Crystallization of authigenic carbonates in mud volcanoes at Lake Baikal   总被引：1，自引：0，他引：1  

A. A. Krylov  O. M. Khlystov  T. I. Zemskaya  H. Minami  A. Hachikubo  H. Shoji  M. Kida  T. P. Pogodaeva  L. Naudts  J. Poort 《Geochemistry International》2008,46(10):985-995

This paper presents data on authigenic siderite first found in surface sediments from mud volcanoes in the Central (K-2) and Southern (Malen’kii) basins of Lake Baikal. Ca is the predominant cation, which substitutes Fe in the crystalline lattice of siderite. The enrichment of the carbonates in the ¹³C isotope (from +3.3 to +6.8‰ for the Malen’kii volcano and from +17.7 to +21.9‰ for K-2) results from the crystallization of the carbonates during methane generation via the bacterial destruction of organic matter (acetate). The overall depletion of the carbonates in ¹⁸O is mainly inherited from the isotopic composition of Baikal water.  相似文献   

Coastal Upwelling Activity on the Pacific Shelf of the Baja California Peninsula     

Oleg Zaytsev  Rafael Cervantes-Duarte  Orzo Montante  Artemio Gallegos-Garcia 《Journal of Oceanography》2003,59(4):489-502

High primary productivity on the Pacific coast of the Baja California Peninsula is usually related to coastal upwelling activity that injects nutrients into the euphotic zone in response to prevailing longshore winds (from the northwest to north). The upwelling process has maximum intensity from April to June, with the coastal upwelling index varying from 50 to 300 m³/s per 100 m of coastline. Along the entire coast of the peninsula, the upwelling intensity changes in accordance with local wind conditions and bottom topography. Spatial variability can also be modulated by the influence of mesoscale meanders of the California Current. We have identified the seasonal and synoptic variability of upwelling signatures on the Baja California shelf, using averaged monthly and weekly sea surface temperature (SST) distributions obtained from remote sensing imagery from the Advanced Very High Resolution Radiometer in the period from 1996 to 2001. Analysis of SST distribution and direct experimental data on temperature and nutrient concentration shows that the areas with the coldest SST anomalies were closely related to the bottom slope, shelf width, and coastline orientation relating to wind direction. We also assume that the nutrient transport into the coastal lagoons may be forced by the coupling of coastal upwelling and tidal pumping of surface waters into the lagoon system. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Seismic evidence of small-scale lacustrine drifts in Lake Baikal (Russia)     

Ceramicola  S.  Rebesco  M.  De Batist  M.  Khlystov  O. 《Marine Geophysical Researches》2001,22(5-6):445-464

High resolution, single-channel seismic sparker profiles across the Akademichesky Ridge, an intra-basin structural high in Lake Baikal (Russia), reveal the presence of small sediment mounds and intervening moats in the upper part of the sedimentary cover. Such features interrupt the generally uniform and even acoustic facies and are not consistent with the hemipelagic sedimentation, which is expected on such an isolated high and which would produce a uniform sediment drape over bottom irregularities. The influence of turbidity currents is excluded since the ridge is an isolated high elevated more than 600-1000 m above adjacent basins. The mounded seismic facies, including migrating sediment waves and non-depositional/erosional incisions, strongly suggest that sediment accumulation was controlled by bottom-current activity. We interpret the mounds as small-scale (< few tens of km² in area) lacustrine drifts. Four basic types of geometry are identified: 1) slope-plastered patch sheets; 2) patch drifts; 3) confined drifts; 4) fault-controlled drifts. The general asymmetry in the sedimentary cover of the ridge, showing thicker deposits on the NW flank, and the common location of patch drifts on the northeast side of small basement knolls indicate that deposition took preferentially place at the lee sides of obstacles in a current flowing northward or sub-parallel to the main contours. Deep-water circulation in the ridge area is not known in detail, but there are indications that relatively cold saline water masses are presently flowing out of the Central Basin and plunging into the deep parts of the North Basin across the ridge, a process that appears to be driven mainly by small differences in salinity. We infer that the process responsible for the observed bottom-current-controlled sedimentary features has to be sought in these large-scale water-mass movements and their past equivalents. The age of the onset of the bottom-current-controlled sedimentation, based on an average sedimentation rate of 4.0 cm/ky, is roughly estimated to be as least as old as 3.5 Ma, which is generally regarded as the age of the onset of the last major tectonic pulse of rift basin development in the Baikal region.  相似文献   

Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada   总被引：1，自引：0，他引：1  

Tassos A. Grammatikopoulos  Oleg Valeyev  Tina Roth 《Chemie der Erde / Geochemistry》2006,66(4):307-314

The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn_0.89–0.98Hg_0.01–0.09.Fe_0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.

The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing.  相似文献   

The ICP-MS determination of rare earths and other metals in Baikal crude oil: Comparison with crude oils in Siberia and the Russian Far East     

T. A. Yasnygina  Yu. M. Malykh  S. V. Rasskazov  S. P. Primina  T. I. Zemskaya  O. M. Khlystov 《Doklady Earth Sciences》2006,411(8):1237-1240

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An X-ray absorption fine structure and nuclear magnetic resonance spectroscopy study of gallium-silica complexes in aqueous solution     

Gleb S Pokrovski  Jacques SchottJean-Louis Hazemann  François Farges  Oleg S Pokrovsky 《Geochimica et cosmochimica acta》2002,66(24):4203-4222

The influence of aqueous silica on gallium(III) hydrolysis in dilute (2 × 10⁻⁴ ≤ m_Ga ≤ 5 × 10⁻³) and moderately concentrated (0.02 ≤ m_Ga ≤ 0.3) aqueous solutions was studied at ambient temperature, using high resolution X-ray absorption fine structure (XAFS) and nuclear magnetic resonance (NMR) spectroscopies, respectively. Results show that, in Si-free acidic solutions (pH < 3), Ga is hexa-coordinated with oxygens of H₂O molecules and/or OH groups in the first coordination sphere of the metal. With increasing pH, these hydroxyl groups are progressively replaced by bridging oxygens (-O-), and polymerized Ga-hydroxide complexes form via Ga-O-Ga chemical bonds. In the 2.5-3.5 pH range, both XAFS and NMR spectra are consistent with the dominant presence of the Ga₁₃ Keggin polycation, which has the same local structure as A1₁₃. Under basic pH (pH > 8), Ga exhibits a tetrahedral coordination, corresponding to Ga(OH)₄⁻ species, in agreement with previous NMR and potentiometric studies. Major changes in Ga hydrolysis have been detected in the presence of aqueous silica. Ga is tetra-coordinated, both in basic and acid (i.e., at pH > 2.7) Si-bearing solutions (0.01 ≤ m_Si ≤ 0.2), and forms stable gallium-silicate complexes. In these species, Ga binds via bridging oxygen to 2 ± 1 silicons, with an average Ga-Si distance of 3.16 ± 0.05 Å, and to 2 ± 1 silicons, with an average Ga-Si distance of 3.39 ± 0.03 Å. These two sets of Ga-Si distances imply the formation of two types of Ga-silicate aqueous complex, cyclic Ga-Si_2-3 species (formed by the substitution of Si in its tri-, tetra- or hexa-cyclic polymers by Ga atoms), and chainlike GaSi_2-4 species (similar to those found for A1), respectively. The increase in the number of Si neighbors (a measure of the complex concentration and stability), in alkaline media, with increasing SiO₂(aq) content and decreasing pH is similar to that for A1-Si complexes found in neutral to basic solutions. At very acid pH and moderate silica concentrations, the presence of another type of Ga-Si complex, in which Ga remains hexa-coordinated and binds to the silicon tetrahedra via the GaO₆ octahedron corners, has also been detected. These species are similar to those found for Al³⁺ in acid solutions. Thus, as for aluminum, silicic acid greatly hampers Ga hydrolysis and enhances Ga mobility in natural waters via the formation of gallium-silicate complexes.  相似文献   

