown. 相似文献
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Ilia Rodushkin Emma Engström Douglas C. Baxter 《Geostandards and Geoanalytical Research》2007,31(1):27-38
The analytical performance of a method for Os isotope ratio measurement by double‐focusing, sector field ICP‐MS (ICP‐SFMS) was evaluated. The method is based on several optimised, concurrent processes: Os extraction from samples in hot concentrated nitric acid; separation of Os from the digest solution by the formation of volatile osmium tetroxide accelerated by continuous hydrogen peroxide addition; transport of analyte vapour by an oxygen flow into the ICP; and isotopic determination by ICP‐SFMS. Due to the very efficient utilisation of analyte (approaching 0.5‰), Os isotope ratio measurement could be performed at low pg levels. Combined with an ability to process sample sizes up to 2 g (up to 50 g if the organic matrix of biological or botanical samples is eliminated by ashing), materials with Os concentrations in the low, or even sub pg g?1 range could be determined by this method. Given that two complete digestion/distillation systems were available for interchangeable use, throughputs of up to fifteen samples per 8 hour shift could be achieved. The method precision, evaluated as the long‐term reproducibility of 187 Os/188Os ratio measurements in a commercial Os reference sample containing 0.5 ng Os, was 0.16% relative standard deviation (RSD, 1s). The method has been applied to perform replicate 187 Os/188 Os ratio measurements on a suite of fifty reference materials of various origins and matrix compositions, with Os concentrations varying from < 0.1 pg g?1 to > 100 ng g?1, yielding an average precision of 3% RSD. Though none of the materials tested are certified for Os content or Os isotope composition, comparison of the obtained data with published Os isotope information for similar sample types revealed close agreement between the two. The method can also be used for the simultaneous, semi‐quantitative determination of Os concentrations. 相似文献
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Peter Nojarov Peter Ivanov Ivo Kalapov Ilia Penev Mirolujba Drenska 《Theoretical and Applied Climatology》2009,98(1-2):201-208
Connection between ozone concentration and atmosphere circulation is investigated based on measurements at BEO station, peak Moussala (2,925 m a.s.l.), for the period 09 August 2006 to 29 January 2008. Ozone concentration data are collected with UV-analyzer “Environnement O3 42” and meteo data with weather station “Vaisala”. There are measurements of 7Be. Data from NOAA HYSPLIT model for particle trajectories are also used. Eight wind directions and three ranges of wind velocities are employed in the analysis. A comparison of ozone concentrations in upward and downward air transport according to HYSPLIT model is made. The number of cases with ozone concentration above 63 ppb has been counted. Mann–Whitney nonparametric test is employed as a basic statistical method. Correlation between atmosphere pressure and tropospheric ozone content is made. The same is done for 7Be and ozone. The main conclusion is that there is not any local or regional pollution effect detectable at peak Moussala, but most of the ozone measured is due to emissions of hydrocarbons and NO x over a larger region. There could be some regional sources of ozone building substances in southwest direction from peak Moussala. Air transported from the north quarter has higher ozone concentrations compared to the south quarter. In vertical direction, upward transport of air masses shows higher values of ozone concentration. Higher wind velocity is associated with low ozone concentrations at peak Moussala. The annual course of ozone concentration has summer maximum and winter minimum. There is right connection between air pressure and ozone concentration. The same is valid for the correlation between 7Be and ozone. Diurnal ozone course shows daytime maximum in winter and nighttime maximum in summer. 相似文献
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Ilia Ioanna Rozos Dimitrios Perraki Theodora Tsangaratos Paris 《Central European Journal of Geosciences》2009,1(4):431-442
Thirty bulk samples of hard soils-soft rocks such as marls, originating from Euboea Island and Peloponnesus area, were investigated to evaluate their geotechnical behavior. Specifically, by conducting a series of physical and geotechnical tests, such as liquid limit and plastic limit tests, along with the estimation of the grain size fraction, Slake Durability and Point Load Test. Certain parameters were determined and used for empirical correlations with their mineralogical characteristics. The mineralogical composition was determined by X-ray diffraction, thermo-gravimetric and thermal analysis, succeeded by textural analysis performed by Optical Microscope. With the help of the above mentioned tests, we interpreted the observed geotechnical behavior of the examined weak rocks by means of mineralogical composition and texture. Durability and the unconfined compressive strength was found to be influenced by high percentages in carbonate minerals. In addition, it was found that a decrease in clay content resulted in higher strength and durability values. The concluded empirical correlations verified the influence of these parameters and gave a general overview of the engineering behavior of the examined weak rocks. 相似文献
