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1.
Tourmalinite and tourmaline-rich rocks associated with Fe-carbonate–graphite phyllite, strata-bound polymetallic sulphide deposits, metabasite and marble were studied, for information on the mechanism of tourmaline formation in the pre-Hercynian low-grade metamorphic sequence of the Mandanici Unit in the Peloritani Mountains of Sicily, southern Italy. The major and trace element compositions of the tourmaline rocks suggest the existence of a sedimentary protolith with pre-metamorphic black shale and bedded chert. Boron was interpreted to be accumulated in a restricted sedimentary basin, between platform carbonate formations, with abundant organic matter and Fe–Al–Ti-rich laterite–bauxite soil-derived clastic supply, under a continental volcano-tectonic extensional regime accompanied by a local convective hydrothermal system along faults. Petrographic, crystal–chemical and δ11B isotopic data are compatible with a model of marine sediment dewatering at temperatures below 200 °C, which caused the removal of boron from clay. Metamorphism led to the development of tourmaline in an Al–Ti-rich environment, in equilibrium with other minerals such as ilmenite, albite and muscovite. The upper temperature of metamorphism (almost 375 °C), estimated on the basis of δ11B, fits geothermometric results from Δ13Ccarbonate–graphite on associated rocks. The estimated value of δ11B in the tourmalinite protolith, − 7.5‰ , is also compatible with continental-derived Al-rich sediments. 相似文献
2.
Gladys V. Melián Inés Galindo Nemesio M. Pérez Pedro A. Hernández Mario Fernández Carlos Ramírez Raúl Mora Guillermo E. Alvarado 《Pure and Applied Geophysics》2007,164(12):2465-2487
We report the results of four soil H2 surveys carried out in 2000–2003 at Poás volcano, Costa Rica, to investigate the soil H2 distribution and evaluate the diffuse H2 emission as a potential surveillance tool for Poás volcano. Soil gas H2 contents showed a wide range of concentration from 0.2 to 7,059 ppmV during the four surveys. Maps of soil gas H2 based on Sequential Gaussian Simulation showed low H2 concentration values in the soil atmosphere (<0.7 ppmV) for most of the study area, whereas high soil gas H2 values were observed inside the active crater of Poás. A significant increase in soil gas H2 concentration was observed inside the active crater during 2001 and 2002 with respect to year 2000, followed by a decrease
in 2003. The observed spatial and temporal variations of soil H2 concentration have been well correlated with seismicity, microgravimetry and fumarolic chemistry changes which occurred during
this study. These observations evidence changes in the shallow magmatic-hydrothermal system of Poás, and it might be related
to a potential magmatic intrusion during the period 1998–2004. Therefore, monitoring diffuse H2 emission of Poás has become an important geochemical tool for the monitoring of its volcanic activity. 相似文献
3.
A shaking table testing program was undertaken with the main objective of providing basic information for the calibration of analytical models, and procedures for determining seismic response of typical stone masonry temples of the 16–18th centuries stone masonry construction in Mexico. A typical colonial temple was chosen as a prototype. A model at a 1:8 geometric scale was built with the same materials and techniques as the prototype, and was subjected to horizontal and vertical motions of increasing intensities. The maximum applied intensity corresponded to a base shear force of about 58 of the total building weight. Vertical component of the base motion significantly affected the response and increased the damage of the model. Damage patterns were similar to those observed in actual temples. Damping coefficients of the response ranged from 7 for undamaged state, reached about 14 for severe damage. The main features of the measured response were compared with those computed using a nonlinear, finite element model; for the latter, a constitutive law developed for plain concrete was adopted for reproducing cracking and crushing of the irregular stone masonry. Observed damage patterns as well as measured response could be reproduced with reasonable accuracy by the analytical simulation, except for some local vibrations, as those at the top of the bell towers. It can be concluded that the simple constitutive law adopted for the simulation was able to reproduce the experimental response with reasonable level of accuracy. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
4.
