Post-solidification cooling and the age of Io's lava flows     

Ashley Gerard Davies  Dennis L. Matson  Glenn J. Veeder  Torrence V. Johnson  Diana L. Blaney 《Icarus》2005,176(1):123-137

The modeling of thermal emission from active lava flows must account for the cooling of the lava after solidification. Models of lava cooling applied to data collected by the Galileo spacecraft have, until now, not taken this into consideration. This is a flaw as lava flows on Io are thought to be relatively thin with a range in thickness from ∼1 to 13 m. Once a flow is completely solidified (a rapid process on a geological time scale), the surface cools faster than the surface of a partially molten flow. Cooling via the base of the lava flow is also important and accelerates the solidification of the flow compared to the rate for the ‘semi-infinite’ approximation (which is only valid for very deep lava bodies). We introduce a new model which incorporates the solidification and basal cooling features. This model gives a superior reproduction of the cooling of the 1997 Pillan lava flows on Io observed by the Galileo spacecraft. We also use the new model to determine what observations are necessary to constrain lava emplacement style at Loki Patera. Flows exhibit different cooling profiles from that expected from a lava lake. We model cooling with a finite-element code and make quantitative predictions for the behavior of lava flows and other lava bodies that can be tested against observations both on Io and Earth. For example, a 10-m-thick ultramafic flow, like those emplaced at Pillan Patera in 1997, solidifies in ∼450 days (at which point the surface temperature has cooled to ∼280 K) and takes another 390 days to cool to 249 K. Observations over a sufficient period of time reveal divergent cooling trends for different lava bodies [examples: lava flows and lava lakes have different cooling trends after the flow has solidified (flows cool faster)]. Thin flows solidify and cool faster than flows of greater thickness. The model can therefore be used as a diagnostic tool for constraining possible emplacement mechanisms and compositions of bodies of lava in remote-sensing data.  相似文献   

Anoxic nitrification: Evidence from Humber Estuary sediments (UK)   总被引：3，自引：0，他引：3  

Rebecca Bartlett  Robert J.G. Mortimer  Katherine Morris 《Chemical Geology》2008,250(1-4):29-39

Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment.  相似文献   

Circulation on the north central Chukchi Sea shelf   总被引：8，自引：0，他引：8  

Thomas Weingartner  Knut Aagaard  Rebecca Woodgate  Seth Danielson  Yasunori Sasaki  Donald Cavalieri 《Deep Sea Research Part II: Topical Studies in Oceanography》2005,52(24-26):3150

Mooring and shipboard data collected between 1992 and 1995 delineate the circulation over the north central Chukchi shelf. Previous studies indicated that Pacific waters crossed the Chukchi shelf through Herald Valley (in the west) and Barrow Canyon (in the east). We find a third branch (through the Central Channel) onto the outer shelf. The Central Channel transport varies seasonally in phase with Bering Strait transport, and is 0.2 Sv on average, although some of this might include water entrained from the outflow through Herald Valley. A portion of the Central Channel outflow moves eastward and converges with the Alaskan Coastal Current at the head of Barrow Canyon. The remainder appears to continue northeastward over the central outer shelf toward the shelfbreak, joined by outflow from Herald Valley. The mean flow opposes the prevailing winds and is primarily forced by the sea-level slope between the Pacific and Arctic oceans. Current variations are mainly wind forced, but baroclinic forcing, associated with upstream dense-water formation in coastal polynyas might occasionally be important.Winter water-mass modification depends crucially on the fall and winter winds, which control seasonal ice development. An extensive fall ice cover delays cooling, limits new ice formation, and results in little salinization. In such years, Bering shelf waters cross the Chukchi shelf with little modification. In contrast, extensive open water in fall leads to early and rapid cooling, and if accompanied by vigorous ice production within coastal polynyas, results in the production of high-salinity (>33) shelf waters. Such interannual variability likely affects slope processes and the transport of Pacific waters into the Arctic Ocean interior.  相似文献   

Stress-induced apoptosis in sea urchin embryogenesis     

Vega RL  Epel D 《Marine environmental research》2004,58(2-5):799-802

We find that early sea urchin embryos have the capability to induce programmed cell death, or apoptosis, in response to chemical and physical stress. Strongylocentrotus purpuratus embryos (fertilized, 4 cell, 16 cell, 64 cell, and early blastula) were exposed to known cytotoxins, in order to determine when apoptosis occurs naturally and in response to stress. Using cell permeability as an indicator of early stage apoptosis, caspase activation as a mid-stage indicator, and DNA fragmentation as a late stage indicator, we find that during the cleavage stage of embryogenesis apoptosis is almost completely absent. However, a statistically significant (p<0.001) rise in apoptosis in stressed embryos is evident around 24 h after fertilization, during the early blastula stage and shortly after hatching. Before this stage, exposed embryos show no statistically significant increases in apoptosis in comparison to the controls. This pattern of apoptosis in development is similar to that seen in lower vertebrate models in which stress-induced apoptosis occurs only around the mid-blastula transition. We conclude that apoptosis may be used to rid embryos of aberrant or damaged cells in early development, but this response is stage-dependant. Repair, rather than apoptosis, may be utilized during earlier stages, or alternatively, embryos exposed to such stressors may continue development with damaged cells and perhaps damaged DNA. Our continued studies will focus on these alternative hypotheses.  相似文献   

