Long-term effects of tributyltin compounds on the baltic amphipod, Gammarus oceanicus     

Roy Laughlin  Karin Nordlund  Olof Lindn 《Marine environmental research》1984,12(4):243-271

Amphipod larvae, Gammarus oceanicus, were exposed for 8 weeks to bis(tributyltin) oxide (TBTO) or tributyltin fluoride (TBTF), or for 5 weeks to leachates from tributyltin-containing antibiofouling paints. No larvae survived 8 weeks' exposure to 3 μg/litre TBTO or TBTF. Differential larval survival occurred during exposure to 0·3 gmg/litre of these same compounds. Paint leachates were shown to cause similar toxicity responses at comparable aqueous tributyltin concentrations. An examination of sublethal responses showed slight decreases in growth for larvae exposed to TBTO and to paint leachates, although responses at tributyltin levels below 1 μg/litre were not marked. Whole-animal oxygen consumption rates were not affected by low tributyltin exposure levels. While these studies demonstrate low level toxicity of tributyltins, effects on oxygen consumption and growth do not indicate a mode of action for these compounds.  相似文献   

Lidar observations of turbulent vortex shedding by an isolated topographic feature     

William P. Hooper  Jeffrey E. James  Richard J. Lind 《Boundary-Layer Meteorology》1996,80(1-2):95-108

Scanning measurements by a single wavelength lidar (1.06 m) were made downwind of the Pt. Sur rock, an isolated hill (height 110 m) along the California coast. Turbulent eddies (approximate diameter 50 m) were observed detaching from a stationary aerosol feature above the rock and moving downwind. Under conditions with a high Froude number [1.8], the Strouhal number [0.22] of vortex shedding was close to that observed in tank experiments with a Reynolds number of 200.  相似文献   

Ludlow (Silurian) stromatoporoid biostromes from Gotland, Sweden: facies, depositional models and modern analogues   总被引：1，自引：0，他引：1  

Olof Sandström  Steve Kershaw† 《Sedimentology》2002,49(3):379-395

Stacked stromatoporoid‐dominated biostromes of the Ludlow‐age Hemse Group (Silurian) in eastern Gotland, Sweden, are 0·5–5 m thick and a few tens of metres to >1 km in lateral extent. They form one of the world's richest Palaeozoic stromatoporoid deposits. This study compiles published and new data to provide an overall facies model for these biostromes, which is assessed in relation to possible modern analogues. Some biostromes have predominantly in‐place fossils and are regarded as reefs, but lack rigid frameworks because of abundant low‐profile non‐framebuilding stromatoporoids; other biostromes consist of stromatoporoid‐rich rudstones interpreted here as storm deposits. Variation between these two `end‐members' occurs both between interlayered biostromes and also vertically and laterally within individual biostromes. Such variation produces problems of applying established reef classification terms and demonstrates the need for the development of terminology that recognizes taphonomic destruction of reef fabrics. An approach to such terminology is found in all four categories of a recent biostrome classification scheme that are easily recognized in the Hemse biostrome facies: autobiostromes (>60% in place); autoparabiostromes (a mixture of in‐place and overturned reef‐building organisms, 20–60% in place); parabiostromes (builders are overturned and damaged, <20% in place); and allobiostromes (transported and detrital reef material, nothing in place). These categories provide a broad taphofacies scheme for the Hemse biostromes, which are mostly autoparabiostrome to allobiostrome. The biostromes developed on crinoidal grainstone sheets and expanded laterally across relatively flat substrates in a marine setting of low siliciclastic input. Planar erosion surfaces commonly terminate biostrome tops. Three broadly similar modern analogues are identified, each of which has elements in common with the Hemse biostromes, but none of which is an exact equivalent: (a) laterally expanded and coalesced back‐barrier patch reefs behind the Belize barrier, an area influenced by limited accommodation space; (b) a hurricane‐influenced shelf, interpreted for Grand Cayman, where reef cores consist of rubble and lack substantial framework; the wide distribution of rounded pebbles and cobbles of stromatoporoids in the Hemse biostromes most probably resulted from hurricanes; (c) coral carpets in 5–15 m water depth of the northern Red Sea, where lateral expansion of low‐diversity frames dominated by Porites coral has produced low‐profile biostromes up to 8 m thick and several km long. Such carpets accumulated large amounts of carbonate, with little export, as in the Hemse biostromes, although the latter did not build frameworks because of the nature of growth of the stromatoporoids. The notable lack of algae in the Hemse biostrome facies is also a feature of Red Sea coral carpets; nevertheless, coral carpets are ecologically different. Hemse biostromes lack evidence of a barrier reef system, although this may not be exposed; the facies assemblage is consistent with either a storm/hurricane‐influenced mid‐ to upper ramp or back‐barrier system.  相似文献   

Entropy estimation of hydrological extremes     

N. C. Lind  H. P. Hong 《Stochastic Environmental Research and Risk Assessment (SERRA)》1991,5(1):77-87

The method of Relative Entropy with Fractile constraints (REF method) is explained and applied to model extreme compound hydrological phenomena, such as extreme sea levels under storm conditions. Also presented is a simple method of Tail Entropy Approximation (TEA), which amounts to a correction of traditional statistical estimates for extreme observations.Distribution assumptions are necessary but downplayed in the REF method, relegating the prior distribution to the role of an extrapolation function. The estimates are objective in an information-theoretical sense. They also satisfy a strict requirement of self-consistency that is generally not satisfied by standard statistical methods: invariance under monotonic transformations of the random variable.Historical records of storm surge levels in the Netherlands and annual maximum tidal heights for Sheerness, UK, are used as examples. Comparison is made with distributions obtained using other methods.It is concluded that the tail entropy approximation provides simple, objective estimates of extremes in the tail beyond the range of observations.  相似文献   

