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In the present study, measurements of surface ozone (\(\hbox {O}_{3}\)) and its precursors (NO and \(\hbox {NO}_{2}\)) were carried out at a sub-urban site of Agra (\(27{^{\circ }}10'\hbox {N}\), \(78{^{\circ }}05'\hbox {E}\)), India during May 2012–May 2013. During the study period, average concentrations of \(\hbox {O}_{3}\), NO, and \(\hbox {NO}_{2}\) were \(39.6 \pm 25.3\), \(0.8 \pm 0.8\) and \(9.1 \pm 6.6 \, \hbox {ppb}\), respectively. \(\hbox {O}_{3}\) showed distinct seasonal variation in peak value of diurnal variation: summer \({>}\) post-monsoon \({>}\) winter \({>}\) monsoon. However, \(\hbox {NO}_{2}\) showed highest levels in winter and lowest in monsoon. The average positive rate of change of \(\hbox {O}_{3}\) (08:00–11:00 hr) was highest in April (16.3 ppb/hr) and lowest in August (1.1 ppb/hr), while average negative rate of change of \(\hbox {O}_{3}\) (17:00–19:00 hr) was highest in December (–13.2 ppb/hr) and lowest in July (–1.1 ppb/hr). An attempt was made to identify the \(\hbox {VOC--NO}_{\mathrm{x}}\) sensitivity of the site using \(\hbox {O}_{3}/\hbox {HNO}_{3}\) ratio as photochemical indicator. Most of the days this ratio was above the threshold value (12–16), which suggests \(\hbox {NO}_{\mathrm{x}}\) sensitivity of the site. The episodic event of ozone was characterized through meteorological parameters and precursors concentration. Fine particles (\(\hbox {PM}_{2.5}\)) cause loss of ozone through heterogeneous reactions on their surface and reduction in solar radiation. In the study, statistical analyses were used to estimate the amount of ozone loss.  相似文献   
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The effects of soil–structure interaction (SSI) while designing the liquid column damper (LCD) for seismic vibration control of structures have been presented in this study. The formulation for the input–output relation of a flexible‐base structure with attached LCD has been presented. The superstructure has been modelled by a single‐degree‐of‐freedom (SDOF) system. The non‐linearity in the orifice damping of the LCD has been replaced by equivalent linear viscous damping by using equivalent linearization technique. The force–deformation relationships and damping characteristics of the foundation have been described by complex valued impedance functions. Through a numerical stochastic study in the frequency domain, the various aspects of SSI on the functioning of the LCD have been illustrated. A simpler approach for studying the LCD performance considering SSI, using an equivalent SDOF model for the soil–structure system available in literature by Wolf (Dynamic Soil–Structure Interaction. International Series in Civil Engineering and Engineering Mechanics. Prentice‐Hall: Englewood Cliffs, NJ, 1985) has also been presented. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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Chlorophyll fluorescence is an indicator of plant photosynthetic activity and has been used to monitor the health status of vegetation. Several studies have exploited the application of red/far-red chlorophyll fluorescence ratio in detecting the impact of various types of stresses in plants. Recently, sunlight-induced chlorophyll fluorescence imaging has been used to detect and discriminate different stages of mosaic virus infection in potted cassava plants with a multi-spectral imaging system (MSIS). In this study, the MSIS is used to investigate the impact of drought and herbicide stress in field grown crop plants. Towards this control and treatment groups of colocasia and sweet potato plants were grown in laterite soil beds and the reflectance images of these crop plants were recorded up to 14-days of treatment at the Fraunhofer lines of O2 B at 687 nm and O2 A at 759.5 nm and the off-lines at 684 and 757.5 nm. The recorded images were analyzed using the Fraunhofer Line Discrimination technique to extract the sunlight-induced chlorophyll fluorescence component from the reflectance images of the plant leaves. As compared to the control group, the chlorophyll fluorescence image ratio (F 687/F 760) in the treatment groups of both the plant varieties shows an increasing trend with increase in the extent of stress. Further, the F 687/F 760 ratio was found to correlate with the net photosynthetic rate (Pn) and stomatal conductance (gs) of leaves. The correlation coefficient (R 2) for the relationship of F 687/F 760 ratio with Pn were found to be 0.78, 0.79 and 0.78, respectively for the control, herbicide treated and drought treated colocasia plants, while these were 0.77, 0.86 and 0.88, respectively for sweet potato plants. The results presented show the potential of proximal remote sensing and the application F 687/F 760 fluorescence image ratio for effective monitoring of stress-induced changes in field grown plants.  相似文献   
