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The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.  相似文献   
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High resolution environmental records with a refined chronology are essential to understand, reconstruct and model the climate dynamics of the last glacial-interglacial transition. Sediments from Lake Torfadalsvatn in northern Iceland contain at least four primary volcanic tephras that belong to ash zone I in the North Atlantic deep-sea cores. We chemically define these basaltic/rhyolitic tephras and the high resolution allows us to date them to about 10,800, 10,600, 9300 and 8900 BP. This detailed tephrostratigraphy will act as a refined dating and correlation tool in the North Atlantic region and enable calibration between different absolute chronologies. The pollen stratigraphy of the sediments suggests that by 10,400 14C years BP plant colonization of coastal north Iceland had begun. The pollen stratigraphy shows a succession of pioneer plants, from open tundra vegetation towards birch-juniper woodland, which probably also reflects a transition from a cool climate at 10,400 BP to conditions similar to today's sub-polar oceanic climate around 9200 BP. Diatom data largely concur with the climatic information from pollen, indicating gradually increasing productivity in the lake.  相似文献   
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We report measurements of dissolved iron (dFe, <0.4 μm) in seawater collected from the upper 300 m of the water column along the CLIVAR SR3 section south of Tasmania in March 1998 (between 42°S and 54°S) and November–December 2001 (between 47°S and 66°S). Results from both cruises indicate a general north-to-south decrease in mixed-layer dFe concentrations, from values as high as 0.76 nM in the Subtropical Front to uniformly low concentrations (<0.1 nM) between the Polar Front and the Antarctic continental shelf. Samples collected from the seasonal sea-ice zone in November–December 2001 provide no evidence of significant dFe inputs from the melting pack ice, which may explain the absence of pronounced ice-edge algal blooms in this sector of the Southern Ocean, as implied by satellite ocean-color images. Our data also allow us to infer changes in the dFe concentration of surface waters during the growing season. South of the Polar Front, a comparison of near-surface with subsurface (150 m depth) dFe concentrations in November–December 2001 suggests a net seasonal biological uptake of at least 0.14–0.18 nM dFe, of which 0.05–0.12 nM is depleted early in the growing season (before mid December). A comparison of our spring 2001 and fall 1998 data indicates a barely discernible seasonal depletion of dFe (0.03 nM) within the Polar Frontal Zone. Further north, most of our iron profiles do not exhibit near-surface depletions, and mixed-layer dFe concentrations are sometimes higher in samples from fall 1998 compared to spring 2001; here, the near-surface dFe distributions appear to be dominated by time-varying inputs of aerosol iron or advection of iron-rich subtropical waters from the north.  相似文献   
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Lake Boksehandsken, the largest lake on Jameson Land, central East Greenland, is situated 54 m a.s.l. and holds a long (6.3 m) and complex stratigraphy. It was analysed with respect to lithology, carbon content, 14C, micro- and macrofossils. The diamict material in the bottom is overlain by a fining-upwards sequence, possibly deposited close to a receding ice margin in a glaciomarine environment. These deposits are interpreted to have been formed at the time of the marine limit ( c . 70 m) in the area. In spite of a large series of 14C datings, very few of the obtained dates were considered reliable. This is because the sediments contain coal fragments and old redeposited plant remains. Based on a set of arguments and correlations to the surrounding glacial stratigraphy it is implied that the marine limit and deglaciation cannot be much older than 10,000 BP. The lithology of the lake sediments, in combination with occurrence of marine macrofossils. shows that deglaciation was succeeded by a (glacio)marine depositional environment. The lake was isolated from the sea at c . 9000 BP. followed by a short transgression and a final isolation at c . 8400 BP. This sequence of events is demonstrated by both litho-and biostratigraphy and possible causes are discussed. A later oscillation some time between 8000 and 7500 BP. evidenced by litho-, carbon-, pollen- and Pecliastrum stratigraphy, is interpreted as a regional climatic cooling possibly correlatable to a distinct δ18O minima in the Greenland ice cores.  相似文献   
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Book reviewed in this article:
Bradley, R. S. (ed.) 1991: Global Changes of the Past. 514 pp. Office for Interdisciplinary Earth Studies, Boulder, Colorado  相似文献   
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Rundgren, M., Ingólfsson, Ó., Björck, S., Jiang, H. & Haflioason, H. 1997 (September): Dynamic sea-level change during the last deglaciation of northern Iceland. Boreas , Vol. 26, pp. 201–215. Oslo. ISSN 0300–9483.
A detailed reconstruction of deglacial relative sea-level changes at the northern coast of Iceland, based on the litho- and biostratigraphy of lake basins, indicates an overall fall in relative sea level of about 45 m between 11300 and 9100 BP, corresponding to an isostatic rebound of 77 m. The overall regression was interrupted by two minor transgressions during the late Younger Dryas and in early Preboreal, and these were probably caused by a combination of expansions of local ice caps and readvances of the Icelandic inland ice-sheet margin. Maximum absolute uplift rates are recorded during the regressional phase between the two transgressions (10000–9850 BP), with a mean value of c . 15 cm 14C yr-1 or 11–12 cm cal. yr-1. Mean absolute uplift during the regressional phase following the second transgression (9700–9100 BP) was around 6 cm 14C yr-1, corresponding to c . 3 cm cal. yr-1, and relative sea level dropped below present-day sea level at 9000 BP.  相似文献   
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The previously established and often debated lake sediment based chronology and event stratigraphy from Hochstetter Forland, NE Greenland, has been re-examined. These new studies show that the last deglaciation of the coastal area is several thousand years younger than previously described. The main reason behind the difference is the fact that the older chronology was based on 14C datings of bulk sediment samples, which are now shown to contain enough coal fragments to produce erroneous ages. The re-examination was performed on sediments from two lakes located within the Nanok moraine system: one is situated at or slightly above the marine limit around 65 m. the other at 21–22 m a.s.l. The combined stratigraphy from the two lakes shows that the area was deglaciated before 9000 BP, after which followed deposition of glaciomarine sediments, fining upwards. The first vegetation seems to have been dominated by grasses, Lycopodium and Polypodiaceae. At c . 8000 BP the limnic production increased significantly and a pioneer vegetation characterized the area. At this time the 'Artemisia' grains appear. A short but distinct climatic cooling occurs at c . 7500 BP causing a significant drop in lake productivity and possibly also producing coarser sediments in the (glacio)marine environment. About 200 years later the lake productivity again increased, very rapidly, and the marine sediments became finer and more rich in molluscs, as a response to the beginning of the climatic optimum. Because of the time-lag between climate and vegetation response it took another 300 years before Betulci nana immigrated, at the same time as the 'Artemisia' grains disappeared, and another several hundred years before a real dwarf-shrub vegetation developed in these parts of Hochstetter Forland. Before the lower lake was isolated from the sea at c . 6000 BP, coarse wave-washed sediments, followed by a typical isolation sequence, were deposited in it.  相似文献   
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