Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

太阳发电机理论研究进展     

姜杰  汪景琇 《天文学进展》2005,23(2):121-134

太阳发电机理论主要解释太阳磁场的起源和演化，是太阳物理中最基本、最重要的问题之一．对它的研究不仅具有重要的科学价值，而且对空间天气的预测和空间技术的发展有一定的影响．随着日震学的发展，该理论也得到了很大改进。从相关观测入手，综述了发电机理论需解释的观测事实，以及为发电机理论提供约束的太阳内部动力学结构；介绍了基本理论和近来的主流模型，并指出尚待解决的问题和进一步的努力方向。  相似文献   

海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

Three Super Active Regions in the Descending Phase of Solar Cycle 23   总被引：2，自引：0，他引：2  

Hong-Qi Zhang  Xing-Ming Bao  Yin Zhang  Ji-Hong Liu  Shu-Dong Bao  Yuan-Yong Deng  Wei Li  Jie Chen  Jin-Ping Dun  Jiang-Tao Su  Juan Guo  Xiao-Fan Wang  Ke-Liang Hu  Gang-Hua Lin  Dong-Guang WangNational Astronomical Observatories  Chinese Academy of Sciences  Beijing   《中国天文和天体物理学报》2003,3(6):491-494

We analyze the magnetic configurations of three super active regions, NOAA 10484, 10486 and 10488, observed by the Huairou Multi-Channel Solar Telescope (MCST) from 2003 October 18 to November 4. Many energetic phenomena, such as flares (including a X-28 flare) and coronal mass ejections (CMEs), occurred during this period. We think that strong shear and fast emergence of magnetic flux are the main causes of these events. The question is also of great interest why these dramatic eruptions occurred so close together in the descending phase of the solar cycle.  相似文献   

Tidal effects on temperature front in the Yellow Sea   总被引：5，自引：0，他引：5  

Ma Jian  Qiao Fangli  Xia Changshui  Yang Yongzeng 《中国海洋湖沼学报》2004,22(3):314-321

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).  相似文献   

The influence of a non‐associated flow rule on the calculation of the factor of safety of soil slopes     

Yu‐Jie Wang  Jian‐Hua Yin  C. F. Lee 《国际地质力学数值与分析法杂志》2001,25(13):1351-1359

This paper presents a method that incorporates a non‐associated flow rule into the limit analysis to investigate the influence of the dilatancy angle on the factor of safety for the slope stability analysis. The proposed method retain's the advantage of the upper bound method, which is simple and has no stress involvement in the calculation of the energy dissipation and the factor of safety. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

PALEOSOLS　OF　SANDY　LANDS　AND　ENVIRONMENTAL　CHANGES　IN　THE　WESTERN　PART　OF　NORTHEAST　PLAIN　OF　CHINA　WESTERN　DURING　HOLOCENE     

裘善文  李取生  夏玉梅  王景璐 《中国地理科学(英文版)》1995,5(2):137-148

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...  相似文献   

Remarks on dynamical ellipticity at the Earth's     

C. Z. Zhang  Y. F. Xia 《Earth, Moon, and Planets》1994,65(3):269-276

In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series.  相似文献   

Early warning research on salt-alkalization desertification in western Songnen Plain     

BIAN Jian-min  LIN Nian-feng  TANG Jie College of Environment  Resources  Jilin  University  Changchun  Jilin  China 《东北亚地学研究》2005,(Z1)

Desertification is an environmental issue in the world. The salt-alkalization desertification land area formed by both primary and secondary salt-alkalization has extended in a large scale, which has become a significant eco-environmental problem. Based on the characteristics of eco-environment and the situation of desertification in western Songnen plain, this paper reports the analyzes of its formation in background and cause. An early warning system on the salt-alkalization desertification is established and the GIS technology is used to abstract the information of desertification evaluation index. Supported by the integrated technology of the GIS and ANN, the orientation and quantitative result of desertification are gained, which is helpful to the eco-environment protection and resource development in western Songnen Plain.  相似文献   

VPN技术在浙江省气象网络中的应用   总被引：2，自引：0，他引：2  

吴孟春  马奇蔚  周必高  周捷  周翔 《成都信息工程学院学报》2006,21(4):551-554

随着浙江省气象业务的不断发展，网络数据交换日益增多，同时更多基于网络的气象业务的增加，如网络视频会商、自动站数据传输等，使目前浙江省气象系统专线网络运行已达到极限，所以需要建立VPN网以对现有的网络作链路上的备份，而VPN的建立同时还可以实现移动办公，领导能在远程调用内网的资料进行远程决策服务和汇报工作。主要介绍VPN技术并叙述VPN技术在浙江省气象系统网络中的具体应用。  相似文献