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Glaciological mass balance(MB)is considered the most direct,undelayed and unfiltered response of the glaciers to climatic perturbations.However,it may inherit errors associated with stake underrepresentation,averaging over the entire glacier and human bias.Therefore,proper validation of glaciological MB with geodetic MB is highly recommended by the World Glacier Monitoring Service(WGMS).The present study focuses on the Dokriani Glacier,central Himalaya which is one of the bench-mark glaciers in the region and has glaciological MB records from 1993 to 2013 with intermittent gaps.In the present study,firstly the glaciological MB series is extended to 2014 i.e.,field-based MB for one more year is computed and,to compare with it,the geodetic MB is computed for the 1999–2014 period using high resolution Cartosat-1 digital elevation model(DEM)and SRTM DEM.Finally,the study assesses the regional representation of the Dokriani Glacier in terms of MB and evaluates the influence of the MB regime on its morphological evolution.Results show that the average glaciological MB(-0.34±0.2 m water equivalent(w.e.)y-1)is more negative than the geodetic MB(-0.23±0.1 m w.e.y-1)for the 1999–2014 period.This is likely because of the partial representation of glacier margins in the glaciological MB,where melting is strikingly low owing to thick debris cover(>30 cm).In contrast,geodetic MB considers all marginal pixels leading to a comparatively low MB.A comparative assessment shows that the MB of Dokriani Glacier is less negative(possibly due to its huge accumulation area)than most other glacier-specific and regional MBs,restricting it to be a representative glacier in the region.Moreover,continuous negative MB has brought a peculiar change in the epiglacial morphology in the lower tongue of the glacier as differential debris thickness-induced differential melting has turned the glacier surface into a concave one.This concavity has led to development of a large(10–20 m deep)supraglacial channel which is expanding incessantly.The supraglacial channel is also connected with the snout wall and accelerates terminus disintegration.Given the total thickness of about 30–50 m in the lower glacier tongue,downwasting at its current pace,deepening/widening of supraglacial channel coupled with rapid terminus retreat may lead to the complete vanishing of the lower one km glacier tongue.  相似文献   
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Life cycle of glaciers in the Himalayan region has notably changed due to the climatic variability since last few decades. Glaciers across the world and specially the Himalayan glaciers have shown large scale degeneration in the last few decades. Himalayan glaciers serve as an important fresh water resource for the downstream communities, who are dependent on this water for domestic and other purposes. Therefore, glacier shrinkage and the associated hydrological changes pose a significant problem for regional-scale water budgets and resource management. These issues necessitate the regular and rigorous monitoring of the wastage pattern of the Himalayan glaciers in field and using satellite remote sensing data. In this work, we report rapid and enhanced degeneration of the frontal part of the Kangriz glacier, Jammu and Kashmir(J K), in terms of surface melting, debris cover, snout characteristics and meltwater discharge. Ablation data acquired during 2016-2017 shows the average lowering of the frontal part of the glacier to be ~148 ± 34 cm, one-third of which was found to have occurred within a 13 day time period in September, 2017. Also, the quantum of ice melt was found to be inversely influenced(r =-0.84) by the debris thickness. 15 day meltwater discharge measurement revealed its strong relationship with snout disintegration pattern, evidenced twice during the said time period. Volume of water discharged from the glacier was estimated to be 7.91×10~6 m~3 for the measurement duration. Also, mean daily discharge estimated for the 15 days interval showed good positive correction(r = 0.78) with temperature indicating the direct dependency of the former on land surface temperature conditions of the region. Besides the lowering and discharge observations, the frequent ice-block break-offs at the glacier snout further enhance its overall drastic degeneration. The study suggests that, being the largest glacier in the Suru basin, the Kangriz glacier needs to be continuously monitored in order to understand its glacio-hydrological conditions.  相似文献   