The Southern Antarctic Circumpolar Current Front: physical and biological coupling at South Georgia     

Peter Ward  Mick Whitehouse  Mike Meredith  Eugene Murphy  Rachael Shreeve  Rebecca Korb  Jon Watkins  Sally Thorpe  Rachel Woodd-Walker  Andrew Brierley  Nathan Cunningham  Sharon Grant  Doug Bone 《Deep Sea Research Part I: Oceanographic Research Papers》2002,49(12):139

The coupling of physics and biology was examined along a 160 km long transect running out from the north coast of South Georgia Island and crossing the Southern Antarctic Circumpolar Current Front (SACCF) during late December 2000. Surface and near surface potential TS properties indicated the presence of three water types: a near-shore group of stations characterised by water which became progressively warmer and fresher closer to South Georgia, an offshore grouping in which sea surface temperatures and those at the winter water level were relatively warm (1.8°C and 0.5°C, respectively), and a third in which surface and winter water temperatures were cooler and reflected the presence of the SACCF. The transect bisected the SACCF twice, revealing that it was flowing in opposite directions, north-westward closest to South Georgia and south-eastwards at its furthest point from the island. The innermost limb was a narrow intense feature located just off the shelf break in 2000–3500 m of water and in which rapid surface baroclinic velocities (up to 35 cm s⁻¹) were encountered. Offshore in the outermost limb, shown subsequently to be a mesoscale eddy that had meandered south from the retroflected limb of the SACCF, flow was broader and slower with peak velocities around 20 cm s⁻¹. Chlorophyll a biomass was generally low (<1 mg m⁻³) over much of the transect but increased dramatically in the region of the innermost limb of the SACCF, where a deepening of the surface mixed layer was coincident with a subsurface chlorophyll maximum (7.4 mg m⁻³) and elevated concentrations down to 100 m. The bloom was coincident with depleted nutrient concentrations, particularly silicate, nitrate and phosphate, and although ammonium concentrations were locally depleted the bloom lay within an elevated band (up to 1.5 mmol m⁻³) associated with the frontal jet. Increased zooplankton abundance, higher copepod body carbon mass and egg production rates all showed a strong spatial integrity with the front. The population structure of the copepods Calanoides acutus and Rhincalanus gigas at stations within the front suggested that rather than simply resulting from entrainment and concentration within the jet, increased copepod abundance was the result of development in situ. Estimates of bloom duration, based on silicate and carbon budget calculations, set the likely duration between 82 and 122 d, a figure supported by the development schedule of the two copepod species. Given this timescale, model outputs from FRAM and OCCAM indicated that particles that occurred on the north side of South Georgia in December would have been in the central-southern Scotia Sea 2–3 months earlier, probably in sea ice affected regions.  相似文献   

Large-scale environmental influences on the benthic macroinfauna of the southern Gulf of Mexico     

Hector A. Hernndez-Arana  Ashley A. Rowden  Martin J. Attrill  Richard M. Warwick  Gerardo Gold-Bouchot 《Estuarine, Coastal and Shelf Science》2003,58(4):825-841

The influence of large-scale natural disturbance from winter storms (‘northers’) and river runoff on the macrobenthic community structure of the southern Gulf of Mexico was investigated in both carbonate and transitional carbonate–terrigenous sedimentary environments. Samples of the infauna were obtained in three seasons from 13 stations from two 250 km transects along 80–170 and 20–50 m water depth. Samples after the northers season had the lowest total number of families and individuals, 114 and 2940, respectively, compared to the dry and rainy seasons with 129 and 132 families and 11580 and 15266 individuals, respectively. Spatial patterns of macroinfauna composition varied across and along the shelf as a response to sedimentary environments and depth. Coarser sediments from the carbonate area harboured the highest mean densities per station with 500–24,000 individuals m⁻² and 108–122 families in total, compared to the transitional sediment with 500–8200 individuals m⁻² and 56–74 families across the three seasons. Univariate and multivariate statistical techniques demonstrated that low densities and number of taxa were associated with winter storms, but storm influence was dependent on depth and sediment type. Multiple linear regression analysis and BIOENV analysis indicated that sediment mean grain size, percentage of clay and organic matter best explained the macroinfauna spatial patterns, although BIOENV indicated that depth has an overriding role. An increase in densities of opportunistic taxa (numerous polychaetes of small sizes) was observed four months after the ‘northers’ and this was more evident in the area of carbonate sediment. Additionally a combined disturbance from northers and river runoff is suspected to be responsible for a naturally impoverished macroinfauna community in the transitional sedimentary environment.  相似文献   

