首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   78篇
  免费   3篇
大气科学   19篇
地球物理   16篇
地质学   8篇
海洋学   14篇
天文学   2篇
自然地理   22篇
  2022年   1篇
  2020年   1篇
  2019年   1篇
  2018年   3篇
  2015年   2篇
  2014年   3篇
  2013年   2篇
  2012年   1篇
  2011年   5篇
  2010年   5篇
  2009年   2篇
  2008年   8篇
  2007年   1篇
  2006年   2篇
  2005年   3篇
  2004年   6篇
  2003年   2篇
  2001年   2篇
  2000年   4篇
  1999年   1篇
  1998年   2篇
  1997年   1篇
  1996年   5篇
  1994年   5篇
  1992年   1篇
  1991年   1篇
  1990年   1篇
  1989年   1篇
  1988年   1篇
  1985年   1篇
  1984年   4篇
  1977年   1篇
  1973年   1篇
  1967年   1篇
排序方式: 共有81条查询结果,搜索用时 250 毫秒
1.
2.
It is shown that the values of pK1C and pK2C for carbonic acid, pKB for boric acid and the ionic product of water, pKw, in sea water may be explained on the basis of their determination in 0.7 Mw sodium chloride and the formation of the following ion-pairs: NaSO4?, MgSO4, CaSO4, MgCO3, CaCO3, MgHCO3+, CaHCO3+, MgOH+, HSO4?, MgB(OH)4+ and CaB(OH)4+. On the whole the calculated stability constants are lower than those given by Garrels and Thompson (1962).  相似文献   
3.
The spring-spawning Baltic Sea herring spawn in coastal areas that also serve as nursery areas for the young fish during their first summer. In a bay known as a herring spawning and nursery area, the pelagic fish abundance was quantified using hydroacoustics every second week from late spring to autumn in 2000 and 2001. A dense system of survey transects allowed determination of the acoustic index (the nautical area scattering coefficient) for fish abundance with high precision. The variation, expressed as the geostatistical coefficient of variation, was on average 5% both years and ranged from 3–11% (2000) and 3–8% (2001). Through the hydroacoustic data intra-annual dynamics in acoustic fish abundance, densities and size composition could be followed, which showed similar trends in both years. In spring and early summer acoustic fish densities were low, followed by a drastic, 20-fold increase in late summer. Hydroacoustic data and biological samples suggest that the increase was caused mainly by the recruitment of young-of-the-year herring to the acoustically assessable pelagic fish community. This age class is commonly not well represented in catches when using traditional sampling gears such as gill nets and trawls, and hydroacoustics may help to improve quantitative estimates of small juvenile fish in order to increase the understanding of biological processes in coastal nursery areas.  相似文献   
4.
Analysis of fly-ash particles in lake sediments has become increasingly important in studies of environmental pollution and lake acidification history. Most fly-ash studies have concerned black spheroidal carbonaceous particles (SCP)(>5 m) produced from oil and coal combustion. This review paper provides a summary of this technique and its application, and focusses on our investigations in Sweden between 1979 and 1993. It consists of five parts: i) preparation and analysis methods, ii) historical trends in atmospheric deposition, iii) geographical surveys of atmospheric deposition, iv) sediment dating, and v) studies of sedimentation processes in lakes. Methods for preparation and analyses of SCP have been developed and applied to investigations using sediment, soil and snow samples. Stratigraphic trends of SCP concentrations in lake-sediment cores reflect the consumption history of fossil fuels. A characteristic temporal SCP pattern, with a marked concentration increase beginning after the 1940's and a peak in the early 1970's, has been recognized in most Swedish lakes and elsewhere in Europe. A survey of SCP concentrations in surface sediments of >100 lakes covering Sweden demonstrated that polluted areas in southern Sweden had >100 times higher SCP concentrations than clean areas in the north. The spatial distribution of SCP over Sweden is similar to the deposition pattern of long-range transported airborne pollutants, such as excess sulphate monitored by network stations. SCP also accumulate in soils, and soil analyses can be used for determining the integrated historical deposition of SCP at the local or regional scale. Finally, SCP have been used for indirect dating of sediment cores and as a marker to assess sediment distribution patterns within lake basins.  相似文献   
5.
The accuracy of three methods used to estimate the whole-lake accumulation rate of chemicals in sediment, the simple mean accumulation rate, regression against water depth and the mean accumulation rate in sedimentation zones, was assessed. The concentrations and accumulation rates of organic carbon, four major cations, phosphorus and four heavy metals in the 1902 to 1988 sediment layer at 43 sites in Kassjön were used and the three methods gave identical results. The accuracy of the simple mean accumulation rate method using 5 or 10 sites was investigated using Monte Carlo simulation and both versions gave accurate results. If the method used the dry sediment accumulation rate at 5 or 10 sites, along with chemical concentration at one central site, then the errors were less than ±10% for five of the chemicals and larger for the others (?20 or 20–40%), although the direction of the bias was predictable. If chemical accumulation rate at the central site only was used to estimate the whole-lake value, the bias increased to 25% for the major cations, 50% for the heavy metals and P, and 85% for organic carbon. Having 43 sites in Kassjön meant that the true whole-lake chemical accumulation rate was known and so the accuracy of the methods and their variants could be assessed for the first time. These findings allow the particulars of the simple mean accumulation rate method to be chosen to suit the accuracy needed for a palaeolimnological investigation.  相似文献   
6.
