Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites     

Milton BLANDER  Arthur D. PELTON  In‐Ho JUNG  Richard WEBER 《Meteoritics & planetary science》2004,39(12):1897-1910

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.  相似文献   

Confirmation of a meteoritic component in impact‐melt rocks of the Chesapeake Bay impact structure,Virginia, USA—Evidence from osmium isotopic and PGE systematics     

Seung Ryeol Lee  J. Wright Horton  Richard J. Walker 《Meteoritics & planetary science》2006,41(6):819-833

Abstract— The osmium isotope ratios and platinum‐group element (PGE) concentrations of impact‐melt rocks in the Chesapeake Bay impact structure were determined. The impact‐melt rocks come from the cored part of a lower‐crater section of suevitic crystalline‐clast breccia in an 823 m scientific test hole over the central uplift at Cape Charles, Virginia. The ¹⁸⁷Os/¹⁸⁸Os ratios of impact‐melt rocks range from 0.151 to 0.518. The rhenium and platinum‐group element (PGE) concentrations of these rocks are 30–270x higher than concentrations in basement gneiss, and together with the osmium isotopes indicate a substantial meteoritic component in some impact‐melt rocks. Because the PGE abundances in the impact‐melt rocks are dominated by the target materials, interelemental ratios of the impact‐melt rocks are highly variable and nonchondritic. The chemical nature of the projectile for the Chesapeake Bay impact structure cannot be constrained at this time. Model mixing calculations between chondritic and crustal components suggest that most impact‐melt rocks include a bulk meteoritic component of 0.01–0.1% by mass. Several impact‐melt rocks with lowest initial ¹⁸⁷Os/¹⁸⁸Os ratios and the highest osmium concentrations could have been produced by additions of 0.1%–0.2% of a meteoritic component. In these samples, as much as 70% of the total Os may be of meteoritic origin. At the calculated proportions of a meteoritic component (0.01–0.1% by mass), no mixtures of the investigated target rocks and sediments can reproduce the observed PGE abundances of the impact‐melt rocks, suggesting that other PGE enrichment processes operated along with the meteoritic contamination. Possible explanations are 1) participation of unsampled target materials with high PGE abundances in the impact‐melt rocks, and 2) variable fractionations of PGE during syn‐ to post‐impact events.  相似文献   

East Asian monsoon variation and climate changes in Jeju Island, Korea, during the latest Pleistocene to early Holocene     

Seung Hyoun Lee  Yong Il Lee  Ho Il Yoon 《Quaternary Research》2008,70(2):265-274

A 4.96-m-long sediment core from the Hanon paleo-maar in Jeju Island, Korea was studied to investigate the paleoclimatic change and East Asian monsoon variations during the latest Pleistocene to early Holocene (23,000-9000 cal yr BP). High-resolution TOC content, magnetic susceptibility, and major element composition data indicate that Jeju Island experienced the coldest climate around 18,000 cal yr BP, which corresponds to the last glacial maximum (LGM). Further, these multi-proxy data show an abrupt shift in climatic regime from cold and arid to warm and humid conditions at around 14,000 cal yr BP, which represents the commencement of the last major deglaciation. After the last major deglaciation, the TOC content decreased from 13,300 to 12,000 cal yr BP and from 11,500 to 9800 cal yr BP, thereby reflecting the weakening of the summer monsoon. The LGM in Jeju Island occurred later in comparison with the Chinese Loess Plateau. Such a disparity in climatic change events between central China and Jeju Island appears to be caused by the asynchrony between the coldest temperature event and the minimum precipitation event in central China and by the buffering effect of the Pacific Ocean.  相似文献   

Three‐dimensional simulation of tsunami run‐up around conical island     

Byung Ho Choi  Dong Chule Kim  Efim Pelinovsky  Seung Buhm Woo 《Coastal Engineering》2007

At the circular Babi Island in the Flores tsunami (1992) and pear shaped island in the Okushiri event (1993), unexpectedly large tsunami run‐up heights in the lee of conic islands were observed. The flume and basin physical model studies were conducted in the Coastal Hydraulic Laboratory, Engineering Research and Development Center, U.S. Army Corps of Engineers to provide a better understanding of the physical phenomena and verify numerical models used in predicting tsunami wave run‐up on beaches, islands, and vertical walls. Reasonably accurate comparison of run‐up height of solitary waves on a circular island has been obtained between laboratory experimental results and two‐dimensional computation model results. In this study we apply three‐dimensional RANS model to simulate wave run‐up on conical island. In the run‐up computation we obtain that 3D calculations are in very good comparison with laboratory and 2D numerical results. A close examination of the three‐dimensional velocity distribution around conical island to compare with depth‐integrated model is performed. It is shown that the velocity distribution along the vertical coordinate is not uniform: and velocity field is weaker in the bottom layer and higher on the sea surface. The maximum difference (about 40%) appears at the time when solitary wave reached the circular island.  相似文献   

