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1.
Distribution of Ferric Iron in some Upper-Mantle Assemblages 总被引：16，自引：5，他引：11
The distribution of ferric iron among the phases of upper-mantlerocks, as a function of pressure (P), temperature (T) and bulkcomposition, has been studied using 57Fe Mssbauer spectroscopyto determine the Fe3+/Fe ratios of mineral separates from 35peridotite and pyroxenite samples. The whole-rock Fe3+ complementof a peridotite is typically shared approximately evenly amongthe major anhydrous phases (spinel and/or garnet, orthopyroxeneand clinopyroxene), with the important exception of olivine,which contains negligible Fe3+. Whole-rock Fe3+ contents areindependent of the T and P of equilibration of the rock, butshow a well-defined simple inverse correlation with the degreeof depletion in a basaltic component. Fe3+ in spinel and inboth pyroxenes from the spinel Iherzolite facies shows a positivecorrelation with temperature, presumably owing to the decreasein the modal abundance of spinel. In garnet peridotites, theFe3+ in garnet increases markedly with increasing T and P, whereasthat in clinopyroxene remains approximately constant. The complexnature of the partitioning of Fe3+ between mantle phases resultsin complicated patterns of the activities of the Fe3+ -bearingcomponents, and thus in calculated equilibrium fO2, which showlittle correlation with whole-rock Fe3+ or degree of depletion.Whether Fe3+ is taken into account or ignored in calculatingmineral formulae for geothermobarometry can have major effectson the resulting calculated T and P. For Fe-Mg exchange geothermometers,large errors must occur when applied to samples more oxidizedor reduced than the experimental calibrations, whose fO2 conditionsare largely unknown. Two-pyroxene thermometry is more immuneto this problem, and probably provides the most reliable P—Testimates. Accordingly, the convergence of P—T valuesderived for a given garnet peridotite assemblage may not necessarilybe indicative of mineral equilibrium. The prospects for thecalculation of accurate Fe3+ contents from electron microprobeanalyses by assuming stoichiometry are good for spinel, uncertainfor garnet, and distinctly poor for pyroxenes. KEY WORDS: mantle; oxidation; partitioning; peridotite; thermobarometry
*Corresponding author. Present address: School of Earth and Ocean Sciences, University of Victoria, P.O. Box 1700, Victoria, B.C., V8W 2Y2, Canada 相似文献
2.
The Sulfide Capacity and the Sulfur Content at Sulfide Saturation of Silicate Melts at 1400{degrees}C and 1 bar 总被引：2，自引：0，他引：2
The solubility of sulfur as S2– has been experimentallydetermined for 19 silicate melt compositions in the system CaO–MgO–Al2O3–SiO2(CMAS)± TiO2 ± FeO, at 1400°C and 1 bar, using CO–CO2–SO2gas mixtures to vary oxygen fugacity (fO2) and sulfur fugacity(fS2). For all compositions, the S solubility is confirmed tobe proportional to (fS2/fO2)1/2, allowing the definition ofthe sulfide capacity (CS) of a silicate melt as CS = [S](fO2/fS2)1/2.Additional experiments covering over 150 melt compositions,including some with Na and K, were then used to determine CSas a function of melt composition at 1400°C. The resultswere fitted to the equation 相似文献
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4.
Element Mobility During Incipient Granulite Formation at Kabbaldurga, Southern India 总被引：7，自引：2，他引：7
At Kabbaldurga, infiltration of carbonic fluids along a systemof ductile shears and foliation planes has led to partial transformationof Archaean grey biotite–hornblende gneiss to coarse-grainedmassive charnockite at about 2.5 b.y. ago. The dehydration ofthe gneiss assemblage was induced by a marked metasomatic changeof the reacting system from granodioritic to granitic, and obviouslytook place under conditions of an open system at 700–750?C and 5–7 kb. Extensive replacement of plagioclase (An16–30)by K-feldspar through Na, Ca–K exchange reactions withthe ascending carbonic fluids led to strong enrichment in K,Rb, Ba, and SiO2, and to a depletion in Ca. Progressive dissolutionof hornblende, biotite, magnetite, and the accessory mineralsapatite and zircon resulted in a marked depletion in Fe, Mg,Ti, Zn, V, P, and Zr. Most important is the recognition of REEmobility: with advancing charnockitization, the moderately fractionatedREE distribution patterns of the grey gneisses (LaN270; LaN/YbN= 5–20; EuN27; Eu/Eu* = 0.6–0.3) give way to stronglyfractionated REE patterns with a positive Eu-anomaly (LaN200;LaN/YbN = 20–80; EuN22; Eu/Eu* = 0.6–1.8). The systematicdepletion especially in the HREE is due to the progressive dissolutionof zircon, apatite (and monazite), which strongly concentratethe REE. Stable isotope data (18O of 6.9–8.0 per mille for gneissesand charnockites; 13C of –8.5 and –6.5 per millefor late carbonate) indicate a magmatogenic source for the carbonicfluids. In contrast to the currently favoured derivation ofcarbonic fluids by decarbonation of the upper mantle or degassingof underplated basaltic intrusions, it is discussed here thatabundant fluid inclusions in lower crustal charnockites providedan extensive reservoir of ‘fossil’ carbonic fluids.Shear deformation has tapped this reservoir and generated thechannel-ways for fluid ascent. Charnockitization of the Kabbaldurgatypethus appears to be a metasomatic process which is tectonicallycontrolled and restricted to the crustal level of the amphiboliteto granulite transition. 相似文献
5.