Dissolved Nutrient Fluxes through a Sandy Estuarine Beachface (Cape Henlopen,Delaware, U.S.A.): Contributions from Fresh Groundwater Discharge,Seawater Recycling,and Diagenesis     

Rebecca L. Hays  William J. Ullman 《Estuaries and Coasts》2008,31(3):606-606

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The partial molar volume, thermal expansivity, and compressibility of H2O in NaAlSi3O8 liquid: new measurements and an internally consistent model     

Frederick A. Ochs III.  Rebecca A. Lange 《Contributions to Mineralogy and Petrology》1997,129(2-3):155-165

The molar volumes of 19 hydrous albitic liquids (1.9 to 6.1 wt% H₂O^total) were determined at one bar and 505–765 K. These volume data were derived from density measurements on hydrous glasses at 298 K, followed by measurements of the thermal expansion of each glass from 298 K to its respective glass transition temperature. The technique exploits the fact that the volume of a glass is equal to that of the corresponding liquid at the limiting fictive temperature (T _f′), and that T _f′ can be approximated as the temperature near the onset of the rapid increase in thermal expansion that occurs in the glass transition interval. The volume data of this study were combined with available volume data for anhydrous, Na₂O-Al₂O₃-SiO₂ liquids to derive the partial molar volume (±1) of the H₂O component in an albitic melt at ∼565 K and one bar. To extend the determination of to higher temperatures and pressures, the molar volumes of the hydrous albitic liquids determined in this study were combined with those measured by previous authors at 1023–1223 K and 480–840 MPa, leading to the following fitted values (±1) at 1673 K and one bar: (±0.46)×10⁻³ cm⁻³/mol-K, and dVˉ ^H ₂ ^{O total} /dP=−3.82 (±0.36)×10⁻⁴ cm³/mol-bar. The measured molar volumes of this study and those of previous authors can be recovered with a standard deviation of 0.5%, which is within the respective experimental errors. There is a significant difference between the values for derived in this study as a function of temperature and pressure and those obtained from an existing polynomial, primarily caused by the previous absence of accurate density measurements on anhydrous silicate liquids. The coefficients of thermal expansion (=4.72×10⁻⁴/K) and isothermal compressibility ( _T =1.66×10⁻⁵/bar) for the H₂O component at 1273 K and 100 MPa, indicate that H₂O^total is the single most expansive and compressible component in silicate liquids. For example, at 1473 K and 70 MPa (conditions of a mid-ocean ridge crustal magma chamber), the presence of just 0.4 wt% H₂O will decrease the density of a basaltic liquid by more than one percent. An equivalent decrease in melt density could be achieved by increasing the temperature by 175 degrees or the decreasing pressure by 230 MPa. Therefore, even minor quantities of dissolved water will have a marked effect on the dynamic properties of silicate liquids in the crustal environment. Received: 20 August 1996 / Accepted: 15 March 1997  相似文献   

Molecular simulation of humic substance-Ca-montmorillonite complexes     

Rebecca Sutton  Garrison Sposito 《Geochimica et cosmochimica acta》2006,70(14):3566-3581

An understanding of the processes that lead to long-term stabilization of organic matter in soils is essential to the effective implementation of strategies designed to mitigate CO₂ loss from the soil carbon reservoir in temperate climatic zones. Decomposition studies indicate that montmorillonite, a smectite that often forms with interlayers rich in Ca²⁺, greatly retards the microbial mineralization of soil organic matter. We performed a series of atomistic simulations designed to identify favorable molecular-scale organo-mineral interactions within nanoscale, hydrated complexes consisting of a humic substance and Ca-montmorillonite. Both protonated and Ca-saturated forms of the model humic molecule, representing acidic and circumneutral solution conditions, respectively, were studied within the hydrated interlayer region of a rigid-atom model of Ca-montmorillonite. The protonated humic substance formed direct hydrophobic and hydrogen bonding (H-bonding) interactions with the clay mineral. A few polar organic groups adsorbed via water bridging interactions. The Ca-saturated humic substance adsorbed via numerous cation bridges, less numerous water bridges, and indirect H-bonding interactions mediated by water molecules. Application of molecular modeling techniques to this complex organo-mineral system thus allowed identification of interactions favorable to carbon sequestration under both acidic and circumneutral conditions.  相似文献   

Molybdenum and uranium geochemistry in continental margin sediments: Paleoproxy potential   总被引：4，自引：0，他引：4  

James McManus  William M. Berelson  Rebecca L. Poulson  Gary P. Klinkhammer 《Geochimica et cosmochimica acta》2006,70(18):4643-4662

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