Geochemical fixation of rare earth elements into secondary minerals in sandstones beneath a natural fission reactor at Bangombé, Gabon     

Hiroshi Hidaka  Janusz Janeczek  Rodney C. Ewing 《Geochimica et cosmochimica acta》2005,69(3):685-694

To study geochemical processes for migration and fixation of fissiogenic rare earth elements (REE) in association with uranium dissolution, in situ isotopic analyses using an ion microprobe were performed on U- and REE-bearing secondary minerals, such as coffinite, françoisite, uraniferous goethite, and uraninite found in a sandstone layer 30 to 110 cm beneath a natural fission reactor at Bangombé, Gabon. Phosphate minerals such as phosphatian coffinite and françoisite with depleted ²³⁵U (²³⁵U/²³⁸U = 0.00609 to 0.00638) contained large amount of fissiogenic light REE, while micro-sized uraninite grains in a solid bitumen aggregate have normal U isotopic values (²³⁵U/²³⁸U = 0.00725) and small amount of fissiogenic REE components. The proportions of fissiogenic and non-fissiogenic REE components in four samples from the core of BAX03 vary in depth ranging from 30 cm to 130 cm beneath the reactor, which suggests mixing between fissiogenic isotopes from the reactor and non-fissiogenic isotopes from original minerals in the sandstone. Significant chemical fractionation was observed between Ce and the other REE in the secondary minerals, which shows evidence of an oxidizing atmosphere during their formation. Pb-isotopic analyses of individual minerals do not directly provide chronological information because of the disturbance of U-Pb decay system due to recent geologic alteration. However, systematic Pb-isotopic results from all of the minerals reveal the mobilization of fissiogenic isotopes, Pb and U from the reactor in association with dolerite dyke intrusion ∼0.798 Ga ago and the formation of the secondary minerals by mixing event between 2.05 Ga-old original minerals and reactor materials due to recent alteration.  相似文献   

Nuclide analyses of rare earth elements of the Oklo uranium ore samples: a new method to estimate the neutron fluence     

Hiroshi Hidaka  Akimasa Masuda 《Earth and Planetary Science Letters》1988,88(3-4)

Isotopic ratios and abundances of all REE in two Oklo ore samples have been measured. We have succeeded in developing a new method to estimate the neutron fluence, the conversion factor of uranium and the average neutron energy (or temperature) based on Gd and U isotopic ratios. This new calculation is found to be useful in evaluating those parameters for the natural nuclear reactors at Oklo. Comparison is made between the neutron fluence values evaluated by our new method employing Gd isotopes and a previous one [11] employing Sm and Nd isotopes. The relative agreement becomes better with the increase of fluence. A relationship between the abundances of fissiongenic nuclides of La, Ce, Nd, Sm, and Gd and their mass numbers is also presented.  相似文献   

∼3,850 Ma tonalites in the Nuuk region,Greenland: geochemistry and their reworking within an Eoarchaean gneiss complex     

Allen P. Nutman  Vickie C. Bennett  Clark R. L. Friend  Kenji Horie  Hiroshi Hidaka 《Contributions to Mineralogy and Petrology》2007,154(4):385-408

