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In 1903 the Swiss Federal Research Institute WSL started its first forest hydrology measurements with the aim to deliver a sound scientific basis for the implementation of new forest legislation introduced in Switzerland in 1876. This legislation was triggered by several large floods that occurred in Switzerland, for which a major cause was widely seen as the poor condition of forests at that time. Consequently, hydrologic research at WSL first focused on the influence of forests on floods. In the second half of the 20th century, other hydrological issues such as water quality, snow hydrology and sediment transport complemented the hydrologic research at WSL. Some recent results of this work are presented in three papers joining this introductory paper to mark the 100th anniversary of hydrologic research at WSL. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
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Limitations of the ferrozine method for quantitative assay of mineral systems for ferrous and total iron 总被引:1,自引:0,他引:1
Alexandre S. Anastácio Hae-In Yoo Joseph W. Stucki 《Geochimica et cosmochimica acta》2008,72(20):5001-5008
The quantitative assay of clay minerals, soils, and sediments for Fe(II) and total Fe is fundamental to understanding biogeochemical cycles occurring therein. The commonly used ferrozine method was originally designed to assay extracted forms of Fe(II) from non-silicate aqueous systems. It is becoming, however, increasingly the method of choice to report the total reduced state of Fe in soils and sediments. Because Fe in soils and sediments commonly exists in the structural framework of silicates, extraction by HCl, as used in the ferrozine method, fails to dissolve all of the Fe. The phenanthroline (phen) method, on the other hand, was designed to assay silicate minerals for Fe(II) and total Fe and has been proven to be highly reliable. In the present study potential sources of error in the ferrozine method were evaluated by comparing its results to those obtained by the phen method. Both methods were used to analyze clay mineral and soil samples for Fe(II) and total Fe. Results revealed that the conventional ferrozine method under reports total Fe in samples containing Fe in silicates and gives erratic results for Fe(II). The sources of error in the ferrozine method are: (1) HCl fails to dissolve silicates and (2) if the analyte solution contains Fe3+, the analysis for Fe2+ will be photosensitive, and reported Fe(II) values will likely be greater than the actual amount in solution. Another difficulty with the ferrozine method is that it is tedious and much more labor intensive than the phen method. For these reasons, the phen method is preferred and recommended. Its procedure is simpler, takes less time, and avoids the errors found in the ferrozine method. 相似文献
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A new class of phytoplankton models with a mechanistic basis has been presented in a companion paper (Baklouti, M., Diaz, F., Pinazo, C., Faure, V., Queguiner, B., 2006. Investigation of mechanistic formulations depicting phytoplankton dynamics for models of marine pelagic ecosystems. Progress in Oceanography). It is the default class of models implemented in our new numerical tool Eco3M, which is dedicated to Ecological, Mechanistic and Modular Modelling. A brief overview of its main features is given in Section 2 of the present paper. In the next sections, a particular phytoplankton model among the aforementioned class has been tested with special emphasis on the mechanistic photosynthesis component relating the photosynthetic rate to the proportion of open photosystems II. The present study encompasses several essential steps that are inherent to any modelling, including model reduction, model sensitivity analysis and comparison of model outputs with experiments. The global sensitivity analysis of the plankton model for one-at-a-time parameter perturbations revealed a restricted set of parameters having major influence on the model outputs. Sensitivity tests involving simultaneous parameter perturbations within the range actually encountered in the literature provided a confidence interval for the outputs. Chemostat experiments performed on nitrate-limited diatoms grown under low (LL) and high-light (HL) conditions have been used for comparison with model outputs. The good fit between measured data and model outputs using the same parameter values in both the LL and HL cases demonstrates the ability of our model to represent the main features of phytoplankton dynamics including photoacclimation. Finally, Eco3M is ultimately intended to include explicit bacterial and zooplankton compartments, as well as to be coupled with ocean circulation models, but the intrinsic behavior of the phytoplankton model has been investigated first, independently of physical forcing. 相似文献
