Geochemistry and mineralogy of arsenic in (natural) anaerobic groundwaters     

J.A. Saunders  M.-K. Lee  M. Shamsudduha  P. Dhakal  A. Uddin  M.T. Chowdury  K.M. Ahmed 《Applied Geochemistry》2008

Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO₄ to stimulate metabolism of indigenous SO₄-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO₄, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO₄ reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS₂. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO₄ reduction commenced but increased to pre-experiment level once SO₄ reduction ended. In the ongoing experiment, both SO₄ and Fe(II) were amended to groundwater to evaluate if FeS/FeS₂ formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions.  相似文献   

Slow arsenic poisoning of the contaminated groundwater users     

M. M. Uddin  A. K. M. Harun-Ar-Rashid  S. M. Hossain  M. A. Hafiz  K. Nahar  S. H. Mubin 《International Journal of Environmental Science and Technology》2006,3(4):447-453

This paper gives impact of Arsenic contaminated water on human health as well as overview of the extent and severity of groundwater arsenic contamination in Bangladesh. Scalp hair is the most important part of the human body to monitor the accumulation of this type of poison. Therefore, an experiment has been carried out by Neutron Activation Analysis (NAA) at Atomic Energy Research Establishment (AERE), Savar, Dhaka, Bangladesh on human hair of corresponding tube well water users of these areas to determine the total accumulation of arsenic to their body. Hair samples collected from the region where the groundwater was found highly contaminated with arsenic. The obtained results of arsenic concentration in the lower age (Hb) categories of users (below 12 years of age users) is in the range of 0.33 to 3.29 /gmg/g (ppm) and that in the Hu categories (upper 12 years of age users) is 0.47 to 6.64 μg/g (ppm). Where as maximum permissible range is 1 ppm certified from WHO. Results show that the peoples are highly affected where the groundwater is highly contaminated with arsenic and acts as the primary source of arsenic poisoning among the peoples of those areas. The results indicate that human population is affected with arsenic locally using the contaminated water for a long time.  相似文献   

A new approach to estimate canopy evaporation and canopy interception capacity from evapotranspiration and sap flow measurements during and following wetting          下载免费PDF全文

J. Uddin  J. P. Foley  R. J. Smith  N. H. Hancock 《水文研究》2016,30(11):1757-1767

Canopy interception and its evaporation into the atmosphere during irrigation or a rainfall event are important in irrigation scheduling, but are challenging to estimate using conventional methods. This study introduces a new approach to estimate the canopy interception from measurements of actual total evapotranspiration (ET) using eddy covariance and estimation of the transpiration from measurements of sap flow. The measurements were conducted over a small‐scale sprinkler‐irrigated cotton field before, during and after sprinkler irrigation. Evaporation and sap flow dynamics during irrigation show that the total ET during irrigation increased significantly because of the evaporation of free intercepted water while transpiration was suppressed almost completely. The difference between actual ET and transpiration (sap flow) during and immediately following irrigation (post irrigation) represents the total canopy evaporation while the canopy interception capacity was calculated as the difference between actual ET and transpiration (sap flow) during drying (post irrigation) following cessation of the irrigation. The canopy evaporation of cotton canopy was calculated as 0.8 mm, and the interception capacity was estimated to be 0.31 mm of water. The measurement uncertainty in both the non‐dimensional ET and non‐dimensional sap flow was shown to be very low. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Anomalous optical variations in the grossular garnet from the Eden Mills,Belvidere Mountain (Vermont,USA)     

Manzoor Ahmad Badar  Safdar Hussain  Shanawer Niaz  Saif ur Rehman 《Arabian Journal of Geosciences》2016,9(9):545

The optical anomalies, and surface and lamellar textures of a birefringent grossular garnet crystal from the Eden Mills, Belvidere Mountain, Vermont, USA, have been investigated by optical polarizing microscope, electron-probe micro-analyzer, back-scattered electron imaging, infrared spectroscopy, and single-crystal X-ray diffractometer from the standpoint of crystal growth. This grossular shows one-to-one correlation between natural surface features and its internal textures under crossed polarizers. Electron-probe micro-analyzer (EPMA) gave average chemical composition in (110) thin section, of bright lamella {Ca_2.97Mn_0.06}_∑3.03 [Al_1.59Fe_0.37Ti_0.01]_∑1.97(Si_3.00)_∑3.00 (Gros_79.5And_18.9Sps_1.6) and of dark host {Ca_2.99Mn _0.06}_∑3.05 [Al_1.73Fe_0.26 Ti_0.01]_∑2.00(Si_2.97OH_0.03)_∑3.00 (Gros_85.4And₁₃Sps_1.6). The correspondence of surface features and the internal textures with spiral or pyramidal growth mechanism suggest that the internal textures of the Eden Mills grossular are formed during growth process. The optical vibrational orientations and the growth steps inclination along [001] and \( \left[\overset{-}{1}10\right] \) directions predict monoclinic symmetry. With X-ray diffractometer (XRD) method, pseudocubic parameters are a = 11.839(2) Å, b = 11.855(1) Å, and c = 11.868(2) Å with interaxial angles α = 90.00(1)°, β = 89.99(1)°, and γ = 90.02(2)° that show orthorhombic symmetry of this crystal. Lamellar texture of Al³⁺-rich host with Fe³⁺-rich lamella infers cation ordering at octahedral site of the garnet structure. IR data favors the non-cubic orientation of [(OH) ₄] at tetrahedral position in this grossular structure.  相似文献   