MATVEEV S.; O'NEILL H. ST. C.; BALLHAUS C.; TAYLOR W. R.; GREEN D. H. 《Journal of Petrology》2001,42(4):721-729
Hydrogen solubility and hydroxyl substitution mechanism in olivineat upper-mantle conditions are not only a function of pressure,temperature, water fugacity and hydrogen fugacity, but are alsoinfluenced by silica activity. Olivine synthesized in equilibriumwith magnesiowüstite displays hydroxyl stretching bandsin the wavenumber range from 3640 to 3430 cm–1. In contrast,olivine in equilibrium with orthopyroxene shows absorption bandsin a narrower wavenumber range from 3380 to 3285 cm–1.The two fundamentally different spectra are assigned to hydroxylin tetrahedral and octahedral sublattices, respectively. Olivinein equilibrium with orthopyroxene is also less capable of incorporatinghydroxyl, relative to olivines in equilibrium with magnesiowüstite,by about a factor of ten. A comparison of spectra obtained aspart of this study with hydroxyl spectra of natural mantle olivinesshows that the latter display hydroxyl stretching patterns reminiscentof equilibrium with magnesiowüstite, although undoubtedlyolivine in the Earth’s mantle coexists with orthopyroxene.This may be attributed to a metasomatic overprint by a low-silicafluid and/or melt that was in reaction relationship with orthopyroxene.A likely metasomatic agent is a carbonatitic melt. When carbonatiticmelts decompose to oxides and CO2, they may temporarily imposea low-aSiO2 environment inherited by the olivine structure.If this suggestion proves true, Fourier transform IR spectroscopymay be used to fingerprint metasomatic episodes in the lithosphericmantle. KEY WORDS: FTIR spectrometry; olivine; mantle; metasomatism; water 相似文献
6.
KRISTEN E. K. ST. JOHN LAWRENCE A. KRISSEK 《Boreas: An International Journal of Quaternary Research》2002,31(1):28-35
Analysis of a Miocene-Pleistocene ice-rafted debris (IRD) record from the western Irminger Basin provides evidence for the initiation and long-term behavior of the SE portion of the Greenland Ice Sheet. In the late Miocene (~7.3 Ma), IRD supply to Ocean Drilling Program site 918 increased significantly indicating that glaciers large enough to reach sea level were present in SE Greenland long before the onset of widespread Northern Hemisphere glaciation. IRD accumulated at this site throughout the Pliocene and Pleistocene, supporting the hypothesis that SE Greenland was a key nucleation area for the formation of the Greenland Ice Sheet. Since glacial onset, the western Irminger Basin IRD record is characterized by a succession of episodes with high IRD mass accumulation rates (MARs). The site 918 IRD record indicates that greatest iceberg production in SE Greenland occurred during major climatic transitions (e.g. widespread Northern Hemisphere glacial expansion at 2.7 Ma and the mid-Pleistocene climate shift at 0.9 Ma), and that SE Greenland sometimes also led the northern North Atlantic region in glacial response to climatic forcing (e.g. glacial intensification at ~4.8 and, along with NE Greenland, at ~3.5 Ma). 相似文献
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P. M. Banks T. Araki C. R. Clauer J. P. ST. Maurice J. C. Foster 《Planetary and Space Science》1984,32(12):1551-1557
This report investigates the suggestion that the pattern of plasma convection in the polar cleft region is directly determined by the interplanetary electric field (IEF). Owing to the geometrical properties of the magnetosphere, the East-West component of the IEF will drive field-aligned currents which connect to the ionosphere at points lying on either side of noon, while currents associated with the North-South component of the IEF will connect the two polar caps as sheet currents centered at noon. The effects of the hypothesized IEF driven cleft current systems on polar cap ionospheric plasma convection are investigated through a series of numerical simulations. The simulations demonstrate that this simple electrodynamic model can account for the narrow “throats” of strong dayside antisunward convection observed during periods of southward interplanetary magnetic field (IMF) as well as the sunward convection observed during periods of strongly northward IMF. Thedawn-dusk shift of polar cap convection which is related to the By component of the IMF is also accounted for by the model. 相似文献
8.
