Size distribution of colloidal trace metals and organic carbon during a coastal bloom in the Baltic Sea   总被引：1，自引：0，他引：1  

Johan Ingri  Susanna Nordling  Jenny Larsson  Jenny Rnnegrd  Nina Nilsson  Ilia Rodushkin  Ralf Dahlqvist  Per Andersson   rjan Gustafsson 《Marine Chemistry》2004,91(1-4):117-130

The physico-chemical speciation of organic carbon and selected metals was measured during a coastal bloom in Ekhagen Bay, Baltic Sea, using ultrafiltration.One important objective with the study was to see if any depletion of trace metals could be measured in the directly bioavailable fraction (<1000 Da, the soluble low molecular weight fraction, LMW) during a plankton bloom. Filters with five different cut-offs were used (1 kD (1000 Da), 5 kD, 10 kD, 100 kD and 0.22 μm) in order to delineate the size distribution of colloidal organic carbon (COC) and trace metals.During the bloom in May, LMW Al, Co, Cu, Mn and Ni concentrations decreased although the colloidal and particulate concentrations were relatively high. Data show that desorption of colloidal and particulate bound trace metals to the LMW fraction was slower than the process depleting the LMW fraction.Estimates of the maximum active uptake of Cu, Ni and Mn by the phytoplankton, and the loss of non-bioactive Al from the LMW fraction, indicate that processes other than active uptake by phytoplankton must contribute to the observed depletion of trace metals in the LMW fraction. Hence, in order to estimate the bioavailable pool of trace metals for plankton during bloom conditions, these other processes must be understood and quantified.Transparent Exopolymeric Particles (TEP, reflecting sugar-rich phytoplankton exudates) increased around eight times during the plankton bloom. We hypothesize that the formation of TEP is a process that might be important for the transfer of trace metals from the LMW to the particulate fraction during the phytoplankton bloom, but the significance of TEP for this depletion in Baltic Sea surface water remains to be shown.  相似文献   

The POC / Th ratio of settling particles isolated using split flow-thin cell fractionation (SPLITT)     

rjan Gustafsson  Jenny Larsson  Per Andersson  Johan Ingri 《Marine Chemistry》2006,100(3-4):314

The common assumption that the ratio between particulate organic carbon (POC) and particulate ²³⁴Th obtained from shallow sediment traps and filterable particles are representative of the ratio in the total particle settling flux should be treated with caution in view of well-known biases associated with tethered shallow sediment traps and the decoupling between size and settling velocity of many natural particle regimes. To make progress toward reliably constraining the POC / ²³⁴Th ratio on truly settling particles, we have tested here a settling collection technique designed to remove any hydrodynamic bias; split flow-thin cell fractionation (SPLITT). These first results from a North Sea fjord and an open Baltic Sea time-series station indicates that the POC / ²³⁴Th ratio on the more complete particle-settling spectrum, isolated with SPLITT, was higher than the POC / ²³⁴Th ratio obtained simultaneously from tethered shallow sediment traps in seven out of seven parallel deployments with an average factor of 210%. The POC / ²³⁴Th ratio from the SPLITT was either in the same range or higher than that obtained on filtered “bulk” particles. To explain this novel data we hypothesize that the slowest settling fraction is organic-matter rich and does not strongly complex ²³⁴Th (i.e., high POC / ²³⁴Th). We suggest that this ultra-slow sinking fraction is better collected by SPLITT than with tethered sediment traps because of minimized hydrodynamic bias.This was tested using the ratio of POC / Al as a tracer of detrital mineral-ballast influenced settling velocity. The higher POC / Al ratios in SPLITT samples relative to in traps is consistent with the hypothesis that SPLITT is better suited for collecting also the slow-settling component of sinking particles. This important slow-settling component appears to here consist primarily of non-APS/TEP components of plankton exudates or other less-strongly ²³⁴Th-complexing organic matter. Further applications of the SPLITT technique are likely to return increasingly new insights on the composition (including “truly settling” POC / ²³⁴Th) of the total spectrum of particles settling out of the upper ocean.  相似文献   

Distribution of lunar impacts by objects in parabolic low inclination orbits     

Nils Aall Barricelli  Ragnar Thorbjørnsen 《Earth, Moon, and Planets》1978,18(4):479-490

This paper presents a computer investigation extending to the case of parabolic orbits, an earlier investigation conducted by Barricelli and Metcalfe (1969) on lunar impacts by external low eccentricity satellites as a means to interpret the asymmetric distribution of lunar maria. Parabolic orbits can be approximated by two kinds of objects:

1. High eccentricity external satellites may, near periapsis, approach the Moon with orbital velocity and other characteristics closely resembling those of a parabolic orbit.
2. Asteroids and meteoroids approaching the Earth-Moon system with a low velocity may have moved in a nearly parabolic orbit when they reached the lunar distance from the Earth at the time when the impacts which carved the lunar maria took place.

