Subglacial tunnel valleys in the Alpine foreland: an example from Bern, Switzerland     

Mirjam Dürst Stucki  Regina Reber  Fritz Schlunegger 《Swiss Journal of Geoscience》2010,103(3):363-374

The morphology of the Alpine and adjacent landscapes is directly related to glacial erosion and associated sediment transport. Here we report the effects of glacio-hydrologic erosion on bedrock topography in the Swiss Plateau. Specifically, we identify the presence of subsurface valleys beneath the city of Bern and discuss their genesis. Stratigraphic investigations of more than 4,000 borehole data within a 430 km²-large area reveal the presence of a network of >200 m-deep and 1,000 m-wide valleys. They are flat floored with steep sided walls and are filled by Quaternary glacial deposits. The central valley beneath Bern is straight and oriented towards the NNW, with valley flanks more than 20° steep. The valley bottom has an irregular undulating profile along the thalweg, with differences between sills and hollows higher than 50–100 m over a reach of 4 km length. Approximately 500 m high bedrock highlands flank the valley network. The highlands are dissected by up to 80 m-deep and 500 m-broad hanging valleys that currently drain away from the axis of the main valley. We interpret the valleys beneath the city of Bern to be a tunnel valley network which originated from subglacial erosion by melt water. The highland valleys served as proglacial meltwater paths and are hanging with respect to the trunk system, indicating that these incipient highland systems as well as the main gorge beneath Bern formed by glacial melt water under pressure.  相似文献   

Multi-angle backscatter classification and sub-bottom profiling for improved seafloor characterization     

Evangelos Alevizos  Mirjam Snellen  Dick Simons  Kerstin Siemes  Jens Greinert 《Marine Geophysical Researches》2018,39(1-2):289-306

This study applies three classification methods exploiting the angular dependence of acoustic seafloor backscatter along with high resolution sub-bottom profiling for seafloor sediment characterization in the Eckernförde Bay, Baltic Sea Germany. This area is well suited for acoustic backscatter studies due to its shallowness, its smooth bathymetry and the presence of a wide range of sediment types. Backscatter data were acquired using a Seabeam1180 (180 kHz) multibeam echosounder and sub-bottom profiler data were recorded using a SES-2000 parametric sonar transmitting 6 and 12 kHz. The high density of seafloor soundings allowed extracting backscatter layers for five beam angles over a large part of the surveyed area. A Bayesian probability method was employed for sediment classification based on the backscatter variability at a single incidence angle, whereas Maximum Likelihood Classification (MLC) and Principal Components Analysis (PCA) were applied to the multi-angle layers. The Bayesian approach was used for identifying the optimum number of acoustic classes because cluster validation is carried out prior to class assignment and class outputs are ordinal categorical values. The method is based on the principle that backscatter values from a single incidence angle express a normal distribution for a particular sediment type. The resulting Bayesian classes were well correlated to median grain sizes and the percentage of coarse material. The MLC method uses angular response information from five layers of training areas extracted from the Bayesian classification map. The subsequent PCA analysis is based on the transformation of these five layers into two principal components that comprise most of the data variability. These principal components were clustered in five classes after running an external cluster validation test. In general both methods MLC and PCA, separated the various sediment types effectively, showing good agreement (kappa >0.7) with the Bayesian approach which also correlates well with ground truth data (r²?>?0.7). In addition, sub-bottom data were used in conjunction with the Bayesian classification results to characterize acoustic classes with respect to their geological and stratigraphic interpretation. The joined interpretation of seafloor and sub-seafloor data sets proved to be an efficient approach for a better understanding of seafloor backscatter patchiness and to discriminate acoustically similar classes in different geological/bathymetric settings.  相似文献   

Energy use, climate change and folk psychology: Does sustainability have a chance? Results from a qualitative study in five European countries     

Anke Fischer  Vera PetersJan Vávra  Mirjam NeebeBoldizsár Megyesi 《Global Environmental Change》2011,21(3):1025-1034

