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1.
Soil moisture is a geophysical key observable for predicting floods and droughts, modeling weather and climate and optimizing agricultural management. Currently available in situ observations are limited to small sampling volumes and restricted number of sites, whereas measurements from satellites lack spatial resolution. Global navigation satellite system (GNSS) receivers can be used to estimate soil moisture time series at an intermediate scale of about 1000 m2. In this study, GNSS signal-to-noise ratio (SNR) data at the station Sutherland, South Africa, are used to estimate soil moisture variations during 2008–2014. The results capture the wetting and drying cycles in response to rainfall. The GNSS Volumetric Water Content (VWC) is highly correlated (r 2 = 0.8) with in situ observations by time-domain reflectometry sensors and is accurate to 0.05 m3/m3. The soil moisture estimates derived from the SNR of the L1 and L2P signals compared to the L2C show small differences with a RMSE of 0.03 m3/m3. A reduction in the SNR sampling rate from 1 to 30 s has very little impact on the accuracy of the soil moisture estimates (RMSE of the VWC difference 1–30 s is 0.01 m3/m3). The results show that the existing data of the global tracking network with continuous observations of the L1 and L2P signals with a 30-s sampling rate over the last two decades can provide valuable complementary soil moisture observations worldwide.  相似文献   
2.
Zusammenfassung Zusammenfassend ergibt sich aus der Untersuchung der Profile einer podsolierten Para-Braunerde and Para-Rendsina auf eihem kalkig gebundenen, feldspatreichen Sandstein des unteren Stubensandsteins folgender Verlauf der Verwitterung:Zunächst wird das kalkige Bindemittel herausgelöst. Dadurch entsteht ein hochporöses, hochdurchässiges Gerüst.Die Verwitterung zeigt sick im wesentlichen in einer Veränderung der Feldspite und einer Tonrnineralumbildung: Die Feldspäte warden aufgelöst, verbunden mit einern Kornzerfall in den Horizonten f (A1), Bfe und Ahe. Der primäre Illit verliert irn Verlauf der Verwitterung K+-Ionen und billet lurch Einlagerung von H3O+-Ionen quellfähige Schichten. Rises Entwicklung zeichnet sich vorwiegend im Oberboden ab. Dutch Einlagerung von Aluminiumhydroxid in die Zwischenschichten entsteht ein 14 Å-Mineral, vorwiegend im Bfe-Horizont.In dem wegen der Entkalkung hochporösen, hochdurchlässigen laden werden feinstkörnige Tonanteile durch herabsickerndes Wasser inechanisch verlagert. Dabei komInt es zu einer bevorzugten Anreicherung des feinerkörnigen Illits und des Mixed-Layer Illit-Montmorillonit im B t -Horizont, zurückbleibt das 14 Å-Mineral im Bfe-Horizont. Die Anreicherung im B t -Horizont führt zur Bildung eines auffallend plastischen Sandes (Honigsand).
Soil formation on calcite-cemented sandstone of the Middle Keuper (Stubensarldstein) is, studied in two profiles (Podsolierte Para-Braunerde and Para-Rendsina).The main results of weathering are: dissolution of calcite, alteration of feldspars and changes in the clay mineral composition.Solution of feldspars along cleavages and subsequent mechanical desintegration have caused a concentration of fine sand and silt in the top soil.Of the clay minerals in the soils, kaolinite, illite and part of the mixed layer illite-montmorillonite are inherited from the parent material.A. 14 Å mineral is restricted to the Bfe- and f(A1)-horizons of the podsolic profile. Ionic complexes of aluminium and hydroxyl released during feldspar alteration were fixed between the montmorillonite layers of the mixed layer mineral. This process, plus continuing supply of montmorillonite layers by the depletion of illite layers, resulted in the 14 Å mineral.The illite and the mixed layer mineral were found to be finer grained than the 14 Å mineral. Thus, the latter remained in the Bfe- and f(A1)-horizons, whereas the former minerals were washed down in the highly porous soil and concentrated in the Bt-horizon.
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The influence of varying groundwater flow velocities on DNAPL infiltration and spreading behaviour was investigated by multiphase modelling using TMVOC and PetraSim. The multiphase models were calibrated by results of previously conducted laboratory experiments for the complete spatio-temporal range of the experiments. The small scale 2D scenario modelling was applied to qualify and quantify changes in position, architecture, geometry and dissolution of a TCE body in a fully saturated homogeneous sandy medium. The applied flow velocities ranging from 0.05 up to 40.00 m/day exhibited that the DNAPL TCE is affected even at the lowest flow velocity in its position, its size and its architecture. Additionally, several impermeable lenses with simple geometry were assumed in the model, to investigate the influence of stratified subsoil. In the experimental set-ups, the DNAPL body reacts more sensitive to the applied groundwater flow velocities than to the geometrical set-up of the scenarios. A possible consequence can be the transportation and displacement of a DNAPL pool due to natural or anthropogenic induced high groundwater flow velocities, as by Pump and Treat facilities, complicating site investigation process and planning of remediation activities.  相似文献   
5.
