Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2     

Irvine WM  Friberg P  Hjalmarson A  Ishikawa S  Kaifu N  Kawaguchi K  Madden SC  Matthews HE  Ohishi M  Saito S  Suzuki H  Thaddeus P  Turner BE  Yamamoto S  Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   

Comparisons of modelled and observed climate for impact assessments     

P. J. Robinson  A. N. Samel  G. Madden 《Theoretical and Applied Climatology》1993,48(2-3):75-87

Summary Comparisons between observed and modelled values of surface temperature, surface precipitation and 500 hPa height for the current climate were made for the southeast United States. Daily values and analyses pertinent to impact assessment, were emphasized. For the model, the time-independent 10-year series of values developed by the Geophysical Fluid Dynamics Laboratory general circulation model were used. Observations were drawn from records for various stations and decades within the model grid-cell. Cumulative frequency distributions of temperature indicated both more clustering close to the mean and greater extremes for the model. The model reproduced the seasonal cycle of day-to-day temperature variability, but introduced a phase shift of about four months. One result was an apparent overabundance of hot spells in the model results. For precipitation the model indicated twice as many raindays as were observed, about the same number of days when precipitation exceeded 5 mm, and fewer days with amounts exceeding 10 mm, effectively decreasing the probability of heavy precipitation while enhancing annual totals. In winter the model appeared to represent the results from an aggregation of stations within the grid-cell, but in summer it was closer to individual station results. The model reproduced the seasonal cycle in the height and standard deviation of the 500 hPa surface, with a damped amplitude in both cases.With 9 Figures  相似文献   

More earliest isotopically dated Mammuthus from North America     

Cary T. Madden 《Quaternary Research》1983,19(2):275-277

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Geomorphic analysis reveals active tectonic deformation on the eastern flank of the Pir Panjal Range,Kashmir Valley,India     

Shabir Ahmad  M. I. Bhat  Christopher Madden  B. S. Bali 《Arabian Journal of Geosciences》2014,7(6):2225-2235

There are plenty of faults that show evidence that they are active. Most of the valley’s floor is occupied by unconsolidated Karewa deposits, in particular on the south–southwest of the Kashmir Valley. In such situations, geomorphic data can reveal the location of active faults. Accordingly, we tried to identify geomorphic indices in SW of the Kashmir Valley (Veshav, Rambiara, and Romushi drainage basins), which revealed the area to be potentially tectonically active. This active faulting was further substantiated by drainage anomalies and field investigations, which provides evidence for an emergent out-of-sequence NE-dipping active reverse fault (identified first time on ground) named the Balapur Fault (BF). The BF can be traced over at least 40 km along the southwest side of the Kashmir Valley. The existence of the active Balapur Fault and of two other inferred faults north of the Panjal Thrust or Murree Thrust presents a picture of a more complex strain-partitioning regime in the Kashmir Himalayas than is usually visualized.  相似文献   

The RHESSI Spectrometer   总被引：2，自引：0，他引：2  

Smith  D.M.  Lin  R.P.  Turin  P.  Curtis  D.W.  Primbsch  J.H.  Campbell  R.D.  Abiad  R.  Schroeder  P.  Cork  C.P.  Hull  E.L.  Landis  D.A.  Madden  N.W.  Malone  D.  Pehl  R.H.  Raudorf  T.  Sangsingkeow  P.  Boyle  R.  Banks  I.S.  Shirey  K.  Schwartz  Richard 《Solar physics》2002,210(1-2):33-60

RHESSI observes solar photons over three orders of magnitude in energy (3 keV to 17 MeV) with a single instrument: a set of nine cryogenically cooled coaxial germanium detectors. With their extremely high energy resolution, RHESSI can resolve the line shape of every known solar gamma-ray line except the neutron capture line at 2.223 MeV. High resolution also allows clean separation of thermal and non-thermal hard X-rays and the accurate measurement of even extremely steep power-law spectra. Detector segmentation, fast signal processing, and two sets of movable attenuators allow RHESSI to make high-quality spectra and images of flares across seven orders of magnitude in intensity. Here we describe the configuration and operation of the RHESSI spectrometer, show early results on in-flight performance, and discuss the principles of spectroscopic data analysis used by the RHESSI software.  相似文献   

The relation of conducting polymer actuator material properties to performance     

Madden  P.G.A. Madden  J.D.W. Anquetil  P.A. Vandesteeg  N.A. Hunter  I.W. 《Oceanic Engineering, IEEE Journal of》2004,29(3):696-705

Materials used in many branches of engineering are of low molecular weight and not flexible. As we develop more sophisticated engineering devices one can look to nature for inspiration and advocate the use of high molecular weight flexible materials. Conducting polymer actuators will soon be used in applications where traditional low molecular weight actuator systems are incapable of mimicking the functionality provided by nature's muscle. To incorporate conducting polymer actuators into engineering systems it is of high importance to not only model and predict the behavior of these actuators but also understand the connection of material properties to performance. In this paper, the importance of fundamental actuation mechanisms and the fundamental material properties of conducting polymer muscles such as ionic diffusion rate, electrochemical operating window, strain to charge ratio, ratio of charge carried by positive versus negative ions, and salt draining are discussed and their effect on performance is demonstrated. The relevance of engineered geometry to the performance of conducting polymer muscles is also shown. Our understanding of what limits the performance of existing conducting polymers actuators provides directions for the improvement of the next generation of conducting polymer actuators.  相似文献   