Citizens’ support for policies that aim to curb carbon emissions and energy use is often seen as informed by their values, attitudes and perceptions of the environmental problem in question. We argue that we also need to understand how people conceptualise policies and the governance approaches underpinning them to be able to judge the likely acceptance of policy change.In this study, we draw on qualitative interviews (n = 202) from five European countries to explore citizens’ views on governance approaches to stimulate behavioural change in the field of resource use, including regulations, price changes, collective action, technological change and education.We found that many of our interviewees referred to generalised characteristics of humankind and contemporary society to back up their arguments for or against specific governance approaches. In particular, many interviewees concurred that people in general were so self-centred, driven by habit and money- and consumption-oriented that only strict regulations, drastic price changes and technological innovation could possibly achieve widespread behavioural change. As a consequence, such ‘folk psychologies’ can have substantial impact not only on public acceptance, but also on the success of policy measures that aim to reduce citizens’ resource use.  相似文献   

Evaluation of cosmogenic 3He and 21Ne production rates in olivine and pyroxene from two Pleistocene basalt flows,western Grand Canyon,AZ, USA     

Cassandra R. Fenton  Samuel Niedermann  Mirjam M. Goethals  Björn Schneider  Jan Wijbrans 《Quaternary Geochronology》2009,4(6):475-492

Combining cosmogenic ³He and ²¹Ne (³He_c and ²¹Ne_c) measurements on both pyroxene and olivine from the Pleistocene Bar Ten flows (85–107 ka) greatly increases our ability to evaluate the accuracy of ³He_c and ²¹Ne_c production rates and, therefore, ³He_c and ²¹Ne_c surface exposure ages. Comparison of ³He_c and ²¹Ne_c age-pairs yielded by experimentally determined production rates and composition-based model calculations indicates that the former give more accurate surface exposure ages than the latter in this study. However, experimental production rates should be adjusted to the composition of the minerals being analyzed to obtain the best agreement between ³He_c and ²¹Ne_c ages for any given sample. ²¹Ne_c/³He_c values are 0.400 ± 0.029 and 0.204 ± 0.014 for olivine and pyroxene, respectively, in Bar Ten lava flows, in agreement with previously published values, and indicate that ²¹Ne_c/³He_c in olivine and pyroxene is not affected by erosion and remains constant with latitude, elevation, and time (up to 10 Myr). Samples with ²¹Ne_c/³He_c that do not agree with these values may indicate the presence of non-cosmogenic helium and/or neon. The neon three-isotope diagram can also indicate whether or not all excess neon in mineral separates comes from cosmogenic sources. An error-weighted regression for olivine defines a spallation line [y = (1.033 ± 0.031)x + (0.09876 ± 0.00033)], which is indistinguishable from that for pyroxene (Schäfer et al., 1999). We have derived a production rate of 25 ± 8 at/g/yr for ²¹Ne_c in clinopyroxene (En_43–44) based on the ⁴⁰Ar/³⁹Ar age of the upper Bar Ten flow. Our study indicates that the production rate of ²¹Ne_c in olivine may be slightly higher than previously determined. Cosmogenic ³He and ²¹Ne remain extremely useful, particularly when paired, in determining accurate eruption ages of young olivine- and pyroxene-rich basaltic lava flows.  相似文献   

Gravity changes and natural gas extraction in Groningen     

Martin van Gelderen  Roger Haagmans  & Mirjam Bilker 《Geophysical Prospecting》1999,47(6):979-993

Gravity observations made over the Groningen gasfield from 1978 onwards are available. The existing gravity data were reanalysed and a new survey was carried out. The observed gravity changes obtained during four surveys, spanning an 18-year period, were compared with the gravity effect due to natural gas extraction computed from the reservoir model and the production data. The random error in the gravity values is small enough to detect the effect of gas extraction after a few years (up to 2 μgal/year). The trends obtained from observed and calculated gravity changes agree well within their expected error margins after statistical data snooping. Due to the inadequate measurement set-up of the previous surveys, systematic errors present in the gravity data hampered the use of this data for refinement of the reservoir and the production models. However, with improved gravity monitoring, in particular a very systematic network set-up and well-calibrated instruments, this should now be feasible. By using the network analysis from the 1996 measurements for the planning of a network in space and time, most of the current problems can be avoided.  相似文献   

Experimental and computational study of trace element distribution between orthopyroxene and anhydrous silicate melt: substitution mechanisms and the effect of iron     

Mirjam van Kan Parker  Axel Liebscher  Dirk Frei  Jelle van Sijl  Wim van Westrenen  Jon Blundy  Gerhard Franz 《Contributions to Mineralogy and Petrology》2010,159(4):459-473