The Eoarchaean (>3,600 Ma) Itsaq Gneiss Complex of southern West Greenland is dominated by polyphase orthogneisses with a complex Archaean tectonothermal history. Some of the orthogneisses have c. 3,850 Ma zircons, and they vary from rare single phase metatonalites to more common complexly banded migmatites. This is due to heterogeneous strain, in situ anatexis and granitic veining superimposed during younger tectonothermal events. In the single-phase tonalites with c. 3,850 Ma zircon, oscillatory-zoned prismatic zircon is all 3,850 Ma old, but shows patchy ancient loss of radiogenic Pb. SHRIMP spot analyses and laser ablation ICP-MS depth profiling show that thin (usually < 10 μm) younger (3,660–3,590 Ma and Neoarchaean) shells of lower Th/U metamorphic zircon are present on these 3,850 Ma zircons. Several samples with this simple zircon population occur on islands near Akilia. In contrast, migmatites usually contain more complex zircon populations, with often more than one generation of igneous zircon present. Additional zircon dating of banded gneisses across the Complex shows that samples with c. 3,850 Ma igneous zircon are not just a phenomenon restricted to Akilia and adjacent islands. For example, migmatites from Itilleq (c. 65 km from Akilia) contain variable amounts of oscillatory-zoned 3,850 Ma and 3,650 Ma zircon, interpreted, respectively, as the rock age and the time of crustal melting under Eoarchaean metamorphism. With only 110–140 ppm Zr in the tonalites and likely magmatic temperatures of >850°C, zircon solubility–melt composition relationships show that they were only one-third saturated in zircon. Any zircon entrained in the precursor magmas would thus have been highly soluble. Combined with the cathodoluminesence imaging, this demonstrates that the c. 3,850 Ma oscillatory zoned zircon crystallised out of the melt and hence gives a magmatic age. Thus the rare well-preserved tonalites and palaeosome in migmatites testify that c. 3,850 Ma quartzo–feldspathic rocks are a widespread (but probably minor) component in the Itsaq Gneiss Complex. C. 3,850 Ma zircon with negative Eu anomalies (showing growth in felsic systems) also occurs as detrital grains in rare c. 3,800 Ma metaquartzites and as inherited grains in some 3,660 Ma granites (sensu stricto). These demonstrate that still more c. 3,850 Ma rocks were present, but were recycled into Eoarchaean sediments and crustally derived granites. The major and trace element characteristics (e.g. LREE enrichment, HREE depletion, low MgO) of the best-preserved c. 3,850 Ma rocks are typical of Archaean TTG suites, and thus argue for crust formation processes involving important contributions from melting of hydrated mafic crust to the earliest Archaean. Five c. 3,850 Ma tonalites were selected as the best preserved on the basis of field criteria and zircon petrology. Four of these samples have overlapping initial ɛ_Nd (3,850 Ma) values from +2.9 to +3.6± 0.5, with the fourth having a slightly lower value of +0.6. These data provide additional evidence for a markedly LREE-depleted early terrestrial mantle reservoir. The role of c. 3,850 Ma crust should be considered in interpreting isotope signatures of the younger (3,800–3,600 Ma) rocks of the Itsaq Gneiss Complex. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Quantitative distribution of late Cenozoic volcanic materials in Japan     

Arata Sugimura  Tokihiko Matsuda  Kiyotaka Chinzei  Kazuaki Nakamura 《Bulletin of Volcanology》1963,26(1):125-140

The late Cenozoic orogeny in Japan is briefly reviewed. Amounts of volcanic materials in the three periods of the orogeny are estimated at: early Neogene 150 × 10³ km³ (mafic 40 %, salic 60 %), middle and late Neogene 20 × 10³ km³ (mafic 70 %, salic 30 %), Quaternary 5 × 10³ km³ (mafic 80 %, salic 20 %). The largest volume per unit time is in the early Neogene, and the smallest in the middle and late Neogene. Volume per unit area becomes larger towards the southeastern margin or «front» of the volcanic belt. Thermal energy transported by volcanic materials is compared with the terrestrial heat flow in the belt.  相似文献   

Obituary     

Koji Hidaka 《Journal of Oceanography》1976,32(2):51-52

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Sponge and coral zooxanthellae in heat and light: preliminary results of photochemical efficiency monitored with pulse amplitude modulated fluorometry     

Christine H. L. Schönberg  Ryota Suwa  Michio Hidaka  & William Kok Weng Loh 《Marine Ecology》2008,29(2):247-258

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Cathodoluminescence of high-pressure feldspar minerals as a shock barometer          下载免费PDF全文

Masahiro Kayama  Toshimori Sekine  Naotaka Tomioka  Hirotsugu Nishido  Yukako Kato  Kiyotaka Ninagawa  Takamichi Kobayashi  Akira Yamaguchi 《Meteoritics & planetary science》2018,53(7):1476-1488