Robust diagnostic modeling of the Japan Sea circulation   总被引：1，自引：0，他引：1  

Y. H. Seung  J. -H. Yoon 《Journal of Oceanography》1995,51(4):421-440

The Japan Sea circulation is numerically modeled with robust diagnostic terms included. The general features are nearly the same as previous prognostic models though small differences appear in local current fields, and agree with most of existing observation results. This model, however, seems to be more successful than prognostic ones in that the overshooting of the East Korean Warm Current, a northward western boundary current, is much reduced and the North Korean Cold Current, a southward western boundary current, is more enhanced. Based on the model results, discussions are made about the large convective structure and the global kinetic energy budget of the Japan Sea circulation.  相似文献   

Species composition and spatial distribution of euphausiids of the yellow sea and relationships with environmental factors   总被引：1，自引：0，他引：1  

Won Duk Yoon  Joon Yong Yang  Donghyun Lim  Sung Hwan Cho  Gyung Soo Park 《Ocean Science Journal》2006,41(1):11-29

We investigated species composition and spatial distribution of the euphausiid community in the Yellow Sea and identified the relationship with environmental factors (temperature, salinity, chlorophyll a, nitrate, phosphate, and silicate) using bimonthly data from June, 1997 to April, 1998. The environment varied during the sampling period. In warm seasons, thermocline was well developed rendering lower temperature and higher salinity and nutrient concentrations in the bottom layer. During cold seasons the water column was well mixed and no such vertical stratification was noted. Horizontal distribution of temperature, however, differed slightly between near-coast and offshore areas because of the shallow depth of the Yellow Sea, and between southern and northern areas because of the intrusion of water masses such as Yellow Sea Warm Current and Changjiang River Diluted Water. Four euphausiid species were identified:Euphausia pacifica, E. sanzoi, Pseudeuphausia sp. andStylocheron affine. E. sanzoi andS. affine were collected, just one juvenile each, from the southern area in June and December, respectively.Pseudeuphausia sp. were collected in the eastern area all the year round except June.E. pacifica occurred at the whole study area and were the predominant species, representing at least 97.6% of the euphausiid abundance. Further, the distribution pattern of the species was varied in regards to developmental stages (adult, furcilia, calyptopis, egg). From spring to fall,E. pacifica adults were abundant in the central area where the Yellow Sea Bottom Cold Water prevailed. Furcilia and calyptopis extended their distribution into nearly all the study area during the same period. From late fall to winter, adults were found at the near-coastal area with similar pattern for furcilia and calyptopis. The distribution pattern ofE. pacifica was consistent regarding temperature, salinity, and three nutrients during the sampling period, whereas chlorophyll a showed a different pattern according to the developmental stages. The nutrients should indirectly affect via chlorophyll a and phytoplankton concentration. With respect to these results, we presented a scenario about how the environmental factors along with the water current affect the distribution ofE. pacifica in the Yellow Sea.  相似文献   

The origin and biogeochemistry of organic matter in surface sediments of Lake Shihwa and Lake Hwaong     

Eun -Ji Won  Hyen -Goo Cho  Kyung -Hoon Shin 《Ocean Science Journal》2007,42(4):223-230

To understand the origin and biogeochemistry of the organic matter in surface sediments of Lake Shihwa and Lake Hwaong, organic nitrogen, inorganic nitrogen, labile organic carbon, and residual organic carbon contents as well as stable isotope ratios for carbon and nitrogen were determined by KOBr-KOH treatment. Ratios of organic carbon to organic nitrogen (C_org/N_org) (mean = 24) were much higher than ratios of organic carbon to total nitrogen (C_org/N_tot) (mean=12), indicating the presence of significant amounts of inorganic nitrogen in the surface sediments of both lakes. Stable isotope ratios for organic nitrogen were, on average, 5.2‰ heavier than ratios of inorganic nitrogen in Lake Shihwa, but those same ratios were comparable in Lake Hwaong. This might be due to differences in the origin or the degree of degradation of sedimentary organic matter between the two lakes. In addition, stable isotope ratios for labile organic carbon were, on average, 1.4‰ heavier than those for residual organic carbon, reflecting the preferential oxidation of¹³C-enriched organic matter. The present study demonstrates that KOBr-KOH treatment of sedimentary organic matter can provide valuable information for understanding the origin and degradation state of organic matter in marine and brackish sediments. This also suggests that the ratio of C_org/N_org and stable isotope ratios for organic nitrogen can be used as indexes of the degree of degradation of organic matter.  相似文献   