Although orthopyroxene (Opx) is present during a wide range of magmatic differentiation processes in the terrestrial and lunar mantle, its effect on melt trace element contents is not well quantified. We present results of a combined experimental and computational study of trace element partitioning between Opx and anhydrous silicate melts. Experiments were performed in air at atmospheric pressure and temperatures ranging from 1,326 to 1,420°C in the system CaO–MgO–Al₂O₃–SiO₂ and subsystem CaO–MgO–SiO₂. We provide experimental partition coefficients for a wide range of trace elements (large ion lithophile: Li, Be, B, K, Rb, Sr, Cs, Ba, Th, U; rare earth elements, REE: La, Ce, Nd, Sm, Y, Yb, Lu; high field strength: Zr, Nb, Hf, Ta, Ti; transition metals: Sc, V, Cr, Co) for use in petrogenetic modelling. REE partition coefficients increase from $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 Although orthopyroxene (Opx) is present during a wide range of magmatic differentiation processes in the terrestrial and lunar mantle, its effect on melt trace element contents is not well quantified. We present results of a combined experimental and computational study of trace element partitioning between Opx and anhydrous silicate melts. Experiments were performed in air at atmospheric pressure and temperatures ranging from 1,326 to 1,420°C in the system CaO–MgO–Al₂O₃–SiO₂ and subsystem CaO–MgO–SiO₂. We provide experimental partition coefficients for a wide range of trace elements (large ion lithophile: Li, Be, B, K, Rb, Sr, Cs, Ba, Th, U; rare earth elements, REE: La, Ce, Nd, Sm, Y, Yb, Lu; high field strength: Zr, Nb, Hf, Ta, Ti; transition metals: Sc, V, Cr, Co) for use in petrogenetic modelling. REE partition coefficients increase from $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 to $ D_{\text{Lu}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.109 $ D_{\text{Lu}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.109 , D values for highly charged elements vary from $ D_{\text{Th}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0026 $ D_{\text{Th}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0026 through $ D_{\text{Nb}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0033 $ D_{\text{Nb}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0033 and $ D_{\text{U}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0066 $ D_{\text{U}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0066 to $ D_{\text{Ti}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.058 $ D_{\text{Ti}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.058 , and are all virtually independent of temperature. Cr and Co are the only compatible trace elements at the studied conditions. To elucidate charge-balancing mechanisms for incorporation of REE into Opx and to assess the possible influence of Fe on Opx-melt partitioning, we compare our experimental results with computer simulations. In these simulations, we examine major and minor trace element incorporation into the end-members enstatite (Mg₂Si₂O₆) and ferrosilite (Fe₂Si₂O₆). Calculated solution energies show that R²⁺ cations are more soluble in Opx than R³⁺ cations of similar size, consistent with experimental partitioning data. In addition, simulations show charge balancing of R³⁺ cations by coupled substitution with Li⁺ on the M1 site that is energetically favoured over coupled substitution involving Al–Si exchange on the tetrahedrally coordinated site. We derived best-fit values for ideal ionic radii r ₀, maximum partition coefficients D ₀, and apparent Young’s moduli E for substitutions onto the Opx M1 and M2 sites. Experimental r ₀ values for R³⁺ substitutions are 0.66–0.67 ? for M1 and 0.82–0.87 ? for M2. Simulations for enstatite result in r ₀ = 0.71–0.73 ? for M1 and ~0.79–0.87 ? for M2. Ferrosilite r ₀ values are systematically larger by ~0.05 ? for both M1 and M2. The latter is opposite to experimental literature data, which appear to show a slight decrease in $ r_{0}^{{{\text{M}}2}} $ r_{0}^{{{\text{M}}2}} in the presence of Fe. Additional systematic studies in Fe-bearing systems are required to resolve this inconsistency and to develop predictive Opx-melt partitioning models for use in terrestrial and lunar magmatic differentiation models.  相似文献   

Peculiar Features in the Solar Coronal Hole Occurrence     

Hofer  Mirjam Y.  Storini  Marisa 《Solar physics》2002,207(1):1-10

A good knowledge of coronal hole (CH) evolution in time is relevant for the understanding of the decay and/or the stability of large-scale magnetic fields in the different heliographic latitudinal belts. Using a CH catalogue, mainly compiled from the Hei line (10830 Å) measurements (Sanchez-Ibarra and Barraza-Paredes, 1992, and updated from the NOAA/Boulder Web pages), some characteristics of the CH behaviour in the solar activity cycles 21 and 22 are identified and described. We found: (i) the total number distributions for the isolated and polar coronal holes are similar, (ii) there is a north/south asymmetry, with a northern dominance in the number distribution of the polar coronal holes, (iii) a hint of a 22-year periodicity in the CH behaviour. In addition, two pairs of two isolated CHs with opposite polarity, maximum ages of more than 14 Carrington rotations, separated by about two years, are found during the early decreasing activity phase of each cycle.  相似文献   

