Equilibrium response of thermohaline circulation to large changes in atmospheric CO2 concentration     

R. J. Stouffer  S. Manabe 《Climate Dynamics》2004,22(2-3):325-326

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Century-Scale Change in Water Availability: CO2-Quadrupling Experiment     

S. Manabe  R. T. Wetherald  P. C. D. Milly  T. L. Delworth  R. J. Stouffer 《Climatic change》2004,64(1-2):59-76

It has been suggested that, unless a major effort is made, the atmospheric concentration of carbon dioxide may rise above four times the pre-industrial level in a few centuries. Here we use a coupled atmosphere-ocean-land model to explore the response of the global water cycle to such a large increase in carbon dioxide, focusing on river discharge and soil moisture. Our results suggest that water is going to be more plentiful in those regions of the world that are already `water-rich'. However, water stresses will increase significantly in regions and seasons that are already relatively dry. This could pose a very challenging problem for water-resource management around the world. For soil moisture, our results indicate reductions during much of the year in many semi-arid regions of the world, such as the southwestern region of North America, the northeastern region of China, the Mediterranean coast of Europe, and the grasslands of Australia and Africa. In some of these regions, soil moisture values are reduced by almost a factor of two during the dry season. The drying in semi-arid regions is likely to induce the outward expansion of deserts to the surrounding regions. Over extensive regions of both the Eurasian and North American continents in high and middle latitudes, soil moisture decreases in summer but increases in winter, in contrast to the situation in semi-arid regions. For river discharge, our results indicate an average increase of ～ 15% during the next few centuries. The discharges from Arctic rivers such as the Mackenzie and Ob' increase by much larger fractions. In the tropics, the discharges from the Amazonas and Ganga-Brahmaputra also increase considerably. However, the percentage changes in runoff from other tropical and many mid-latitude rivers are smaller.  相似文献   

Theoretical and experimental evidence for the post-cotunnite phase transition in zirconia at high pressure     

Daisuke Nishio-Hamane  Haruhiko Dekura  Yusuke Seto  Takehiko Yagi 《Physics and Chemistry of Minerals》2015,42(5):385-392

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Raman spectra of methane hydrate up to 86 GPa     

Shin-Ichi Machida  Hisako Hirai  Taro Kawamura  Yoshitaka Yamamoto  Takehiko Yagi 《Physics and Chemistry of Minerals》2007,34(1):31-35

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.  相似文献   

The use of sintered diamond anvils in the MA8 type high-pressure apparatus     

Tadashi Kondo  Hiroshi Sawamoto  Akira Yoneda  Manabu Kato  Akihito Matsumuro  Takehiko Yagi  Takumi Kikegawa 《Pure and Applied Geophysics》1993,141(2-4):601-611

A new multi-anvil type high-presure apparatus has been developed using sintered diamond anvils to generate pressures over 30 GPa and temperatures up to about 2000°C. A maximum sample volume of about 1 mm³ is available in this system. The pressure was confirmed by dissociation of forsterite into Mg-perovskite and periclase. The basic techniques and problems in utilizing sintered diamond in the MA8 type high-pressure apparatus are discussed with an emphasis on the future prospect of incorporating simultancous X-ray diffraction observation.  相似文献   

Equilibrium interface segregation in the diopside-forsterite system I: Analytical techniques, thermodynamics, and segregation characteristics     

Takehiko Hiraga  David L. Kohlstedt 《Geochimica et cosmochimica acta》2007,71(5):1266-1280