The Low Metallicity ISM of Dwarf Galaxies     

Suzanne C. Madden 《Astrophysics and Space Science》2002,281(1-2):247-252

The properties of the low metallicity environments of dwarf galaxies are studied through dust observations in conjunction with the FIR fine-structure cooling lines. There is a striking enhancement of the I[CII]/I(CO) in dwarf galaxies that is explained by the decreased attenuation of the UV light in molecular clouds. An important consequence is that a significant mass of the molecular gas mass inventory can be missed through CO observations alone. Modeling the infrared spectral energy distribution into submillimeter wavelengths in dwarf galaxies reveals the presence of very cold (∼ 8K) dust,which accounts for a large fraction of the dust mass, until now missed by models using IRAS observations alone. In spite of the striking defficiency of the mid-infrared aromatic band carriers, cooling in the photodissociation regions, via [CII] line emission is a very efficient process. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

Comment on 'Generalized thin sheet analysis in magnetotellurics: an extension of Price's analysis'     

R. P. Ranganayaki  T. R. Madden  Malcolm J. Drury 《Geophysical Journal International》1981,65(1):237-238

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Kinetics of methane clathrate formation and dissociation under Mars relevant conditions     

S.R. Gainey  M.E. Elwood Madden 《Icarus》2012,218(1):513-524

Spectral observations have detected methane within the martian atmosphere (Formisano, V., Atreya, S., Encrenaz, T., Ignatiev, N., Giuranna, M. [2004]. Science 306, 1758–1761; Mumma, M.J. et al. [2009]. Science 323, 1041–1045), however, the origin of the methane has not been determined. Methane clathrate (also referred to as methane hydrate) has been suggested as a potential subsurface reservoir, storing and releasing biologic and/or abiogenic methane. In this study, rates of methane hydrate formation and dissociation were measured experimentally at 234–264 K and 1.4–4.7 MPa to test the clathrate reservoir hypothesis. Initial formation rates range from 4.3 × 10^?6 to 8.1 × 10^?5 mol m^?2 s^?1. Results show decreasing rates of formation over time in individual experiments, indicating initial rapid clathration, followed by diffusion-limited transport of methane into the ice through the previously formed hydrate. These experiments indicate increased pressure results in increased formation rates, likely the result of higher concentration gradients, enhancing the methane diffusion flux into the solid phase. Experiments conducted at elevated temperatures produced faster initial rates of formation, resulting from increased kinetic energy of methane molecules and/or thickening of the Quasi-Liquid Layer. Based on this temperature dependence, the activation energy for methane hydrate formation from ice was determined to be 35.9 kJ/mol. Hydrate dissociation experiments initiated by depressurization or warming at conditions between 222 K and 265 K and 0.1–2.0 MPa were conducted following each formation experiment, yielding methane hydrate dissociation rates from 3.01 × 10^?6 to 9.92 × 10^?5 mol m^?2 s^?1. While both hydrate dissociation and formation showed decreasing instantaneous rates over the course of each experiment, the transition between the initial rate of dissociation and the interpreted diffusion-limited period of continued dissociation was more abrupt than that observed in formation experiments, supporting an ice shielding effect. The initial concentration of methane in the solid phase had a significant effect on hydrate dissociation rates. Higher methane concentrations in the solid phase produce faster initial rates, likely due to increased concentration gradients, thus increasing the diffusion component of dissociation. Increased temperatures also produced faster dissociation rates, yielding an activation energy for dissociation of 32.7 kJ/mol. The rates determined within this study suggest that small near-surface methane hydrate reservoirs are a feasible source for recent methane plumes detected on Mars. Rates of methane release from gas hydrates also indicate that gas hydrate dissociation may have played a role in forming ancient chaos terrain and associated outflow channels.  相似文献   

Supersonic jet formation and propagation in x-pinches     

D. M. Haas  S. C. Bott  J. Kim  D. A. Mariscal  R. E. Madden  Y. Eshaq  U. Ueda  G. Collins IV  K. Gunasekera  F. N. Beg  J. P. Chittenden  N. Niasse  C. A. Jennings 《Astrophysics and Space Science》2011,336(1):33-40

Observations of supersonic jet propagation in low-current x-pinches are reported. X-pinches comprising of four 7.5 ??m diameter tungsten wires were driven by an 80 kA, 50 ns current pulse from a compact pulser. Coronal plasma surrounding the wire cores was accelerated perpendicular to their surface due to the global J×B force, and traveled toward the axis of the x-pinch to form an axially propagating jet. These jets moved towards the electrodes and, late in time (??150 ns), were observed to propagate well above the anode with a velocity of 3.3±0.6×10⁴ m/s. Tungsten jets remained collimated at distances of up to 16 mm from the cross point, and an estimate of the local sound speed gives a Mach number of ??6. This is the first demonstration that supersonic plasma jets can be produced using x-pinches with such a small, low current pulser. Experimental data compares well to three-dimensional simulations using the GORGON resistive MHD code, and possible scaling to astrophysical jets is discussed.  相似文献