A re-evaluation of the threat status of New Zealand's marine invertebrates was undertaken in 2009, following earlier review of New Zealand's Threat Classification System and subsequent refinement of the national criteria for classifying threat of extinction to New Zealand's flora and fauna. Sufficient information was available to enable 295 marine invertebrate taxa to be fully evaluated and assigned to a national threat category. The 10 taxa at most risk of extinction (‘nationally critical’) were the giant seep clam Calyptogena sp., the primitive acorn barnacle Chionelasmus crosnieri, O'Shea's vent barnacle Volcanolepas osheai, the stalked barnacle Ibla idiotica, the four-blotched umbrella octopus Cirroctopus hochbergi, the roughy umbrella octopus Opisthoteuthis chathamensis, the giant squid Idioteuthis cordiformis, the large-egged polychaete Boccardiella magniovata and two gravel maggots, Smeagol climoi and Smeagol manneringi. The key threatening processes identified for marine invertebrates were fishing and land-use associated impacts such as sedimentation. We identified no taxa that had improved in threat status as a result of past or ongoing conservation management action, nor any taxa that had worsened in threat status because of known changes in their distribution, abundance or rate of population decline. We evaluated a small fraction of New Zealand's marine invertebrate fauna for their threat status. Many taxa remain ‘data deficient’ or unlisted. In addition to the most threatened taxa, we recommend these taxa and their habitats as priorities for further survey and monitoring. 相似文献
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River water quality, particularly in lowland catchments, is a matter of concern to the New Zealand public. We assessed river water quality and biological state and trends using data from more than 900 monitoring sites. Parallel state and trend analyses were carried out using all sites and a subset of lowland river sites. Median water-quality state in urban and pastoral land-cover classes was poorer than in exotic forest and natural land-cover classes, and lowland sites in the urban and pastoral classes had the poorest water quality. Nutrient and Escherichia coli concentrations increased and visual clarity and Macroinvertebrate Community Index scores decreased as proportions of catchments in high-intensity agricultural and urban land cover increased. Ten-year trends (2004–2013) indicated recent improvements in ammoniacal nitrogen, dissolved reactive phosphorus and total phosphorus in the pastoral and urban classes, possibly reflecting improved land management. In contrast, trends in nitrate-nitrogen in the exotic forest and cool-dry/pastoral classes indicated worsening conditions. 相似文献
10.
The Thukela Bank, KwaZulu-Natal, supports a diverse ecosystem and South Africa’s only prawn fishery. Oceanographic studies suggest riverine input is not important for the biology of this system, whereas biological studies suggest the contrary, with prawn catches increasing with increased fluvial run-off. The aim of this study was to determine (i) the importance of riverine and marine organic matter for the Thukela Bank food web; and (ii) whether there are seasonal changes in the Thukela River stable isotope values, and, if so, whether these are reflected in the isotope values of demersal organisms. Estuarine organic matter, sediments and demersal organisms were collected from several sites across the bank in the wet and dry seasons of 2008, 2009 and 2010. Marine particulate organic matter was also collected in 2010 and analysed for δ13C and δ15N, as well as C/N ratios. There were strong seasonal changes in isotopic values of organic matter and fauna, especially faunal δ13C. There was an apparent time-lag in organisms assimilating riverine organic matter isotopic values, with the isotopic signature of demersal organisms reflecting that of riverine organic matter from the previous season, which is likely the result of tissue turnover time. In 2010, Thukela Bank sediment organic matter was of riverine origin and this maintained the demersal food web. We conclude that Thukela River organic matter is an important input to the food web of the Thukela Bank, indicating that any future damming of the catchment area could have serious consequences for this ecosystem. 相似文献