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M. Tamzid Rahman T. Kameda S. Kumagai T. Yoshioka 《International Journal of Environmental Science and Technology》2018,15(2):263-272
Health hazards from heavy metal pollution in water systems are a global environmental problem. Of similar concern is sludge that results from wastewater treatment due to unsatisfactory sludge management technology. Therefore, the effectiveness of using Mg–Al-layered double hydroxide in the removal of heavy metals from mine wastewater was tested and compared with that of calcium hydroxide [Ca(OH)2], which is a common treatment method for heavy metal removal. Initially, the mine wastewater contained cations of the heavy metals iron (Fe), zinc (Zn), copper (Cu), and lead (Pb). The Mg–Al-layered double hydroxides were able to remove 371, 7.2, 121, and 0.4 mg/L of these pollutants, respectively, using the co-precipitation method. The removal of these metals is most effective using 0.5 g Mg–Al-layered double hydroxide (Mg/Al molar ratio 4) and 20 min of shaking. Zn was removed by the formation of Zn(NO3)(OH)·H2O and Zn5(NO3)2(OH)8 when LDH, Mg/Al molar ratios of 4 and 2, respectively, were used. Similarly, Fe, Cu, and Pb were removed by the formation of Fe–Al-layered double hydroxide, Cu2(OH)3·NO3 and Pb4(OH)4(NO3)4, respectively. While Ca(OH)2 is also capable of reducing the heavy metal concentrations below the Japanese recommended values, this analysis shows that using 0.5 g Mg–Al-layered double hydroxide is a better treatment condition for mine wastewater, because it generates lower sludge volumes than 0.1 g of Ca(OH)2. The measured sludge volume was 1.5 mL for Mg–Al-layered double hydroxide and 2.5 mL for Ca(OH)2, a nearly twofold further reduction. 相似文献
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Hypervelocity impact experiments are carried out with alumina ceramic targets at impact velocities of 2-4 km/s. The fractal dimension (or roughness exponent) of fragment surfaces is estimated by two different methods (different length scales). One is a divider method (large scale) and the other is a gas-absorption one (small scale). The obtained fractal dimensions are different: ∼2.2-2.4 for larger scale and ∼2.5-2.7 for smaller scale. These values are regardless of the degree of fragmentation. 相似文献
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Chlorophyll biomass off Sanriku, northwestern Pacific, estimated by Ocean Color and Temperature Scanner (OCTS) and a vertical distribution model 总被引：2，自引：0，他引：2
To estimate chlorophyll biomass from satellite-derived data, we established an empirical model for the estimation of the chlorophyll
vertical profile as a function of surface chlorophyll for four separate regions of the Sanriku area, using algorithms based
upon ship observations from 1986 to 1995. The modeled profiles compared well with observations during the Sanriku Field Campaign.
Chlorophyll biomass in the Sanriku Area estimated by a combination of OCTS data and the model varied from 2.6×104 t in the Oyashio water to 8.2×103 t in the Kuroshio water. 相似文献
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To understand the fundamental chemical processes of fluid–rock interaction during the pulverization of quartz grains in fault zones, quartz grains were crushed within pure water. The crushing experiments were performed batch style using a shaking apparatus. The crushing process induced a decrease in pH and an increase in hydrogen gas with increased shaking duration. The amount of hydrogen ions generated was five times larger than that of the hydrogen gas, which was consistent with the amount of Si radicals estimated from electron spin resonance measurements by Hochstrasser and Antonini (1972). This indicates that hydrogen gas was generated by consuming most of the Si radicals. The generation of hydrogen ions was most likely related to the presence of silanols on the newly formed mineral surface, implying a change of proton activities in the fluid after pulverization of quartz. 相似文献
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Shota Mochizuki Takuhiko Murakami 《International Journal of Applied Earth Observation and Geoinformation》2011
The aim of this study was to evaluate changes in macaque habitat selection during a 29-year period. We focused on the 1970s, when little crop damage was caused by Japanese macaques (Macaca fuscata), and the 2000s, when the damage became remarkable. Landsat/MSS from 1978 and ALOS/AVNIR-2 from 2007 were employed for land-cover mapping. For the 2007 land-cover classification, we applied an object-oriented image classification and a classification and regression tree. The Kappa coefficient of the 2007 land-cover map was 0.89. For the 1978 land-cover classification, change detection using principal component analysis and object-oriented image classification were applied to reduce resolution difference errors. The Kappa coefficient of the 1978 land-cover map was 0.84. We applied a Random Forest model for machine learning and data mining to predict the habitat selection of macaques. Several important environmental factors were identified for macaque habitat selection: the ratio of coniferous forest to farmland, distance to farmland, and maximum snow depth. The Random Forest model was extrapolated to the 1978 land-cover map. Over the 29-year period, coniferous forest changed to broad-leaved forest and/or mixed forest within the macaque habitat area. Coniferous forests were not selected as food resources by Japanese macaques. Furthermore, large-scale patches of farmland were used as food resources over the 29-year period. These changes indicated that habitat selection by Japanese macaques changed over the study period. The results show that the home range of macaques expanded, and macaques may now be distributed over a wider area as a result of changes in landscape configuration. Thus, forest planning, such as sustainable management of artificial conifer forests, is important for reducing crop damage. 相似文献
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Early stage processes of Mg-rich chlorite (clinochlore) dissolution were examined, focusing especially on the structural modification
at grain edges during dissolution. Focused ion beam transmission electron microscopy sample preparation was applied to crystals
dissolved in a flow-through reaction system at pH 3.0 and 25°C for 31 days. The obtained Si and Mg dissolution rates are −11.49
and −11.14 (logR, mol/(m2/s)), respectively, implying dissolution is non-stoichiometric. TEM-EDX analyses of dissolved samples reveal the development
of 20–50-nm thick amorphous zone at an outermost rim with a chemical gradient of Mg, lower towards the solid surface, and
Si enrichment in this amorphous zone. Crystalline material is partially interwoven with amorphous one at the interface between
the amorphous and crystalline regions. These results indicate that the amorphous zone was produced by selective leaching of
cations except for Si. Chlorite dissolution may proceed via the formation and thickening of leached layer as a by-product
of release to solution of Si at slightly slower rate than Mg. 相似文献
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