Siberian river run-off and Late Quaternary glaciation in the southern Kara Sea, Arctic Ocean: preliminary results   总被引：3，自引：0，他引：3  

Ruediger Stein  Frank Niessen  Klaus Dittmers  Michael Levitan  Frank Schoster  Johannes Simstich  Tatjana Steinke  Oleg V. Stepanets 《Polar research》2002,21(2):315-322

The extent of the Barents-Kara Ice Sheet during the eastern Last Glacial Maximum (LGM) is not yet fully known. A detailed echo-sounding survey performed during the Boris Petrov Expedition 2001 permitted the detailed mapping of part of it. Based on the profiling results, a southern connection between the LGM Barents-Kara Ice Sheet and a local ice sheet on Taymyr Peninsula appears to be unlikely. Based on sediment core data and profiling results, most of the terrigenous river-derived material accumulated in the estuaries during late Holocene times, whereas during early Holocene times of lowered sea level major amounts were transported further offshore and accumulated on the shelf. During the post-glacial sea level rise, the main depocentre migrated southward, reaching its present position no earlier than about 6 cal. Ky BP (or 5.2 Kya). Future studies of accelerator mass spectrometry (AMS) ¹⁴C-dated sediment cores will allow a detailed reconstruction of the variability of fluvial sediment discharge and the history of glaciation in the Kara Sea during late Quaternary times.  相似文献   

Time-domain electromagnetic migration in the solution of inverse problems   总被引：5，自引：0，他引：5  

Michael S. Zhdanov  Oleg Portniaguine 《Geophysical Journal International》1997,131(2):293-309

Time-domain electromagnetic (TDEM) migration is based on downward extrapolation of the observed field in reverse time. In fact, the migrated EM field is the solution of the boundary-value problem for the adjoint Maxwell's equations. The important question is how this imaging technique can be related to the solution of the geoelectrical inverse problem. In this paper we introduce a new formulation of the inverse problem, based on the minimization of the residual-field energy flow through the surface or profile of observations. We demonstrate that TDEM migration can be interpreted as the first step in the solution of this specially formulated TDEM inverse problem. However, in many practical situations this first step produces a very efficient approximation to the geoelectrical model, which makes electromagnetic migration so attractive for practical applications. We demonstrate the effectiveness of this approach in inverting synthetic and practical TDEM data.  相似文献   

The evolution of slump-induced destruction of Kukuy Griva slope (Lake Baikal) revealed on the base of the data of seismic and acoustic surveys     

M. A. Solovyeva  A. V. Starovoytov  G. G. Akhmanov  O. M. Khlystov  A. V. Khabuev  M. Yu. Tokarev  D. A. Chensky 《Moscow University Geology Bulletin》2016,71(6):416-428

As a result of careful interpretation of the data of recent seismo-acoustic surveys, two major seismic complexes were identified in the structure of the upper sedimentary section of the north-western slope of Kukuy Griva (ridge). They are composed of several inner seismo-facies, which are very characteristic and separated with well-expressed regional reflector. Seismic and acoustic data revealed evidences of numerous landslide processes which were different in age and peculiarities of manifestation. For the first time, detailed schemes of seismo-facies distribution are compiled for major seismic complexes at the area. The boundary between seismic complexes is dated as 150 thousands years. It is shown that sliding was more intensive during Late Pleistocene and Holocene, reflecting activation of tectonic movements in this part of Baikal rift system.  相似文献   

Authigenic rhodochrosite from a gas hydrate-bearing structure in Lake Baikal     

Krylov  Alexey A.  Hachikubo  Akihiro  Minami  Hirotsugu  Pogodaeva  Tatyana V.  Zemskaya  Tamara I.  Krzhizhanovskaya  Mariya G.  Poort  Jeffrey  Khlystov  Oleg M. 《International Journal of Earth Sciences》2018,107(6):2011-2022

International Journal of Earth Sciences - Early diagenetic carbonates are rare in Lake Baikal. Siderite (Fe carbonate) concretions in the sediments were discovered only recently. Here, we discuss...  相似文献