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Ilia Rochlin Mary-Jane James-Pirri Susan C. Adamowicz Mary E. Dempsey Thomas Iwanejko Dominick V. Ninivaggi 《Estuaries and Coasts》2012,35(3):727-742
An integrated marsh management (IMM) project in an urbanized watershed on Long Island, New York, USA, aimed to mitigate salt marsh degradation and to reduce mosquito production by an innovative combination of restoration and open marsh water management methods. The grid ditch network at two treatment marshes was replaced with naturalized tidal channels and ponds. Effects of the hydrologic alterations were monitored utilizing a before–after–control–impact approach. The treatment marshes experienced a number of beneficial outcomes including a fourfold reduction in the invasive Phragmites australis and increased native vegetation cover in the most degraded portions of the marsh, increased abundance and diversity of marsh killifish and estuarine nekton species, higher shorebird and waterfowl densities, and increased avian species diversity. The successful implementation of IMM concept led to improved marsh health and diminished mosquito production. Therefore, this study may serve as a template for similar large-scale integrated salt marsh restoration projects. 相似文献
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Sebastian Sobek Roland Zurbrügg Ilia Ostrovsky 《Aquatic Sciences - Research Across Boundaries》2011,73(3):355-364
Even though lake sediments constitute a significant long-term carbon sink, studies on the regulation of carbon burial in lakes
sediments have, to date, been surprisingly few. We investigated to what degree the organic carbon (OC) being deposited onto
the bottom of Lake Kinneret (Israel) is buried in the sediment at four different sites with varying degrees of oxygenation
and varying supply of allochthonous particles from the River Jordan. For estimation of the OC burial efficiency (OC BE), i.e.,
the ratio between buried and deposited OC, we calculated OC burial from dated sediment cores, and calculated OC deposition
using three different approaches. Calculation of OC deposition from sediment trap-derived mass deposition rates multiplied
with the OC content of surface sediment yielded OC BE values that were at odds with published values for sediments dominated
by autochthonous OC sources. Calculation via sediment trap data on organic matter flux collected within the Lake Kinneret
monitoring program, as well as calculation of OC deposition as the sum of OC burial plus OC mineralization, returned fairly
congruent estimates of OC BE (range 10–41%), but only if the sediment trap data were corrected for the proportion of resuspended
particles in the traps. Differences in OC BE between sites were small, indicating that OC source (common to all sites) was
a more important regulator of OC BE in Lake Kinneret than oxygen exposure or mineral particles characteristics. 相似文献
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Seismic Design of Symmetric Structures for Accidental Torsion 总被引：5，自引：0，他引：5
The paper presents an analytical estimation of the dynamic effects, caused by the shifting of the centre of mass with accidental
eccentricity in symmetric structures. The approximate analytical solution proves, that even under small accidental eccentricities
the symmetric structures exhibit “irregular behaviour” and the accidental torsional effects cannot be described properly by
static application of torsional moments. The prescribed application rule by Eurocode 8 for multimodal analysis underestimates
the accidental torsional effects up to 21% for 5% eccentricity for the structures considered in the paper. An expression for
the correction of member responses is derived. It is proved by numerical simulations of the dynamic response of three-dimensional
models of symmetric structures, that the proposed correction coefficient gives accurate results in cases of single-storey
and multi-storey structures. It gives a convenient way for the design practice to estimate accurately the accidental torsional
effects on planar and 3-D models of symmetric structures.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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