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1.
Time–space fractional governing equations of transient groundwater flow in confined aquifers: Numerical investigation
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In order to model non‐Fickian transport behaviour in groundwater aquifers, various forms of the time–space fractional advection–dispersion equation have been developed and used by several researchers in the last decade. The solute transport in groundwater aquifers in fractional time–space takes place by means of an underlying groundwater flow field. However, the governing equations for such groundwater flow in fractional time–space are yet to be developed in a comprehensive framework. In this study, a finite difference numerical scheme based on Caputo fractional derivative is proposed to investigate the properties of a newly developed time–space fractional governing equations of transient groundwater flow in confined aquifers in terms of the time–space fractional mass conservation equation and the time–space fractional water flux equation. Here, we apply these time–space fractional governing equations numerically to transient groundwater flow in a confined aquifer for different boundary conditions to explore their behaviour in modelling groundwater flow in fractional time–space. The numerical results demonstrate that the proposed time–space fractional governing equation for groundwater flow in confined aquifers may provide a new perspective on modelling groundwater flow and on interpreting the dynamics of groundwater level fluctuations. Additionally, the numerical results may imply that the newly derived fractional groundwater governing equation may help explain the observed heavy‐tailed solute transport behaviour in groundwater flow by incorporating nonlocal or long‐range dependence of the underlying groundwater flow field. 相似文献
2.
A constitutive model that captures the material behavior under a wide range of loading conditions is essential for simulating complex boundary value problems. In recent years, some attempts have been made to develop constitutive models for finite element analysis using self‐learning simulation (SelfSim). Self‐learning simulation is an inverse analysis technique that extracts material behavior from some boundary measurements (eg, load and displacement). In the heart of the self‐learning framework is a neural network which is used to train and develop a constitutive model that represents the material behavior. It is generally known that neural networks suffer from a number of drawbacks. This paper utilizes evolutionary polynomial regression (EPR) in the framework of SelfSim within an automation process which is coded in Matlab environment. EPR is a hybrid data mining technique that uses a combination of a genetic algorithm and the least square method to search for mathematical equations to represent the behavior of a system. Two strategies of material modeling have been considered in the SelfSim‐based finite element analysis. These include a total stress‐strain strategy applied to analysis of a truss structure using synthetic measurement data and an incremental stress‐strain strategy applied to simulation of triaxial tests using experimental data. The results show that effective and accurate constitutive models can be developed from the proposed EPR‐based self‐learning finite element method. The EPR‐based self‐learning FEM can provide accurate predictions to engineering problems. The main advantages of using EPR over neural network are highlighted. 相似文献
3.
The cosmological, astrophysical, and nucleocosmochronological methods for estimating the age of the universe and the corresponding uncertainties are comparatively studied in the present paper. We are led to the conclusion that the new measurements of cosmological parameters, and the recent estimates of the age of globular clusters have led to the gradual disappearance of the age problem from the arena of modern cosmology. 相似文献
4.
5.
SHRIMP zircon dating and Sm/Nd isotopic investigations of Neoproterozoic granitoids, Eastern Desert, Egypt 总被引:2,自引:0,他引:2
Ewais M.M. Moussa Robert J. Stern William I. Manton Kamal A. Ali 《Precambrian Research》2008,160(3-4):341-356
There is an increasing evidence for the involvement of pre-Neoproterozoic zircons in the Arabian–Nubian Shield, a Neoproterozoic crustal tract that is generally regarded to be juvenile. The source and significance of these xenocrystic zircons are not clear. In an effort to better understand this problem, older and younger granitoids from the Egyptian basement complex were analyzed for chemical composition, SHRIMP U–Pb zircon ages, and Sm–Nd isotopic compositions. Geochemically, the older granitoids are metaluminous and exhibit characteristics of I-type granites and most likely formed in a convergent margin (arc) tectonic environment. On the other hand, the younger granites are peraluminous and exhibit the characteristics of A-type granites; these are post-collisional granites. The U–Pb SHRIMP dating of zircons revealed the ages of magmatic crystallization as well as the presence of slightly older, presumably inherited zircon grains. The age determined for the older granodiorite is 652.5 ± 2.6 Ma, whereas the younger granitoids are 595–605 Ma. Xenocrystic zircons are found in most of the younger granitoid samples; the xenocrystic grains are all Neoproterozoic, but fall into three age ranges that correspond to the ages of other Eastern Desert igneous rocks, viz. 710–690, 675–650 and 635–610 Ma. The analyzed granitoids have (+3.8 to +6.5) and crystallization ages, which confirm previous indications that the Arabian–Nubian Shield is juvenile Neoproterozoic crust. These results nevertheless indicate that older Neoproterozoic crust contributed to the formation of especially the younger granite magmas. 相似文献
6.