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Jean-Pascal Torrton Emma Rochelle-Newall Aymeric Jouon Vincent Faure Sverine Jacquet Pascal Douillet 《Estuarine, Coastal and Shelf Science》2007,74(4):766
Hydrodynamic modeling can be used to spatially characterize water renewal rates in coastal ecosystems. Using a hydrodynamic model implemented over the semi-enclosed Southwest coral lagoon of New Caledonia, a recent study computed the flushing lag as the minimum time required for a particle coming from outside the lagoon (open ocean) to reach a specific station [Jouon, A., Douillet, P., Ouillon, S., Fraunié, P., 2006. Calculations of hydrodynamic time parameters in a semi-opened coastal zone using a 3D hydrodynamic model. Continental Shelf Research 26, 1395–1415]. Local e-flushing time was calculated as the time requested to reach a local grid mesh concentration of 1/e from the precedent step. Here we present an attempt to connect physical forcing to biogeochemical functioning of this coastal ecosystem. An array of stations, located in the lagoonal channel as well as in several bays under anthropogenic influence, was sampled during three cruises. We then tested the statistical relationships between the distribution of flushing indices and those of biological and chemical variables. Among the variables tested, silicate, chlorophyll a and bacterial biomass production present the highest correlations with flushing indices. Correlations are higher with local e-flushing times than with flushing lags or the sum of these two indices. In the bays, these variables often deviate from the relationships determined in the main lagoon channel. In the three bays receiving significant riverine inputs, silicate is well above the regression line, whereas data from the bay receiving almost insignificant freshwater inputs generally fit the lagoon channel regressions. Moreover, in the three bays receiving important urban and industrial effluents, chlorophyll a and bacterial production of biomass generally display values exceeding the lagoon channel regression trends whereas in the bay under moderate anthropogenic influence values follow the regressions obtained in the lagoon channel. The South West lagoon of New Caledonia can hence be viewed as a coastal mesotrophic ecosystem that is flushed by oligotrophic oceanic waters which subsequently replace the lagoonal waters with water considerably impoverished in resources for microbial growth. This flushing was high enough during the periods of study to influence the distribution of phytoplankton biomass, bacterial production of biomass and silicate concentrations in the lagoon channel as well as in some of the bay areas. 相似文献
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Miriam Borba-Roschel Anne Alexandre Anglica Fortes Drummond Chicarino Varajo Jean Dominique Meunier Csar Augusto Chicarino Varajo Fabrice Colin 《Journal of Geochemical Exploration》2006,88(1-3):172
This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed. 相似文献
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A design procedure is proposed to minimize water infiltration into landfills by optimizing the water diversion length of inclined
covers with capillary barrier effect (CCBE). This design procedure is based on a conceptual, mathematical and numerical approach
and aims at selecting materials and optimizing layer thickness. Selection among candidate materials is made based on their
hydraulic conductivity functions and on a threshold infiltration rate imposed on the designer. The capillary break layer (CBL;
bottom layer) is characterized by a weak capillarity, while the moisture retention layer (MRL; upper layer) is characterized
by a compromise between strong capillarity and high hydraulic conductivity. The thickness of the CBL corresponds to the height
where suction reaches its maximum value for a given infiltration rate. This height can be calculated using the Kisch [Géotechnique 9 (1959)] model. The optimal thickness of the MRL is determined by applying an adaptation of the Ross [Water Resources Research 26 (1990)] model. The results obtained using the proposed design procedure were compared to those obtained from numerical simulations
performed using a finite element unsaturated seepage software. The procedure was applied for two cover systems; one where
deinking by-products (DBP) were used as MRL and sand as CBL and another where sand was used as MRL and gravel as CBL. Using
this procedure, it has been shown that an infiltration control system composed of thin layers of sand over gravel is highly
efficient in terms of diversion length and that its efficiency can be enhanced by placing a hydraulic barrier – such as a
layer of DBP – above the MRL. 相似文献