Cathodoluminescence (CL) analyses were carried out on maskelynite and lingunite in L6 chondrites of Tenham and Yamato-790729. Under CL microscopy, bright blue emission was observed in Na-lingunite in the shock veins. Dull blue-emitting maskelynite is adjacent to the shock veins, and aqua blue luminescent plagioclase lies farther away. CL spectroscopy of the Na-lingunite showed emission bands centered at ~330, 360–380, and ~590 nm. CL spectra of maskelynite consisted of emission bands at ~330 and ~380 nm. Only an emission band at 420 nm was recognized in crystalline plagioclase. Deconvolution of CL spectra from maskelynite successfully separated the UV–blue emission bands into Gaussian components at 3.88, 3.26, and 2.95 eV. For comparison, we prepared K-lingunite and experimentally shock-recovered feldspars at the known shock pressures of 11.1–41.2 GPa to measure CL spectra. Synthetic K-lingunite has similar UV–blue and characteristic yellow bands at ~550, ~660, ~720, ~750, and ~770 nm. The UV–blue emissions of shock-recovered feldspars and the diaplectic feldspar glasses show a good correlation between intensity and shock pressure after deconvolution. They may be assigned to pressure-induced defects in Si and Al octahedra and tetrahedra. The components at 3.88 and 3.26 eV were detectable in the lingunite, both of which may be caused by the defects in Si and Al octahedra, the same as maskelynite. CL of maskelynite and lingunite may be applicable to estimate shock pressure for feldspar-bearing meteorites, impactites, and samples returned by spacecraft mission, although we need to develop more as a reliable shock barometer.  相似文献   

MicroRaman spectroscopy of anomalous planar microstructures in quartz from Mt. Oikeyama: Discovery of a probable impact crater in Japan     

Masao SAKAMOTO  Arnold GUCSIK  Hirotsugu NISHIDO  Kiyotaka NINAGAWA  Tasuku OKUMURA  Shin TOYODA 《Meteoritics & planetary science》2010,45(1):32-42

Abstract– Planar deformation features (PDFs) and planar fractures (PFs) have been found and confirmed by optical microscope observations and microRaman spectroscopy in quartz grains from Mt. Oikeyama (Akaishi Mountains, Central Japan), for which the semicircular topographic feature of the ridge suggests a crater formed by an impact event. According to the optical microscope observations, a low shock pressure (8–10 GPa) is estimated by the occurrence of basal or ω PDFs leading to lack of multiple sets of PDFs. In addition, a new type of planar microstructure was found in several quartz grains. The microRaman characteristics of PDFs in quartz from Mt. Oikeyama show the amorphous state indicating the presence of weak broad bands at 400 and 800 cm^?1 peak positions. These characteristics are indicative of PDFs that are limited to shocked quartz. This indicates an impact origin for distinct planar microstructures in quartz from Mt. Oikeyama.  相似文献   

Neutron capture records of mesosiderites and an iron meteorite     

Hiroshi Hidaka  Shigekazu Yoneda 《Geochimica et cosmochimica acta》2011,75(19):5706-5715

The Sm and Gd isotopic compositions of silicates from six mesosiderites (Dalgaranga, Estherville, Morristown, Northwest Africa (NWA) 1242, NWA 2932, and Vaca Muerta) and one iron meteorite (Udei Station) were determined to elucidate the cosmic-ray exposure records. All seven samples showed significant ¹⁵⁰Sm/¹⁴⁹Sm and ¹⁵⁸Gd/¹⁵⁷Gd isotopic shifts from neutron capture reactions corresponding to neutron fluences of (1.3-21.8) × 10¹⁵ n cm⁻². In particular, Vaca Muerta showed a significantly higher neutron fluences than the other six samples. The parameter for the degree of neutron thermalization (ε_Sm/ε_Gd) also showed a significant difference between Vaca Muerta (0.76) and the other samples (0.93-1.20). These results suggest a two-stage irradiation of the Vaca Muerta silicates in the parent body (>50 Ma) before formation of the mesosiderite and during its transit to Earth (138 Ma). This is consistent with the ⁸¹Kr-Kr cosmic-ray exposure age data of a Vaca Muerta pebble from a previous noble gas isotopic study.  相似文献   

Binary and triple collisions causing instability in the free-fall three-body problem     

Hiroaki Umehara  Kiyotaka Tanikawa 《Celestial Mechanics and Dynamical Astronomy》2000,76(3):187-214

Dominant factors for escape after the first triple-encounter are searched for in the three-body problem with zero initial velocities and equal masses. By a global numerical survey on the whole initial-value space, it is found that not only a triple-collision orbit but also a particular family of binary-collision orbits exist in the set of escape orbits. This observation is justified from various viewpoints. Binary-collision orbits experiencing close triple-encounter turn out to be close to isosceles orbits after the encounter and hence lead to escape. Except for a few cases, binary-collision orbits of near-isosceles slingshot also escape. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献