Prediction of ground vibration due to quarry blasting based on gene expression programming: a new model for peak particle velocity prediction   总被引：1，自引：1，他引：0  

R Shirani Faradonbeh  D Jahed Armaghani  M. Z. Abd Majid  M. MD Tahir  B. Ramesh Murlidhar  M. Monjezi  H. M. Wong 《International Journal of Environmental Science and Technology》2016,13(6):1453-1464

Blasting is a widely used technique for rock fragmentation in opencast mines and tunneling projects. Ground vibration is one of the most environmental effects produced by blasting operation. Therefore, the proper prediction of blast-induced ground vibrations is essential to identify safety area of blasting. This paper presents a predictive model based on gene expression programming (GEP) for estimating ground vibration produced by blasting operations conducted in a granite quarry, Malaysia. To achieve this aim, a total number of 102 blasting operations were investigated and relevant blasting parameters were measured. Furthermore, the most influential parameters on ground vibration, i.e., burden-to-spacing ratio, hole depth, stemming, powder factor, maximum charge per delay, and the distance from the blast face were considered and utilized to construct the GEP model. In order to show the capability of GEP model in estimating ground vibration, nonlinear multiple regression (NLMR) technique was also performed using the same datasets. The results demonstrated that the proposed model is able to predict blast-induced ground vibration more accurately than other developed technique. Coefficient of determination values of 0.914 and 0.874 for training and testing datasets of GEP model, respectively show superiority of this model in predicting ground vibration, while these values were obtained as 0.829 and 0.790 for NLMR model.  相似文献   

Geology and Active Tectonics of the Lalmai Hills,Bangladesh–An Overview from Chittagong Tripura Fold Belt Perspective     

Md. Sharif Hossain Khan  Md. Sakawat Hossain  Md. Azim Uddin 《Journal of the Geological Society of India》2018,92(6):713-720

The Lalmai Hills is a low amplitude anticline with significant variations in landforms, situated along the western fringe of the Chittagong-Tripura Fold Belt (CTFB) and immediate east of the Indo-Burmese deformation front. This fold belt of the Bengal Basin along with more easterly Indo-Burman Range (IBR) developed as a consequence of the oblique collision between Indian and Burmese plates. This neotectonic activity is still continuing and shaping the geomorphology of the area. This study is conducted based on the geomorphological observation of the topo maps and satellite images, and through reconnaissance field work. Stream length gradient index (SL Index) and Mountain front sinuosity (S_mf) reveals the relative status of tectonic activity. Anomalous SL index values confirm the position of the sympathetic minor faults and also relate to the local stratigraphy. A 2D structural model based on the seismic section reveals thrusts controlled wedge-shape upliftment of the central part as pop-up anticlinal structure. The western thrust is the direct result of the collision of the Indian and Burmese plates, and the eastern one is the back thrust of the western fault. Low S_mf value found in the western flank signifies recent tectonics and relatively high S_mf value in the eastern flank indicates that weathering intensity is relatively greater compared to western flank. Finally, the findings not only enhanced the understanding of geomorphic evolution and active tectonics of the Lalmai Hills area but also the overall tectonic and geomorphic evolution of the western most folded part of the CTFB.  相似文献   

Asymmetric behavior of different solar activity features over solar cycles 20–23     

Neeraj Singh Bankoti  Navin Chandra Joshi  Bimal Pande  Seema Pande  Wahab Uddin  Kavita Pandey 《New Astronomy》2011,16(4):269-275

This paper presents the study of normalized north–south asymmetry, cumulative normalized north–south asymmetry and cumulative difference indices of sunspot areas, solar active prominences (at total, low (?40°) and high (?50°) latitudes) and Hα solar flares from 1964 to 2008 spanning the solar cycles 20–23. Three different statistical methods are used to obtain the asymmetric behavior of different solar activity features. Hemispherical distribution of activity features shows the dominance of activities in northern hemisphere for solar cycle 20 and in southern hemisphere for solar cycles 21–23 excluding solar active prominences at high latitudes. Cumulative difference index of solar activity features in each solar cycle is observed at the maximum of the respective solar cycle suggesting a cyclic behavior of approximately one solar cycle length. Asymmetric behavior of all activity features except solar active prominences at high latitudes hints at the long term periodic trend of eight solar cycles. North–south asymmetries of SAP (H) express the specific behavior of solar activity at high solar latitudes and its behavior in long-time scale is distinctly opposite to those of other activity features. Our results show that in most cases the asymmetry is statistically highly significant meaning thereby that the asymmetries are real features in the N–S distribution of solar activity features.  相似文献   