After syntheses of partially molten diopside-forsterite polycrystalline aggregates doped with various solutes, we analyzed the equilibrium segregation of Ni, Mn, Sr, Al, Yb, Y, Nd, La, and Ti at interfaces between diopside/diopside, diopside/forsterite and, forsterite/forsterite grains based on STEM/EDX (scanning transmission electron microscopy/energy dispersive X-ray spectrometry) to examine the effects of ionic size, valence state, co-segregation, and interface type on interface chemistry. We derive relationships between two quantities describing interface segregation and X-ray intensities acquired both from areas that include an interface and from areas that do not. These segregation quantities are (i) interface excess density and (ii) interface enrichment factor, which rely on Gibbsian thermodynamics and the Langmuir-McLean segregation model, respectively. Interface excess densities, which vary from −0.5 to 10 atoms/nm², indicate that the level of interface excess density depends on solutes and sample assemblage. Interface enrichment factors, which range from almost 1 to 130, reveal that the ionic size of the solutes affects their segregation via production of misfit lattice strain due to the difference between the size of a solute ion and that of the ideal strain-free lattice site. The ionic sizes of Yb and Y are almost identical to the size of the strain-free site; however, their segregation is significant indicating that a difference in valence state between the host elements (i.e., Ca and Mg) and the solutes also drives segregation. In contrast to other solutes, segregation characteristics of Al differ from these simple segregation rules. Segregation quantities do not change with interface type, indicating that the number of sites available for segregants and the driving force for segregation are similar among type of interfaces. We compare the element partitioning between diopside-melt and diopside-interfaces within the same sample assemblages. These two partition coefficients coincide if we approximate the number of segregation sites at interfaces as equivalent to 2 mono-atomic layers. Examination of the energetics in crystal-melt partitioning reveals that the interface segregation energy is essentially equal to the solute solution energy in a crystal.  相似文献   

Equilibrium interface segregation in the diopside-forsterite system II: Applications of interface enrichment to mantle geochemistry     

Takehiko Hiraga  Marc M. Hirschmann 《Geochimica et cosmochimica acta》2007,71(5):1281-1289

Segregation of incompatible elements at grain interfaces may have considerable influence on the physical and chemical properties of mantle rocks. Using a recently developed predictive model to estimate the interface enrichment of elements based on their mineral/melt partitioning (Hiraga and Kohlstedt, companion paper), we consider interface enrichment for a simplified model peridotite consisting of olivine, orthopyroxene, and clinopyroxene. Our calculated results reveal the following: (1) Significant amounts of heavy alkali elements and rare gases likely reside at grain-grain interfaces, whereas interface concentrations of less incompatible are less pronounced. (2) The contribution of the chemical components stored at interfaces to whole-rock chemistry strongly depends on mineral mode and, most importantly, on grain size. (3) Grain size reduction resulting from dynamic recrystallization can increase the total storage of highly incompatible elements on grain interfaces and thereby will diminish their concentration in mineral grains. (4) Analysis of Cs concentrations in mantle clinopyroxenes potentially provides estimates of the grain size of mantle rocks. (5) Transport through peridotite will be dominated by diffusion along interfaces rather than through grain interiors for elements less compatible than Lu.  相似文献   

Effect of hydrostatic pressure on the lattice parameters of Fe₂SiO₄ olivine up to 70 kbar     

Takehiko Yagi  Yoshiaki Ida  Yosiko Sato  Syun-Iti Akimoto 《Physics of the Earth and Planetary Interiors》1975,10(4):348-354

The pressure dependence of the three lattice parameters and unit cell volume of fayalite (Fe₂SiO₄ olivine) was determined by X-ray diffraction under hydrostatic pressures up to 70 kbar. In order to eliminate stress inhomogeneity within a composite material consisting of a specimen mixed with an internal-pressure standard, a liquid (1 : 1 mixture of ethanol and methanol) was used as a pressure-transmitting medium. The isothermal bulk modulus calculated on the basis of the second-order Birch-Murnaghan equation of state gives the values K₀ = 1.19 ± 0.10 Mbar and K₀′ = 7 ± 4, and if we assume K₀′ = 5: K₀ = 1.24 ± 0.02 Mbar. Three axes of fayalite were found to be compressible in the following order, b >c >a. Comparisons with the results obtained under non-hydrostatic compression are made.  相似文献   

Discussant's comments on “the effects of changes in ocean temperature on the atmosphere”     

S. Manabe 《Dynamics of Atmospheres and Oceans》1979,3(2-4)

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Reversed magnetozone in the late Pleistocene sediments from the Pacific coast of Odaka, northeast Japan     

Ken-Ichi Manabe 《Quaternary Research》1977,7(3):372-379

Paleomagnetic measurements have been carried out on 103 specimens taken at about 15 cm intervals in a sea cliff exposing the marine terrace formation. Secondary components were removed by partial demagnetization in a peak field of 200 Oe. Two short reversed magnetozones are recognized. Geological and biostratigraphical evidence indicates that they are equivalent to the Blake event, which was first reported by Smith and Foster (1969) (Science 163, 565–567) from the North Atlantic deep-sea cores. The present result suggests a split nature for the Blake Event.  相似文献