Regional Be production rate calibration for the past 12 ka deduced from the radiocarbon-dated Grøtlandsura and Russenes rock avalanches at 69° N, Norway     

Cassandra R. Fenton  Reginald L. Hermanns  Lars H. Blikra  Peter W. Kubik  Charlotte Bryant  Samuel Niedermann  Anette Meixner  Mirjam M. Goethals 《Quaternary Geochronology》2011,6(5):437-452

Two rock avalanches in Troms County – the Grøtlandsura and Russenes – were selected as CRONUS-EU natural cosmogenic ¹⁰Be production-rate calibration sites because they (a) preserve large boulders that have been continuously exposed to cosmic irradiation since their emplacement; (b) contain boulders with abundant quartz phenocrysts and veins with low concentrations of naturally-occurring ⁹Be (typically < 1.5 ppb); and (c) have reliable minimum radiocarbon ages of 11,424 ± 108 cal yr BP and 10,942 ± 77 cal yr BP (1σ), respectively. Quartz samples (n = 6) from these two sites contained between 4.28 × 10⁴ and 5.06 × 10⁴ at ¹⁰Be/g using the 1.387 Myr ¹⁰Be half-life. Determination of these concentrations accounts for topographic and self-shielding, and effects on nuclide production due to isostatic rebound are shown to be negligible. Persistent, constant snow and moss cover cannot be proven, but if taken into consideration they may have reduced ¹⁰Be concentrations by 10%. Using the ¹⁰Be half-life of 1.387 Myr and the Stone scaling scheme, and accounting for snow- and moss-cover, we calculate an error-weighted mean total ¹⁰Be production rate of 4.12 ± 0.19 at/g/yr (1σ). A corresponding error-weighted mean spallogenic ¹⁰Be production rate is 3.96 ± 0.16 at/g/yr (1σ), respectively. These are in agreement within uncertainty with other ¹⁰Be production rates in the literature, but are significantly, statistically lower than the global average ¹⁰Be production rate. This research indicates, like other recent studies, that the production of cosmogenic ¹⁰Be in quartz is lower than previously established by other production-rate calibration projects. Similarly, our findings indicate that regional cosmogenic production rates should be used for determining exposure ages of landforms in order to increase the accuracy of those ages. As such, using the total ¹⁰Be production rate from our study, we determine an error-weighted mean surface-exposure age of a third rock avalanche in Troms County (the Hølen avalanche) to be 7.5 ± 0.3 kyr (1σ). This age suggests that the rock avalanche occurred shortly after the 8.2 kyr cooling event, just as the radiocarbon ages of the Grøtlandsura and Russenes avalanches confirm field evidence that those rock-slope failures occurred shortly after deglaciation.  相似文献   

Iron speciation and isotope fractionation during silicate weathering and soil formation in an alpine glacier forefield chronosequence     

Mirjam Kiczka  Jan G. Wiederhold  Jakob Frommer  Stephan M. Kraemer  Ruben Kretzschmar 《Geochimica et cosmochimica acta》2011,75(19):5559-5573