Eleazar Padrón Gladys Melián Rayco Marrero Dácil Nolasco José Barrancos Germán Padilla Pedro A. Hernández Nemesio M. Pérez 《Pure and Applied Geophysics》2008,165(1):95-114
Significant changes in the diffuse emission of carbon dioxide were recorded in a geochemical station located at El Hierro,
Canary Islands, before the occurrence of several seismic events during 2004. Two precursory CO2 efflux increases started thirteen and nine days before two seismic events of magnitude 2.3 and 1.7, which took place near
El Hierro Island, Canary Islands, on March 23 and April 15, reaching a maximun value of 51.1 and 46.2 g m−2 d−1, respectively, five and eight days before the two seismic events. Other similar increases started thirteen and five days
before the occurrence of two seismic events of magnitude 1.3 and 1.5 which took place on October 15 and 21 respectively, reaching
the maximum values four and one day before the earthquakes. These changes were not related to variations in atmospheric or
soil parameters. The Material Failure Forecast Method (FFM), which analyzes the rate of precursory phenomena, was successfully
applied to forecast the first seismic event that took place in El Hierro Island in 2004. 相似文献
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Previous field and laboratory studies have identified the alga Lobophora variegata as a good candidate for biomonitoring metal contamination in the New Caledonia lagoon which is subjected to intensive and extensive metal inputs from land-based mining activities. The aim of this work was to further assess the bioindicative potential of this species by investigating, in the field, its bioaccumulation capacity for local key contaminants, i.e. Ag, As, Cd, Co, Cr, Cu, Mn, Ni and Zn. Algae from clean and contaminated sites were cross-transplanted for a period of three months in order to determine the in situ uptake and depuration kinetics of the nine elements. Results indicate that algae transplanted to the contaminated site displayed a significant linear increase in concentration with time for Ag, As, Cd, Co, Cr, Cu, Mn and Ni. In contrast, algae transplanted to the clean site did not show major depuration of these elements, except for Co. Overall, L. variegata showed a rapid temporal response in metal uptake, especially for the elements intensively released into the coastal environment of New Caledonia (viz., Co, Cr, Mn and Ni). This species appears therefore as an excellent bioindicator species of metal contamination in this area. Our results also provide background information necessary for using L. variegata under in situ experimental conditions so as to provide better quantitative information on ambient metal contamination levels. The wide distribution of L. variegata in tropical areas further enhances its potential as a bioindicator species of metal contamination in other tropical coastal environments. 相似文献
7.
G. Melián F. Tassi N. Pérez P. Hernández F. Sortino O. Vaselli E. Padrón D. Nolasco J. Barrancos G. Padilla F. Rodríguez S. Dionis D. Calvo K. Notsu H. Sumino 《Bulletin of Volcanology》2012,74(6):1465-1483
The present work reports the results of 15 studies of diffuse CO2 degassing performed at Teide Volcano crater (Canary Island, Spain) and the chemical and isotopic compositions of fluids discharged from a fumarolic field located at the top of the volcano as measured between 1991 and 2010. A higher contribution of magmatic gases accompanied by enhanced total diffuse CO2 emissions were observed in relation with a seismic crisis that occurred in Tenerife Island between 2001 and 2005, with the main peak of seismic activity between April and June 2004. A significant pulse in total diffuse CO2 emission was observed at the crater of Teide (up to 26.3?t day?1) in 2001. In December 2003, the chemical composition of the Teide fumarole changed significantly, including the appearance of SO2, an increase in the HCl and CO concentrations and in the C2H6/C2H4 and C3H8/C3H6 ratios, and a decrease in the H2S, CH4, and C6H6 concentrations and in the gas/steam ratio. A few months after a drastic decrease in seismic activity, the SO2, HCl, and CO concentrations and the C2H6/C2H4 and C3H8/C3H6 ratios strongly decreased, whereas the CH4 and C6H6 concentrations and the gas/steam ratios increased. According to the trends shown by both the geochemical parameters and the seismic signals late in the observation period, the risk of a rejuvenation of volcanic activity at Teide is considered to be low. The associated temporal changes in seismic activity and magmatic degassing indicate that geophysical and fluid geochemistry signals in this system are related. Future monitoring programs aimed at mitigating volcanic hazard on Tenerife Island should involve coupled geophysical and geochemical studies. 相似文献
8.
