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1.
The spatial and temporal dynamics of dissolved inorganic nitrogen, dissolved phosphate, dissolved silica and chlorophyll a were measured seasonally at eight stations in the Ria de Aveiro. Between December 2000 and September 2001, the seasonal succession of phytoplankton assemblages, inferred after the spatial and seasonal variation of silica and of chlorophyll a concentrations, showed that diatoms (μmol Si L−1) dominated from late autumn until early spring, while chlorophytes (μg Chl a L−1) bloomed during late spring and summer. The Si:N:P ratios and Si concentrations indicated no seasonal depletion in dissolved silica, as in other temperate systems, possibly because of abnormal precipitation and flood events prolonging the supply of dissolved Si to the system. The Si:N:P ratios suggested P limitation at the system level. Despite the relative proportions of available nutrients, the mean phosphorus concentration (5.3 μmol L−1) was above the reported half-saturation constants for P uptake by phytoplankton. Thus, in Ria de Aveiro, the seasonal succession of phytoplankton assemblages may also be dependent on the grazing capacity of the pelagic community through top-down regulation.  相似文献   
2.
Iron-rich concretions are frequently found around plant roots in Tagus estuary (Portugal) where radial delivery of O2 takes place. Salt marsh sediments exhibit cracks that are an additional feature to introduce O2 and other solutes in the upper sediments. Metal concentrations in salt marsh sediments are clearly above the background levels reflecting the anthropogenic sources from a large city with 2.5 million inhabitants, and several industrial centres. In order to evaluate how both oxidised structures influences the redistribution of redox sensitive elements in salt marsh sediments, concretions were collected from roots of Halimione portucaloides below the oxygenated zone. These tubular cylindrical structures were analysed for Fe, Al, Mn, As, and P along 1-cm radial transect in a millimetre scale from the inner part to the adjacent anoxic sediment. In addition, oxidised cracks were analysed for the same spatial resolution, from the sediment–water interface to anoxic layers (2-cm transept). The parallelism between Fe, As, and P concentrations at this microscale is the most noticeable aspect. Iron and As presented very high concentrations in the 4-mm concretions (3.4 mmol g−1 and 3.1 μmol g−1, respectively) and decreased sharply to the host sediment. Oxygen released from roots oxidise the solid sulphides, and the reduced Fe and As are transported towards the root by both diffusion and pore water flow associated with the root water uptake. Subsequently, Fe(III) precipitates and As is retained by sorption and/or coprecipitation. These elements are also enriched in the first 2-mm of oxidised cracks, but in lower concentrations (50% and 30%, respectively). Manganese concentrations in concretions were low (11.8 μmol g−1), indicating that Fe dominates the sediment chemistry. Phosphorus and iron concentrations in the ascorbate fraction were higher in the oxidising surfaces of concretions (10.7 μmol g−1 and 1.6 mmol g−1, respectively) and of cracks (5.1 μmol g−1 and 0.47 mmol g−1). The parallelism of Fe and As distributions includes not only their similar redox chemistries, but also that to phosphate, including control by coprecipitation of the host iron phases. The mechanisms involved in the mobilisation of As and P are however different, whereas As comes from the oxidation of iron sulphides; dissolved P derives from reduction of ferri-hydroxide phases.  相似文献   
3.
Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
4.
A flyschoid facies occurs in the Bezno Formation (Coniacian up to Santonian) of the eastern marginal part of the Bohemian Cretaceous Basin. According toJerzykiewicz (1970, 1971) this facies is of deep water, turbidite origin. He based his interpretation on the study of sedimentary structures. New palaeogeographic reconstruction of lithofacies relations, investigation of deep drillings and detailed sedimentological analysis, however, allowed new results concerning the sedimentary environments and depositional mechanism of this facies. According to the new model presented here, this flyschoid facies was deposited in a shallow marine environment. Clayey sedimentation was the natural response to normal environmental conditions, whereas sandstone intercalations reflect anomalous conditions during heavy storms. During these events, sands were transported basinwards up to distances of 25 km, with normal bottom currents, as well as turbidity currents, acted as transporting mechanisms. This flyschoid facies corresponds to other examples of clayey sequences with sandy storm layers.
Zusammenfassung Die Bezno Schichtenfolge (Coniac bis Santon) enthält im östlichen Randteil des Böhmischen Kreidebeckens sogenannte flyschoide Fazies. NachJerzykiewicz (1970, 1971) entstand sie im tiefen Wasser wie echte Turbidite. Die paläogeographische Rekonstruktion von Faziesbeziehungen, ausführliche Bearbeitung der Schichtenfolge in Bohrungen, und vollständige Beckenanalyse ermöglichten eine Neudeutung von Transportmechanismen und Ablagerungsmilieu. Es werden Beweise für Flachwassersedimentation erbracht. Das Sedimentationsgebiet entsprach einem Bereich der Tonablagerung, der von Zeit zu Zeit während anomaler Bedingungen — seltenen, sehr schweren Sturmfluten durch Sandzufuhr gestört wurde. Während dieser Sturmfluten wurde Sand ins Becken geschüttet bis zu einer Entfernung von 25 km von der Küste. Die Funktion von Traktionströmen wird diskutiert im Verhältnis zum Einfluß von Trübeströmen. Die beschriebene flyschoide Fazies entspricht Schichtfolgen mit sandigen Sturmflutlagen.