The chemical weathering of primary Fe-bearing minerals, such as biotite and chlorite, is a key step of soil formation and an important nutrient source for the establishment of plant and microbial life. The understanding of the relevant processes and the associated Fe isotope fractionation is therefore of major importance for the further development of stable Fe isotopes as a tracer of the biogeochemical Fe cycle in terrestrial environments. We investigated the Fe mineral transformations and associated Fe isotope fractionation in a soil chronosequence of the Swiss Alps covering 150 years of soil formation on granite. For this purpose, we combined for the first time stable Fe isotope analyses with synchrotron-based Fe-EXAFS spectroscopy, which allowed us to interpret changes in Fe isotopic composition of bulk soils, size fractions, and chemically separated Fe pools over time in terms of weathering processes. Bulk soils and rocks exhibited constant isotopic compositions along the chronosequence, whereas soil Fe pools in grain size fractions spanned a range of 0.4‰ in δ⁵⁶Fe. The clay fractions (<2 μm), in which newly formed Fe(III)-(hydr)oxides contributed up to 50% of the total Fe, were significantly enriched in light Fe isotopes, whereas the isotopic composition of silt and sand fractions, containing most of the soil Fe, remained in the range described by biotite/chlorite samples and bulk soils. Iron pools separated by a sequential extraction procedure covered a range of 0.8‰ in δ⁵⁶Fe. For all soils the lightest isotopic composition was observed in a 1 M NH₂OH-HCl-25% acetic acid extract, targeting poorly-crystalline Fe(III)-(hydr)oxides, compared with easily leachable Fe in primary phyllosilicates (0.5 M HCl extract) and Fe in residual silicates. The combination of the Fe isotope measurements with the speciation data obtained by Fe-EXAFS spectroscopy permitted to quantitatively relate the different isotope pools forming in the soils to the mineral weathering reactions which have taken place at the field site. A kinetic isotope effect during the Fe detachment from the phyllosilicates was identified as the dominant fractionation mechanism in young weathering environments, controlling not only the light isotope signature of secondary Fe(III)-(hydr)oxides but also significantly contributing to the isotope signature of plants. The present study further revealed that this kinetic fractionation effect can persist over considerable reaction advance during chemical weathering in field systems and is not only an initial transient phenomenon.  相似文献   

Trace element partitioning between ilmenite, armalcolite and anhydrous silicate melt: Implications for the formation of lunar high-Ti mare basalts     

Mirjam van Kan Parker  Wim van Westrenen 《Geochimica et cosmochimica acta》2011,75(15):4179-4193

We performed a series of experiments at high pressures and temperatures to determine the partitioning of a wide range of trace elements between ilmenite (Ilm), armalcolite (Arm) and anhydrous lunar silicate melt, to constrain geochemical models of the formation of titanium-rich melts in the Moon. Experiments were performed in graphite-lined platinum capsules at pressures and temperatures ranging from 1.1 to 2.3 GPa and 1300-1400 °C using a synthetic Ti-enriched Apollo ‘black glass’ composition in the CaO-FeO-MgO-Al₂O₃-TiO₂-SiO₂ system. Ilmenite-melt and armalcolite-melt partition coefficients (D) show highly incompatible values for the rare earth elements (REE) with the light REE more incompatible compared to the heavy REE ( 0.0020 ± 0.0010 to 0.069 ± 0.010 for ilmenite; 0.0048 ± 0.0023 to 0.041 ± 0.008 for armalcolite). D values for the high field strength elements vary from highly incompatible for Th, U and to a lesser extent W (for ilmenite: 0.0013 ± 0.0008, 0.0035 ± 0.0015 and 0.039 ± 0.005, and for armalcolite 0.008 ± 0.003, 0.0048 ± 0.0022 and 0.062 ± 0.03), to mildly incompatible for Nb, Ta, Zr, and Hf (e.g. 0.28 ± 0.05 and : 0.76 ± 0.07). Both minerals fractionate the high field strength elements with D_Ta/D_Nb and D_Hf/D_Zr between 1.3 and 1.6 for ilmenite and 1.3 and 1.4 for armalcolite. Armalcolite is slightly more efficient at fractionating Hf from W during lunar magma ocean crystallisation, with D_Hf/D_W = 12-13 compared to 6.7-7.5 for ilmenite. The transition metals vary from mildly incompatible to compatible, with the highest compatibilities for Cr in ilmenite (D ∼ 7.5) and V in armalcolite (D ∼ 8.1). D values show no clear variation with pressure in the small range covered.Crystal lattice strain modelling of D values for di-, tri- and tetravalent trace elements shows that in ilmenite, divalent elements prefer to substitute for Fe while armalcolite data suggest REE replacing Mg. Tetravalent cations appear to preferentially substitute for Ti in both minerals, with the exception of Th and U that likely substitute for the larger Fe or Mg cations. Crystal lattice strain modelling is also used to identify and correct for very small (∼0.3 wt.%) melt contamination of trace element concentration determinations in crystals.Our results are used to model the Lu-Hf-Ti concentrations of lunar high-Ti mare basalts. The combination of their subchondritic Lu/Hf ratios and high TiO₂ contents requires preferential dissolution of ilmenite or armalcolite from late-stage, lunar magma ocean cumulates into low-Ti partial melts of deeper pyroxene-rich cumulates.  相似文献