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Arsenic (As) and fluoride (F?) in groundwater are increasing global water quality and public health concerns. The present study provides a deeper understanding of the impact of seasonal change on the co-occurrence of As and F?, as both contaminants vary with climatic patterns. Groundwater samples were collected in pre- and post-monsoon seasons (n = 40 in each season) from the Brahmaputra flood plains (BFP) in northeast India to study the effect of season on As and F? levels. Weathering is a key hydrogeochemical process in the BFP and both silicate and carbonate weathering are enhanced in the post-monsoon season. The increase in carbonate weathering is linked to an elevation in pH during the post-monsoon season. A Piper diagram revealed that bicarbonate-type water, with Na+, K+, Ca2+, and Mg2+ cations, is common in both seasons. Correlation between Cl? and NO3 ? (r = 0.74, p = 0.01) in the post-monsoon indicates mobilization of anthropogenic deposits during the rainy season. As was within the 10 µg L?1 WHO limit for drinking water and F? was under the 1.5 mg L?1 limit. A negative correlation between oxidation reduction potential and groundwater As in both seasons (r = ?0.26 and ?0.49, respectively, for pre-monsoon and post-monsoon, p = 0.05) indicates enhanced As levels due to prevailing reducing conditions. Reductive hydrolysis of Fe (hydr)oxides appears to be the predominant process of As release, consistent with a positive correlation between As and Fe in both seasons (r = 0.75 and 0.73 for pre- and post-monsoon seasons, respectively, at p = 0.01). Principal component analysis and hierarchical cluster analysis revealed grouping of Fe and As in both seasons. F? and sulfate were also clustered during the pre-monsoon season, which could be due to their similar interactions with Fe (hydr)oxides. Higher As levels in the post-monsoon appears driven by the influx of water into the aquifer, which drives out oxygen and creates a more reducing condition suitable for reductive dissolution of Fe (hydr)oxides. An increase in pH promotes desorption of As oxyanions AsO4 3? (arsenate) and AsO3 3? (arsenite) from Fe (hydr)oxide surfaces. Fluoride appears mainly released from F?-bearing minerals, but Fe (hydr)oxides can be a secondary source of F?, as suggested by the positive correlation between As and F? in the pre-monsoon season.  相似文献   
10.
We present data from three acoustic Doppler current profilers (ADCPs) moored off Cuddalore (12°N), Kakinada (16.5°N), and Gopalpur (19°N) on the continental slope of the western Bay of Bengal and one mooring on the slope of the northern bay (89°E, 19°N; referred to as being located at Paradip). The data were collected during May 2009 to March 2013 and the observations show that the seasonal cycle, which includes the annual cycle, the semi-annual cycle, and a peak around 120 days, dominates the observed variability of the East India Coastal Current (EICC). Spectral analysis suggests that the 120-day peak dominates the seasonal variability at Paradip and is strong at Gopalpur and Kakinada. The annual cycle is coherent along the western boundary of the bay, i.e., the east coast of India, but with significant phase differences between moorings. At the semi-annual and 120-day periods, the alongshore coherence is weaker. Intraseasonal variability is weaker than the seasonal cycle, particularly at Cuddalore and Paradip, and it exhibits seasonality: the strongest intraseasonal variation is during spring (February–April). Peaks around 12 and 20–22 days are also seen at Gopalpur, Kakinada, and Cuddalore. A striking feature of the currents is the upward phase propagation, but there are also instances when phase propagates downward. The much lower vertical phase speed in the top ~100 m at Cuddalore leads to a distinct undercurrent at this location; at other locations, the undercurrent, though it exists often, is not as striking. During spring, however, the EICC tends to flow poleward (eastward) at Cuddalore, Kakinada, and Gopalpur (Paradip) over the top ~300 m, which is the maximum depth to which observations were made. The cross-shore component of the EICC is much weaker than the alongshore component at Cuddalore and, except for a few bursts during spring, at Kakinada and Gopalpur. It is only at Paradip, on the slope of the northern boundary, that significant cross-shore flows are seen during spring and the summer monsoon (June–August) and these flows are seen to be associated with eddy-like circulations in the altimeter data. We use the ADCP data to validate popular current data products like OSCAR (Ocean Surface Currents Analyses Real-time), ECCO2 (Estimating the Circulation and Climate of the Ocean, Phase II), and GODAS (Global Ocean Data Assimilation System). The OSCAR currents at Paradip match the observed currents well, but the correlation is much weaker at the other three locations. Both ECCO2 and GODAS fair poorly, particularly the latter because its variability in this boundary-current regime is extremely weak. Though it performs badly at Paradip, ECCO2 does capture the observed variability on occasions at the other locations.  相似文献   
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