Anomalous Diffuse CO2 Emissions at the Masaya Volcano (Nicaragua) Related to Seismic-Volcanic Unrest
Germán D. Padilla Pedro A. Hernández Nemesio M. Pérez Ernesto Pereda Eleazar Padrón Gladys Melián José Barrancos Fátima Rodríguez Samara Dionis David Calvo Martha Herrera Wilfried Strauch Angélica Muñoz 《Pure and Applied Geophysics》2014,171(8):1791-1804
Anomalous changes in the diffuse emission of carbon dioxide within the Masaya caldera have been observed before two seismic events that occurred at 10 and 30 km from the observation site. Their epicenters are located, respectively, south of Managua in Las Colinas (4.3 magnitude) and the Xiloa caldera (3.6 magnitude), in 2002 and 2003, recorded by the geochemical station located at El Comalito, Masaya volcano (Nicaragua). Anomalous increases were observed, which occurred around 50 and 8 days before the main seismic event that took place in Las Colinas, and 4 days before the seismic swarm at the Xiloa caldera, with a maximum CO2 efflux of 9.3 and 10.7 kg m?2 day?1, respectively. The anomalous CO2 efflux increases remained after filtering with multiple regression analysis was applied to the CO2 efflux time series, which indicated that atmospheric variables, during the first 4 months, explained 23 % CO2 variability, whereas, during the rest of the time series, CO2 efflux values are poorly controlled with only 6 %. The observed anomalies of the diffuse CO2 emission rate might be related to pressure changes within the volcanic–hydrothermal system and/or to geostructural changes in the crust due to stress/strain changes caused before and during the earthquakes’ formation, and seem not to be related to the activity of the main crater of Masaya volcano. 相似文献
9.
P. A. Hernández N. M. Pérez J. C. Varekamp B. Henriquez A. Hernández J. Barrancos E. Padrón D. Calvo G. Melián 《Pure and Applied Geophysics》2007,164(12):2507-2522
A sudden eruption at Santa Ana occurred on 1 October 2005, producing an ash-and-gas plume to a height in excess of 10 km above
the volcano. Several days before, thermal infrared images of the crater provided precursory signals of the eruption. A significant
increase in the extent and intensity of the fumarolic field inside the crater rim and of the surface temperature of the crater’s
lake was observed. Changes in energy input was also estimated to explain the increase in lake temperature based on energy/mass
balance calculations. 相似文献
10.
Nemesio M. Pérez Pedro A. Hernández Eleazar Padrón Gladys Melián Rayco Marrero Germán Padilla José Barrancos Dácil Nolasco 《Pure and Applied Geophysics》2007,164(12):2431-2448
Precursory geochemical signatures of radon degassing in the subsurface of the Tenerife Island were observed several months
prior to the recent 2004 seismic-volcanic crisis. These premonitory signatures were detected by means of a continuous monitoring
of 222Rn and 220Rn activity from a bubbling CO2-rich gas spot located at 2.850 m depth inside a horizontal gallery for groundwater exploitation at Tenerife. Multivariate
Regression Analysis (MRA) on time series of the radon activity was applied to eliminate the radon activity fluctuation due
to external variables such as barometric pressure, temperature and relative humidity as well as power supply. Material Failure
Forecast Method (FFM) was successfully applied to forecast the anomalous seismicity registered in Tenerife Island in 2004.
The changes in the 222Rn/220Rn ratio observed after the period of anomalous seismicity might suggest a higher gas flow rate and/or changes in the vertical
permeability induced by seismic activity. 相似文献