Résumé Dans la partie marginale du Bassin Crétacée de Bohême, la formation de Bezno (Coniacien à Santonien) est caractérisée par le développement du faciès flyschoide. Ce faciès a été étudié parJerzykiewicz (1970, 1971), qui a proposé son origine dans un bassin profond, sous l'activité de courants de turbidité. L'étude détaillée de la succession des couches dans les forages profonds, de nouvelles données sédimentologiques ainsi que la reconstruction paléogéographique ont amené l'auteur à établir un nouveau modèle de mécanisme de transport dans les milieux de sédimentation. Selon ce modèle le faciès flyschoid se déposerait dans la mer épicontinentale peu profonde. Les argiles marquent les conditions normales de ce milieu sédimentaire; les grès reflètent des conditions hydrodynamiques anomales au cours de tempêtes rares et très fortes. Durant ces tempêtes les sables côtiers ont été redéposés dans des fonds plus profonds jusqu' à une distance de 25 km. La fonction des courants de traction est discutée en rapport avec l'influence des courants de turbidité entant qu' agents de transport. Le faciès étudié est comparable avec les séquences des argiles à intercalations de grès.

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5.
This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.  相似文献   
6.
It is well known that individual impairments create disparities in the accessibility of individuals to opportunities, lengthening the distances or time needed to reach them or even completely impeding access. However, the accurate calculation and representation of these disparities remain a major challenge for urban and transportation planners. In this paper, we adopt the concept of accessibility disparity, originally applied to measure place accessibility by different modes of transport, to measure and represent the accessibility of individuals with physical disabilities compared to those without disabilities. We use spatial network analysis to calculate spatial connectivity and the accessibility of Lisbon’s city center, revealing what we define as ‘disability-induced accessibility disparity’. Our results reveal not only the locations responsible for reduced accessibility, i.e., barriers and/or deterrents to movement, but also how much any given disparity reduces the accessibility of an individual, allowing the use of this methodology by planners to identify critical areas and to design inclusive public spaces.  相似文献   
7.
Sediment gravity cores and grab samples were collected in the Sado Estuary and in its coastal area. The cores were sliced on board and the percentage of weight loss on ignition was determined in the laboratory, and analysed for polychlorinated biphenyl (PCB) congeners. PCB contents were higher in samples from the North Channel of the estuary, nearby the industrial zone (max. 114 ng g-1 dry weight), while levels in the coastal area were lower than 4.9 ng g-1. The concentrations of the quantified congeners varied irregularly with sediment depth in the estuary, but showed two opposite distribution patterns in cores from the coastal area: the proportions of lower chlorinated congeners increased with depth, while congeners with higher number of chlorines decreased. This suggests a dechlorination of the most chlorinated congeners into less toxic compounds, under reductive conditions of the sediment. Though measurements were done in natural environment it appears that dechlorination was not entirely dependent on chlorine position in the phenyl rings.  相似文献   
8.
Juvenile Senegalese soles were exposed through 28-day laboratory and field (in situ) bioassays to sediments from three sites of the Sado estuary (W Portugal): a reference and two contaminated by metallic and organic contaminants. Fish were surveyed for ten hepatic histopathological alterations divided by four distinct reaction patterns and integrated through the estimation of individual histopathological condition indices. Fish exposed to contaminated sediments sustained more damage, with especial respect to regressive changes like necrosis. However, differences were observed between laboratory- and field-exposed animals, with the latest, for instance, exhibiting more pronounced fatty degeneration and hepatocellular eosinophilic alteration. Also, some lesions in fish exposed to the reference sediment indicate that in both assays unaccounted variables produced experimental background noise, such as hyaline degeneration in laboratory-exposed fish. Still, the field assays yielded results that were found to better reflect the overall levels of contaminants and physico-chemical characteristics of the tested sediments.  相似文献   
9.
The abundance and distribution of rare earth elements (REE) and their signatures in the Vigo Ria were studied from 50 samples of surface sediments and related to the geological formation in its watershed. The total amount of REE in the Ria is heterogeneous. It ranges from 220 mg kg−1 in the southern middle Ria margin in the vicinity of the Galiñeiro geological shore complex, which contains REE-enriched minerals, to 2 mg kg−1 near the Ria mouth due to dilution with high levels of carbonated biogenic particles (31% of Ca). Rare earth elements of the Ria sediments are considerably enriched in light-REE relative to heavy-REE (a LREE/HREE ratio of 9.7±1.6) and also show a slightly negative Eu-anomaly. Low European shale normalised REE patterns were distinguished in the innermost sediments of Vigo Ria, but were not correlated with Al. This suggests a minor contribution of REE from upstream freshwater inputs to the sediments in the middle Vigo Ria zone. Normalised REE ratios in the middle Ria imply that fine particles enriched in REE may be exported from the Ria to shelf mud patches and REE can be useful as sediment tracers of Ria input on the shelf.  相似文献   
10.
Facies evolution and vertical changes within the Late Cretaceous sequence of the Bohemian Cretaceous Basin reveal fluctuations of intra- and extrabasinal circumstances. Evidence of periodic oscillations is recognized and two categories of aperiodic event indications are distinguished according to their significance and lateral persistence. Several lithoevents may be related to eustatic changes, while others indicate the independent evolution of the basin, influenced by epeirogenetic movements of segments of the Bohemian Massif.  相似文献   
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