In this work, investigations dealing with the determination of hydrocarbons in contaminated soil water are presented. The hydrocarbons under investigation range from low to high volatility compounds. A GC‐FID method was developed that due to its efficiency, routine suitability, relative rapidity, and low cost is suitable for the analysis of complex chemical mixtures of highly volatile hydrocarbons (with boiling points between 69 and 190°C). The standard used was a gasoline mixture with boiling points ranging from 100 to 190°C. For this standard, no supplementary preparation is needed and it is suitable for the whole range of hydrocarbons under investigation. The determination of the hydrocarbon content of the samples was performed applying univariate and multivariate statistical analysis to the experimental data. In the characterization of a contamination with highly volatile hydrocarbons of soil water originating from different depth layers from the chemistry location Leuna (Sachsen‐Anhalt, Germany), the advantages of a multivariate method are demonstrated in exemplary manner.  相似文献   
6.
Rates of transformation, recycling and burial of nitrogen and their temporal and spatial variability were investigated in deep-sea sediments of the Porcupine Abyssal Plain (PAP), NE Atlantic during eight cruises from 1996 to 2000. Benthic fluxes of ammonium (NH4) and nitrate (NO3) were measured in situ using a benthic lander. Fluxes of dissolved organic nitrogen (DON) and denitrification rates were calculated from pore water profiles of DON and NO3, respectively. Burial of nitrogen was calculated from down core profiles of nitrogen in the solid phase together with 14C-based sediment accumulation rates and dry bulk density. Average NH4 and NO3-effluxes were 7.4 ± 19 μmol m−2 d−1 (n = 7) and 52 ± 30 μmol m−2 d−1 (n = 14), respectively, during the period 1996–2000. During the same period, the DON-flux was 11 ± 5.6 μmol m−2 d−1 (n = 5) and the denitrification rate was 5.1 ± 3.0 μmol m−2 d−1 (n = 22). Temporal and spatial variations were only found in the benthic NO3 fluxes. The average burial rate was 4.6 ± 0.9 μmol m−2 d−1. On average over the sampling period, the recycling efficiency of the PON input to the sediment was 94% and the burial efficiency hence 6%. The DON flux constituted 14% of the nitrogen recycled, and it was of similar magnitude as the sum of burial and denitrification. By assuming the PAP is representative of all deep-sea areas, rates of denitrification, burial and DON efflux were extrapolated to the total area of the deep-sea floor (>2000 m) and integrated values of denitrification and burial of 8 ± 5 and 7 ± 1 Tg N year−1, respectively, were obtained. This value of total deep-sea sediment denitrification corresponds to 3–12% of the global ocean benthic denitrification. Burial in deep-sea sediments makes up at least 25% of the global ocean nitrogen burial. The integrated DON flux from the deep-sea floor is comparable in magnitude to a reported global riverine input of DON suggesting that deep-sea sediments constitute an important source of DON to the world ocean.  相似文献   
7.
Rock avalanches destroy and reshape landscapes in only a few minutes and are among the most hazardous processes on Earth. The surface morphology of rock avalanche deposits and the interaction with the underlying material are crucial for runout properties and reach. Water within the travel path is displaced, producing large impact waves and reducing friction, leading to long runouts. We hypothesize that the 0.2 km3 Holocene Eibsee rock avalanche from Mount Zugspitze in the Bavarian Alps overran and destroyed Paleolake Eibsee and left a unique sedimentological legacy of processes active during the landslide. We captured 9.5 km of electrical resistivity tomography (ERT) profiles across the rock avalanche deposits, with up to 120 m penetration depth and more than 34 000 datum points. The ERT profiles reveal up to ~50 m thick landslide debris, locally covering up to ~30 m of rock debris with entrained fine-grained sediments on top of isolated remnants of decametre-wide paleolake sediments. The ERT profiles allow us to infer processes involved in the interaction of the rock avalanche with bedrock, lake sediments, and morainal sediments, including shearing, bulging, and bulldozing. Complementary data from drilling, a gravel pit exposure, laboratory tests, and geomorphic features were used for ERT calibration. Sediments overrun by the rock avalanche show water-escape structures. Based on all of these datasets, we reconstructed both position and size of the paleolake prior to the catastrophic event. Our reconstruction of the event contributes to process an understanding of the rock avalanche and future modelling and hazard assessment. Here we show how integrated geomorphic, geophysical, and sedimentological approaches can provide detailed insights into the impact of a rock avalanche on a lake. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   
8.