The investigation gives, therefore, not only additional information relevant to the interpretation of the distribution of lunar maria by the satellite impacts hypothesis (in this case high eccentricity ones), but also information about the alternative hypothesis (Wood, 1973) that asteroid impacts rather than satellite impacts were involved.  相似文献   

Alkaline fluid circulation in ultramafic rocks and formation of nucleotide constituents: a hypothesis     

Nils G Holm  Marion Dumont  Magnus Ivarsson  Cécile Konn 《Geochemical transactions》2006,7(1):7-7

Seawater is constantly circulating through oceanic basement as a low-temperature hydrothermal fluid (<150°C). In cases when ultramafic rocks are exposed to the fluids, for instance during the initial phase of subduction, ferromagnesian minerals are altered in contact with the water, leading to high pH and formation of secondary magnesium hydroxide, among other – brucite, that may scavenge borate and phosphate from seawater. The high pH may promote abiotic formation of pentoses, particularly ribose. Pentoses are stabilized by borate, since cyclic pentoses form a less reactive complex with borate. Analyses have shown that borate occupies the 2' and 3' positions of ribose, thus leaving the 5' position available for reactions like phosphorylation. The purine coding elements (adenine, in particular) of RNA may be formed in the same general hydrothermal environments of the seafloor.  相似文献   

A model of the geomagnetic field and its secular variation for epoch 2000 estimated from Ørsted data     

Nils Olsen 《Geophysical Journal International》2002,149(2):454-462

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Age and origin of groundwater resources in the Ararat Valley,Armenia: a baseline study applying hydrogeochemistry and environmental tracers     

Schubert  Michael  Michelsen  Nils  Schmidt  Axel  Eichenauer  Laura  Knoeller  Kay  Arakelyan  Alexander  Harutyunyan  Lilith  Schüth  Christoph 《Hydrogeology Journal》2021,29(7):2517-2527

Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ²H, δ¹⁸O) and radioactive (³⁵S, ³H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (³⁵S), the detected ³H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.

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Flow dynamics,sedimentation and erosion of glacial lake outburst floods along the Middle Pleistocene Scandinavian Ice Sheet (northern central Europe)          下载免费PDF全文

Jutta Winsemann  Petteri Alho  Leena Laamanen  Nils Goseberg  Jörg Lang  Josef Klostermann 《Boreas: An International Journal of Quaternary Research》2016,45(2):260-283

During the Middle Pleistocene late Saalian glaciation of northern central Europe numerous pro‐glacial lakes formed along the southwestern margin of the Scandinavian Ice Sheet. Little is known about the drainage history of these lakes, the pathways of glacial lake outburst floods and their impacts on erosion, sedimentation and landscape evolution. This study investigated the impact of the late Saalian Weser and Münsterland Lake (Germany) outburst floods. In particular, we reconstructed the routing and flow dynamics of the lake outburst flood and analysed the flood related sediments. We employed one‐dimensional hydraulic modelling to calculate glacial lake outburst flood hydrographs. We modelled the flow pathway and local flow conditions along the pathway based on the boundary conditions of two different hydrographs and two different ice‐margin positions. The modelling results were compared with geomorphological and sedimentological field data in order to estimate the magnitude and impact of the flood on erosion and sedimentation. Two major lake drainage events are reconstructed for the study area, during which approximately 90–50 km³ of water was released. Modelling results indicate that the lake outburst floods created a high‐energy flood wave with a height of 35–50 m in confined valley areas that rapidly spread out into the Lower Rhine Embayment eventually flowing into the North Sea basin. The sedimentary record of the outburst floods comprises poorly sorted coarse‐grained gravel bars, long‐wavelength bedforms and sandy bedforms deposited by supercritical and subcritical flows. Some parts of the sandy flood deposits are rich in reworked mammoth bones or mammoth and horse teeth, pointing to reworking of older fluvial sediments, hydraulic concentration and subsequent re‐sedimentation of vertebrate remains. These deposits are preserved in sheltered areas or at high elevations, well above the influence of postglacial fluvial erosion. The flood‐related erosional features include up to 80‐m‐deep scour pools, alluvial channels and streamlined hills.  相似文献   

β-FeOOH · Cl_n (akaganéite) and Fe_1-xO (wüstite) in hot brine from the Atlantis II Deep (Red Sea) and the uptake of amino acids by synthetic β-FeOOH · Cl_n     

Nils G Holm  Michael J Dowler  Tommy Wadsten  Gustaf Arrhenius 《Geochimica et cosmochimica acta》1983,47(8):1465-1470

A yellowish brown precipitate in samples of Red Sea hot brine has been identified as β-FeOOH · Cl_n (akaganéite) by Guinier-Hägg X-ray diffraction techniques, transmission electron microscopy (TEM), electron diffraction and electron excited X-ray fluorescence. Microcrystals of Fe_1-xO (wüstite) were also identified by electron diffraction. Synthetic β-FeOOH · Cl_n characterized by the same techniques was identical with the brine precipitate.Bonding between β-FeOOH · Cl_n and ¹⁴C labeled amino acids is pH dependent: between pH 3 and pH 7.6 amino acids were bound to the extent of 40 to 60% or 0.6 to 0.9 mmol per kg of iron oxide hydroxide. Some selectivity in affinity for different amino acids was observed, however, the effect is insufficient to explain the unusual distribution in the Atlantis II Deep brine reported in the literature.  相似文献   

A three-dimensional geophysical model of the crust in the Barents Sea region: model construction and basement characterization   总被引：2，自引：0，他引：2  

Oliver Ritzmann  Nils Maercklin  Jan Inge Faleide  Hilmar Bungum  Walter D. Mooney  Shane T. Detweiler 《Geophysical Journal International》2007,170(1):417-435

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Lagrangian perturbation theory for rotating magnetic stars     

Kostas Glampedakis  Nils Andersson 《Monthly notices of the Royal Astronomical Society》2007,377(2):630-644

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