Seismic analysis of base-isolated liquid storage tanks using the BE–FE–BE coupling technique     

Moon Kyum Kim  Yun Mook Lim  Seong Yong Cho  Kyung Hwan Cho  Kang Won Lee 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):1151-1158

A three-dimensional soil–structure–liquid interaction problem is numerically simulated in order to analyze the dynamic behavior of a base-isolated liquid storage tank subjected to seismic ground motion. A dynamic analysis of a liquid storage tank is carried out using a hybrid formulation, which combines the finite shell elements for structures and the boundary elements for liquid and soil. The system is composed of three parts: the liquid–structure interaction part, the soil–foundation interaction part, and the base-isolation part. In the liquid–structure interaction part, the tank structure is modeled using the finite elements and the liquid is modeled using the internal boundary elements, which satisfy the free surface boundary condition. In the soil–foundation interaction part, the foundation is modeled using the finite elements and the half-space soil media are modeled using the external boundary elements, which satisfy the radiation condition in the infinite domain. Finally, above two parts are connected with the base-isolation system to solve the system's behavior. Numerical examples are presented to demonstrate the accuracy of the developed method, and an earthquake response analysis is carried out to demonstrate the applicability of the developed technique. The properties of a real LNG tank located in the west coast of Korea are used. The effects of the ground and the base-isolation system on the behavior of the tank are analyzed.  相似文献   

Landslide susceptibility analysis using GIS and artificial neural network     

Saro Lee  Joo‐Hyung Ryu  Kyungduck Min  Joong‐Sun Won 《地球表面变化过程与地形》2003,28(12):1361-1376

The purpose of this study is to develop landslide susceptibility analysis techniques using an arti?cial neural network and to apply the newly developed techniques to the study area of Yongin in Korea. Landslide locations were identi?ed in the study area from interpretation of aerial photographs, ?eld survey data, and a spatial database of the topography, soil type and timber cover. The landslide‐related factors (slope, curvature, soil texture, soil drainage, soil effective thickness, timber age, and timber diameter) were extracted from the spatial database. Using those factors, landslide susceptibility was analysed by arti?cial neural network methods. The landslide susceptibility index was calculated by the back‐propagation method, which is a type of arti?cial neural network method, and the susceptibility map was made with a geographic information system (GIS) program. The results of the landslide susceptibility analysis were veri?ed using landslide location data. The validation results showed satisfactory agreement between the susceptibility map and the existing data on landslide location. A GIS was used to ef?ciently analyse the vast amount of data, and an arti?cial neural network to be an effective tool to maintain precision and accuracy. The results can be used to reduce hazards associated with landslides and to plan land use and construction. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Assessing Winter Wheat Responses to Climate Change Scenarios: A Simulation Study in the U.S. Great Plains   总被引：3，自引：0，他引：3  

Albert Weiss  Cynthia J. Hays  Jaepil Won 《Climatic change》2003,58(1-2):119-147

Hard red winter wheat (Triticum aestivum L.) is a major crop in the Great Plains region of the U.S. The goal of this assessment effort was to investigate the influence of two contrasting global climate change projections (U.K. Hadley Center for Climate Prediction and Research and Canadian Centre for Climate Modelling and Analysis) on the yield and percent kernel nitrogen content of winter wheat at three locations in Nebraska. These three locations represent sub-humid and semi arid areas and the transition between these areas and are also representative of major portions of the winter wheat growing areas of the central Great Plains. Climate scenarios based on each of the projections for each location were developed using the LARS-WG weather generator along with data from automated weather stations. CERES-Wheat was used to simulate the responses for two contrasting cultivars of wheat using two sowing dates. The first sowing date represented current sowing dates appropriate for each location. The second sowing date was later and represents the approximate date when the mean air temperature from the climate scenarios is the same as the mean air temperature from the actual climate data at the current sowing dates. The yield and percent kernel nitrogen content using the two climate scenarios generally decrease going from the sub-humid eastern to the semi arid western parts of Nebraska. Results from these simulations indicate that yield and percent kernel nitrogen content using the two climate scenarios could not both be maintained at levels currently simulated. Protein content (directly related to kernel nitrogen content) and end-use quality are the primary determinants for the use of hard red winter wheat in baked goods. Nitrogen management and new cultivars, which can enhance the uptake and translocation of nitrogen, will be proactive steps to meet the challenges of global climate change as represented by these climate scenarios.  相似文献