Sulfur has played a central role in the acidification of many lakes in Scandinavia and other regions. As part of the research into sulfur cycling, numerous studies have analyzed the sediment record in order to develop insights into past in-lake cycling of sulfur, particularly in the context of reconstructing past deposition rates. Although many of these studies have shown that it is not easy to interpret the sediment record in terms of past sulfur deposition rates, analyses of sulfur in sediment still provide valuable information on the response of lakes to anthropogenic sulfur deposition. Here, we have analyzed sulfur in top and bottom samples from short surface cores (25–35 cm, representing ≥250 years) as well as bulk cores from ∼110 lakes located throughout Sweden, which were collected during 1986, as well as in more-detailed profiles from six lakes. The lakes with the highest surface sediment concentrations (9–24 mg S g−1 dry mass) and the highest calculated inventories of ‘excess’ sulfur (20–180 g S m−2) are found in southern Sweden and around one industrial area along the northeastern coast where sulfur deposition rates and lake-water concentrations have been highest. For many lakes in the central and northern inland region it is common that the sediment cores exhibit either no enrichment or even a decline in sulfur concentrations in near-surface sediments, which we suggest was the pre-pollution norm for lakes. Although interpreting sulfur sediment profiles is problematic for reconstructing deposition, a more-comprehensive spatial sampling approach shows that there is a good geographic agreement between sulfur deposition, lake-water chemistry and sediment sulfur accumulation.  相似文献   
7.
8.
9.
Easily discernible sediment varves (annual laminations) may be formed in temperate zone lakes, and reflect seasonal changes in the composition of the accumulating material derived from the lake and its catchment (minerogenic and organic material). The appearance of varves may also be influenced by chemical processes. We assessed the role of iron (Fe) and sulfur (S) in the appearance of varves in sediments from Lake Nylandssjön in northern Sweden. We surveyed Fe in the lake water and established whether there is internal transport of Fe within the sediment. We used a unique collection of seven stored freeze cores of varved sediment from the lake, collected from 1979 to 2004. This suite of cores made it possible to follow long-term changes in Fe and S in the sediment caused by processes that occur in the lake bottom when the sediment is ageing. We compared Fe and S concentrations using X-ray fluorescence spectroscopy (XRF) in specific years in the different cores. No diagenetic front was found in the sediment and the data do not suggest that there is substantial vertical transport of Fe and S in the sediment. We also modeled Fe and S based on thermodynamic, limnological, and sediment data from the lake. The model was limited to the five components H+, e?, Fe3+, SO4 2?, H2CO3 and included the formation of solid phases such as Fe(OH)3 (amorphous), FeOOH (aged, microcrystalline), FeS and FeCO3. Modeling showed that there are pe (redox) ranges within which either FeS or Fe(OH)3/FeOOH is the only solid phase present and there are pe ranges within which the two solid phases co-exist, which supports the hypothesis that blackish and grey-brownish layers that occur in the varves were formed at the time of deposition. This creates new possibilities for deciphering high-temporal-resolution environmental information from varves.  相似文献   
10.
The organic horizon (the mor layer) of podzolized boreal forest soils has accumulated atmospheric fallout of mercury and lead over centuries, resulting in current concentrations close to levels where negative effects on soil biota are thought to occur. To what extent the pollution history is preserved in the stratigraphy of this horizon is not well known. In this study we asses whether the chronology of a large historic pulse of atmospheric pollution emitted from the Rönnskär smelter in northern Sweden, particularly between 1950 and 1980, is preserved within the stratigraphy of the mor layer, which is typically 5-cm thick. Vertical sub-sampling (?5 mm) of five mor profiles sampled along a 100-km pollution gradient away from the smelter are analyzed for mercury and lead concentrations, spheroidal carbonaceous particles from fossil fuel combustion (SCPs) and stable lead isotopes (206Pb/207Pb and 208Pb/207Pb). Their vertical distribution is compared with the temporal variations in atmospheric inputs reconstructed for the last ∼100 years from analyses of an ombrotrophic peat core and a varved lake sediment core sampled within a distance of 50 km of the smelter. The mor profiles situated ?12 km from the smelter record the pollution history of the smelter. There is a 20 to 40-times enrichment of Hg, Pb and SCP at the transition in the O-horizon from the F- to H-layer compared to the basal part and a distinct peak in the 206Pb/207Pb ratio (∼1.22) in the F-layer. The mor profiles situated outside the historical contamination range of the smelter (80 and 100 km away) record no obvious influence from the Rönnskär smelter, instead their vertical 206Pb/207Pb profiles follow the general regional pollution history in northern Sweden. We conclude that the mor layer preserves a record of atmospheric Hg, Pb and SCP inputs and due to low leaching rates this organic horizon serves as a semi-archive of atmospheric Hg and Pb pollution. We stress the need of including this property in the existing ‘black-box’ models predicting the fate of Hg and Pb within contaminated boreal forest soils.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号