Karst aquifers represent important water resources in many parts of the world. Unfortunately, karst aquifers are characterised
by high contamination risks. This paper presents a travel time based method for the estimation of karst groundwater vulnerability.
It considers (1) physics-based lateral flow within the uppermost weathered zone (epikarst) in a limestone-dominated region
and (2) high velocities of vertical infiltration at discrete infiltration points (e.g. sinkholes) or lines (e.g. dry valleys,
faults). Consequently, the Transit Time Method honours the actual flow path within the unsaturated zone of a karst aquifer
system. A test site in Northern Jordan was chosen for the demonstration of the assessment technique, i.e. the catchment area
of the Qunayyah Spring north of the capital Amman. The results demonstrate that zones of highest vulnerability lie within
valleys and nearby main fault zones. It also reveals that regions, categorised as protected areas by other methods due to
thick unsaturated zones, contribute to a major degree to the total risk. 相似文献
7.
David M. Sherman Caroline L. Peacock Christopher G. Hubbard 《Geochimica et cosmochimica acta》2008,72(2):298-310
Sorption of U(VI) to goethite is a fundamental control on the mobility of uranium in soil and groundwater. Here, we investigated the sorption of U on goethite using EXAFS spectroscopy, batch sorption experiments and DFT calculations of the energetics and structures of possible surface complexes. Based on EXAFS spectra, it has previously been proposed that U(VI), as the uranyl cation , sorbs to Fe oxide hydroxide phases by forming a bidentate edge-sharing (E2) surface complex, >Fe(OH)2UO2(H2O)n. Here, we argue that this complex alone cannot account for the sorption capacity of goethite (α-FeOOH). Moreover, we show that all of the EXAFS signal attributed to the E2 complex can be accounted for by multiple scattering. We propose that the dominant surface complex in CO2-free systems is a bidentate corner-sharing (C2) complex, (>FeOH)2UO2(H2O)3 which can form on the dominant {101} surface. However, in the presence of CO2, we find an enhancement of UO2 sorption at low pH and attribute this to a (>FeO)CO2UO2 ternary complex. With increasing pH, U(VI) desorbs by the formation of aqueous carbonate and hydroxyl complexes. However, this desorption is preceded by the formation of a second ternary surface complex (>FeOH)2UO2CO3. The three proposed surface complexes, (>FeOH)2UO2(H2O)3, >FeOCO2UO2, and (>FeOH)2UO2CO3 are consistent with EXAFS spectra. Using these complexes, we developed a surface complexation model for U on goethite with a 1-pK model for surface protonation, an extended Stern model for surface electrostatics and inclusion of all known UO2-OH-CO3 aqueous complexes in the current thermodynamic database. The model gives an excellent fit to our sorption experiments done in both ambient and reduced CO2 environments at surface loadings of 0.02-2.0 wt% U. 相似文献
8.
Martin R. Lee Mark E. Hodson Maureen MacKenzie Caroline L. Smith 《Geochimica et cosmochimica acta》2008,72(20):4962-4975
Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction. 相似文献
9.
Geologic relations indicate that silica phases transformed in the Monterey Formation in two zones that persist over a narrow
depth/temperature range and do not stratigraphically overlap. The wide and overlapping range of reported temperatures of these
transformations is mainly a result of the many uncertainties inherent in the different methods used to estimate temperature
and does not indicate that phases transform throughout these ranges. Our approach to a reliable temperature scale for silica
diagenesis combines as empirical zonation of silica phases with temperature calibration from a sequence at maximum temperature
and depth of burial. 相似文献
10.
Arthur C. R. Gleason Diego Lirman Dana Williams Nuno R. Gracias Brooke E. Gintert Hossein Madjidi R. Pamela Reid G. Chris Boynton Shahriar Negahdaripour Margaret Miller & Philip Kramer 《Marine Ecology》2007,28(2):254-258
Four hurricanes impacted the reefs of Florida in 2005. In this study, we evaluate the combined impacts of hurricanes Dennis, Katrina, Rita, and Wilma on a population of Acropora palmata using a newly developed video‐mosaic methodology that provides a high‐resolution, spatially accurate landscape view of the reef benthos. Storm damage to A. palmata was surprisingly limited; only 2 out of 19 colonies were removed from the study plot at Molasses Reef. The net tissue losses for those colonies that remained were only 10% and mean diameter of colonies decreased slightly from 88.4 to 79.6 cm. In contrast, the damage to the reef framework was more severe, and a large section (6 m in diameter) was dislodged, overturned, and transported to the bottom of the reef spur. The data presented here show that two‐dimensional video‐mosaic technology is well‐suited to assess the impacts of physical disturbance on coral reefs and can be used to complement existing survey methodologies. 相似文献