Our study analyses satellite and land-based observations of the Yakutsk region centred at the Lena watershed, an area characterised mainly by continuous permafrost. Using monthly solutions of the Gravity Recovery And Climate Experiment satellite mission, we detect a mass increase over central Siberia from 2002 to 2007 which reverses into a mass decrease between 2007 and 2011. No significant mass trend is visible for the whole observation period. To further quantify this behaviour, different mass signal components are studied in detail: (1) inter-annual variation in the atmospheric mass, (2) a possible effect of glacial isostatic adjustment (GIA), and (3) hydrological mass variations. In standard processing the atmospheric mass signal is reduced based on the data from numerical weather prediction models. We use surface pressure observations in order to validate this atmospheric reduction. On inter-annual time scale the difference between the atmospheric mass signal from model prediction and from surface pressure observation is $<$ 4 mm in equivalent water height. The effect of GIA on the mass signal over Siberia is calculated using a global ice model and a spherically symmetric, compressible, Maxwell-viscoelastic earth model. The calculation shows that for the investigated area any effect of GIA can be ruled out. Hence, the main part of the signal can be attributed to hydrological mass variations. We briefly discuss potential hydrological effects such as changes in precipitation, river discharge, surface and subsurface water storage.  相似文献   
9.
The ~0.2 km3 Eibsee rock avalanche impacted Paleolake Eibsee and completely displaced its waters. This study analyses the lake impact and the consequences, and the catchment response to the landslide. A quasi-3D seismic reflection survey, four sediment cores from modern Lake Eibsee, reaching far down into the rock avalanche mass, nine radiocarbon ages, and geomorphic analysis allow us to distinguish the main rock avalanche event from a secondary debris avalanche and debris flow. The highly fluidized debris avalanche formed a megaturbidite and multiple swashes that are recorded in the lake sediments. The new calibrated age for the Eibsee rock avalanche of ~4080–3970 cal yr BP indicates a coincidence with rockslides in the Fernpass cluster and subaquatic landslides in Lake Piburg and Lake Plansee, and raises the possibility that a large regional earthquake triggered these events. We document a complex history of erosion and sedimentation in Lake Eibsee, and demonstrate how the catchment response and rebirth of the lake are revealed through the complementary application of geophysics, sedimentology, radiocarbon dating, and geomorphology. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   
10.
Tidal and seasonal behaviour of the redox-sensitive trace metals Mn, Fe, Mo, U, and V have been investigated in the open-water column and shallow pore waters of the backbarrier tidal flats of the island of Spiekeroog (Southern North Sea) in 2002 and 2007. The purpose was to study the response of trace metal cycles on algae blooms, which are assumed to cause significant changes in the redox state of the entire ecosystem. Trace metal data were complemented by measurements of nutrients and enumeration of algae cells in 2007. Generally, Mn and V show a tidal cyclicity in the water column with maximum values during low tide which is most pronounced in summer due to elevated microbial activity in the sediments. Mo and U behave almost conservatively throughout the year with slightly increasing levels towards high tide. Exceptions are observed for both metals after summer algae blooms. Thus, the seasonal behaviour of the trace metals appear to be significantly influenced by productivity in the water column as the occurrence of algae blooms is associated with an intense release of organic matter (e.g. transparent exopolymer particles, TEP) thereby forming larger organic-rich aggregates. Along with elevated temperatures in summer, the deposition of such aggregates favours microbial activity within the surface sediments and release of DOC, nutrients and trace metals (Mn, Mo and V) during the degradation of the aggregates. Additionally, pronounced reducing conditions lead to the reduction of Mn(IV)-oxides and Fe(III)-(oxihydr)oxides, thereby releasing formerly scavenged compounds as V and phosphate. Therefore, pore-water profiles show significant enrichments in trace metals especially from July to September. Finally, the trace metals are released to the open water column via draining pore waters (esp. Mo, Mn, and V) and/or fixed in the sediment as sulphides (Fe, Mo) and bound to organic matter (U). Non-conservative behaviour of Mo in oxygenated seawater, first observed in the investigation area by Dellwig et al. (Geochim Cosmochim Acta 71:2745–2761, 2007a), was shown to be a recurrent phenomenon which is closely coupled to bacterial activity after the breakdown of algae blooms. In addition to the postulated fixation of Mo in oxygen-depleted micro-zones of the aggregates or by freshly formed organic matter, a direct removal of Mo from the water column by reduced sediment surfaces may also play an important role.  相似文献   
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