Thermodynamic stability of CoOOH and its coprecipitation with manganese     

John D. Hem  Charles E. Roberson  Carol J. Lind 《Geochimica et cosmochimica acta》1985,49(3):801-810

A precipitate of cobalt oxyhydroxides formed by bubbling oxygen through a dilute solution of Co(NO₃)₂ held at pH 9.0 and 25°C was aged for 23 months in contact with the original solution, with access to atmospheric oxygen. Co₃O₄ and CoOOH were identified in the precipitate by X-ray diffraction. Chemical equilibria involving these solids were evaluated by measurements of solution pH and Co²⁺ activities and by redox potential measurements and gave a $\text{ΔG}{}_{\mathrm{coOOH}}{}^0$ of $\text{?92.3 ± 0.5 kcal/mole}$. This value and other thermodynamic data show relative feasibility of hypothetical reaction steps and changes in reaction paths during automated coprecipitation titrations and subsequent aging of a precipitate that finally contained βMnOOH, MnO₂ (birnessite) and CoOOH.  相似文献   

Nonequilibrium models for predicting forms of precipitated manganese oxides     

John D. Hem  Carol J. Lind 《Geochimica et cosmochimica acta》1983,47(11):2037-2046

Manganese oxides precipitated by bubbling air through 0.01 molar solutions of MnCl₂, Mn(NO₃)₂, MnSO₄, or Mn(ClO₄)₂ at a constantly maintained pH of 8.5 to 9.5 at temperatures of 25°C or higher consisted mainly of hausmannite, Mn₃O₄. At temperatures near 0°C, but with other conditions the same, the product is feitknechtite, βMnOOH, except that if the initial solution is MnSO₄ and the temperature is near 0°C the product is a mixture of manganite, γMnOOH and groutite, αMnOOH.All these oxides are metastable in aerated solution and alter by irreversible processes to more highly oxidized species during aging. A two-step nonequilibrium thermodynamic model predicts that the least stable species, βMnOOH, should be most readily converted to MnO₂. Some preparations of βMnOOH aged in their native solution at 5°C attained a manganese oxidation state of +3.3 or more after 7 months. Hausmannite aged at 25°C altered to γMnOOH. The latter is more stable than a or βMnOOH, and manganese oxidation states above 3.0 were not reached in hausmannite precipitates during 4 months of aging. Initial precipitation of MnCO₃ rather than a form of oxide is likely only where oxygen availability is very low.Composition of solutions and oxidation state and morphology of solids were determined during the aging process by chemical analyses, X-ray and electron diffraction and transmission electron micrographs.  相似文献   

Book reviews     

A. M. O'Connor  Fouad Ibrahim  W. F. Schmidt-Eisenlohr  Olof Nordström  Gunnar Alexandersson  Lutz Holzner  L. A. Kosiński 《GeoJournal》1978,2(5):492-494

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A study of apparently nearby stars with coinciding spectral type and apparent magnitude     

Lars Olof Lodén 《Astrophysics and Space Science》1973,24(2):511-529

At visual inspection of objective-prism plates one frequently detects a pair or higher multiple of apparently identical stellar spectra so close together that they form a conspicuous configuration for the eye. An attempt to analyse this type of objects has given no positive indication that it should be identified with any unique physical phenomenon. A series of explanations is presented. A minor fraction of the objects may constitute widely separated binary components, the identity of which is physically conditioned by the process of formation. For the majority, however, it seems more probable that they form parts of cluster remnants or very small clusters, and that the coincidence of the spectral types is in the first instance to consider as a fortunate random effect that facilitates the detection of the hidden cluster. Although there are several interpretations of the appearance of such ‘miniclusters’, I find it particularly important to take the possibility into consideration that the number of open clusters (and associations) may be considerably greater than one has hitherto assumed—from observational as well as from theoretical point of view.  相似文献   

Stability constants of phosphoric acid in seawater of 5–40‰ salinity and temperatures of 5–25°C     

Olof Johansson  Margareta Wedborg 《Marine Chemistry》1979,8(1):57-69

The stability constants K₁ and K₁₂ of phosphoric acid were determined for artificial seawater of six different salinities (5, 10, 20, 30, 35, 40‰) and in 0.2, 0.4 and 0.7 M NaCl at three temperatures (5, 15, 25°C). The results are compared with those of Kester and Pytkowicz (1967), Atlas et al. (1976) and Dickson and Riley (1979). The ionic product of water, K_w, was determined in sodium chloride media at 5, 15 and 25°C. Complex formation among Ca²⁺, Mg²⁺, HPO₄^2? and PO₄^3? is discussed.  相似文献   

Geothermal investigations in the Bohus granite area in southwestern Sweden     

Ove Landstrm  Sven ke Larson  Gustaf Lind  David Malmqvist 《Tectonophysics》1980,64(1-2)

Heat generation and heat flow were determined for the Bohus granite massif in western Sweden. This is the start of a major program concerning geothermal energy in Sweden. Neutron activation analyses, temperature measurements, thermal conductivity measurements have been carried out. As was expected the result, 76 mW m⁻², shows that even old Precambrian shields locally exhibit much higher values than normal.  相似文献