Homologous Flares and Magnetic Field Topology in Active Region NOAA 10501 on 20 November 2003     

R. Chandra  B. Schmieder  C. H. Mandrini  P. Démoulin  E. Pariat  T. Török  W. Uddin 《Solar physics》2011,269(1):83-104

We present and interpret observations of two morphologically homologous flares that occurred in active region (AR) NOAA 10501 on 20 November 2003. Both flares displayed four homologous Hα ribbons and were both accompanied by coronal mass ejections (CMEs). The central flare ribbons were located at the site of an emerging bipole in the centre of the active region. The negative polarity of this bipole fragmented in two main pieces, one rotating around the positive polarity by ≈ 110° within 32 hours. We model the coronal magnetic field and compute its topology, using as boundary condition the magnetogram closest in time to each flare. In particular, we calculate the location of quasi-separatrix layers (QSLs) in order to understand the connectivity between the flare ribbons. Though several polarities were present in AR 10501, the global magnetic field topology corresponds to a quadrupolar magnetic field distribution without magnetic null points. For both flares, the photospheric traces of QSLs are similar and match well the locations of the four Hα ribbons. This globally unchanged topology and the continuous shearing by the rotating bipole are two key factors responsible for the flare homology. However, our analyses also indicate that different magnetic connectivity domains of the quadrupolar configuration become unstable during each flare, so that magnetic reconnection proceeds differently in both events.  相似文献   

How Can a Negative Magnetic Helicity Active Region Generate a Positive Helicity Magnetic Cloud?     

R. Chandra  E. Pariat  B. Schmieder  C. H. Mandrini  W. Uddin 《Solar physics》2010,261(1):127-148

The geoeffective magnetic cloud (MC) of 20 November 2003 was associated with the 18 November 2003 solar active events in previous studies. In some of these, it was estimated that the magnetic helicity carried by the MC had a positive sign, as did its solar source, active region (AR) NOAA 10501. In this article we show that the large-scale magnetic field of AR 10501 has a negative helicity sign. Since coronal mass ejections (CMEs) are one of the means by which the Sun ejects magnetic helicity excess into interplanetary space, the signs of magnetic helicity in the AR and MC must agree. Therefore, this finding contradicts what is expected from magnetic helicity conservation. However, using, for the first time, correct helicity density maps to determine the spatial distribution of magnetic helicity injections, we show the existence of a localized flux of positive helicity in the southern part of AR 10501. We conclude that positive helicity was ejected from this portion of the AR leading to the observed positive helicity MC.  相似文献   

Uranium (U) concentration and its genetic significance in the phosphorites of the Paleoproterozoic Bijawar Group of the Lalitpur district,Uttar Pradesh,India     

Shamim A. Dar  K. F. Khan  Saif A. Khan  Akhtar R. Mir  H. Wani  V. Balaram 《Arabian Journal of Geosciences》2014,7(6):2237-2248

The paper presents the uranium (U) concentration and distribution pattern in the Paleoproterozoic phosphorites of Lalitpur district of Uttar Pradesh. The study of thin sections, SEM and XRD reveal that apatite is the essential phosphate mineral while quartz and feldspars are the dominant gangue in the phosphorites of the investigated area. The collophane is observed to be mostly oolitic in form and microspherulitic in texture. The major element geochemistry indicated that the phosphorite samples are rich in P₂O₅, CaO, SiO₂ and Fe₂O₃ whereas depletion of MgO, MnO, K₂O and Al₂O₃ was observed. The CaO/P₂O₅ ratio ranges from 1.13 to 1.46 which is slightly lower than that of cations and anions substituted francolite (1.621) and close to that of carbonate-fluorapatite (1.318). The trace element geochemistry indicates that the phosphorites of Lalitpur have the significant range of U concentration (1.67 to 129.67 μg/g) which is more than that of Th (0.69 to 0.09 μg/g) among the analysed trace elements in the phosphorite samples of the area. The positive correlation of U with P₂O₅, CaO and U/P₂O₅ indicates a close association of U with phosphate minerals like collophane (apatite), whereas negative correlation of U with SiO₂ and Fe₂O₃ may be due to mutual replacement. The antipathetic relationship of U with Ni may be an indication of high oxidizing conditions, whereas sympathetic relationship of U with K₂O points towards higher alkaline conditions of the basin of deposition during phosphatization. The variable concentration of U and its relationship with significant major and trace elements in most of the phosphorite samples lead one to believe that the deposition of these phosphorites might have taken place in highly alkaline medium during fairly oxidizing to weakly reducing environmental conditions of geosynclinal basin.  相似文献