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Xanthates are used in the flotation of sulfide ores although their aqueous solutions are not stable under certain conditions. Their stability in acidic and weakly acidic aqueous solutions was therefore investigated, as these media are required for some processes.The peak absorbances of ethylxanthate ion and carbon disulfide were first determined in aqueous solution. The decomposition of ethylxanthate ion was analyzed by measuring variations in absorbance (at 301 nm) and pH with respect to time. A pH regulation system was then used while measuring variations in absorbance and productions of protons caused by xanthate decomposition.The results concerning xanthate half-lives show good agreement with the literature, but the kinetic results deviate substantially. The following relation was obtained for half-life:
T12=9.67×10?6(pH)11;4?7;T12in seconds
We established that ethylxanthate decomposition at pH 4 is a first order reaction with respect to ethylxanthate concentration, and postulating this order to the other pH values, the following kinetic relation was found:
v= ?(1.22×104[H+]?1.36×10?2)([EtX?]) (4?pH?7)
where v is the rate of decomposition (mol l?1 min?1), and [EtX?] is the ethylxanthate concentration when the decomposition equilibria are reached (mol l?1). The better concentration was found to obey the law:
[EtX?]=3.142×10?5 pH ? 1.255 × 10?4 (4?pH?6)
  相似文献   
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In February 2008, cruise P362/2 was undertaken aboard R/V Poseidon to the Giza and North Alex mud volcanoes (MVs) on the upper slope of the western Nile deep-sea fan. Emitted fluids were strongly depleted in chloride and rich in hydrocarbons, predominantly of thermogenic origin. In-situ sediment temperature measurements indicate extremely high and moderate levels of activity for the North Alex MV and Giza MV, respectively, and suggest rapid changes from dormant to active stages. Both the physical properties of core sediments (e.g., color and magnetic susceptibility), and their assemblages of micro- and nannofossils point to different sources for the two mud volcanoes. Biostratigraphic dating suggests source depths of 2,100–2,450 mbsf for the Giza MV and 1,150–1,550 mbsf for the North Alex MV. Very high temperatures of up to 70°C in shallow sediments at the North Alex MV can be explained only if the fluid source were warmer and deeper than the sediment source.  相似文献   
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We have examined forty-two carbon stars which show excess emission at 60 and/or 100µm by applying maximum-entropy image reconstruction techniques to the IRAS 60µm survey data. Thirteen stars are found to be extended in the reconstructed images. Four of them show a detached ring centered on the stellar position. In particular, U Ant may have a double detached dust shell. The implications of our results are discussed concerning the variation of mass loss on the AGB evolution.  相似文献   
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Contrasting regional discharge evolutions in the Amazon basin (1974–2004)   总被引:1,自引:0,他引:1  
Former hydrological studies in the Amazon Basin generally describe annual discharge variability on the main stem. However, the downstream Amazon River only represents the mean state of the Amazonian hydrological system. This study therefore uses a new data set including daily discharge in 18 sub-basins to analyze the variability of regional extremes in the Amazon basin, after recalling the diversity of the hydrological annual cycles within the Amazon basin. Several statistical tests are applied in order to detect trends and breaks in the time series. We show that during the 1974–2004 period, the stability of the mean discharge on the main stem in Óbidos is explained by opposite regional features that principally involve Andean rivers: a decrease in the low stage runoff, particularly important in the southern regions, and an increase in the high stage runoff in the northwestern region. Both features are observed from the beginning of the nineties. These features are also observed in smaller meridian sub-basins in Peru and Bolivia. Moreover we show that the changes in discharge extremes are related to the regional pluriannual rainfall variability and the associated atmospheric circulation as well as to tropical large-scale climatic indicators.  相似文献   
7.
Basin‐wide correlation of Messinian units and Plio‐Quaternary chronostratigraphic markers (5.3 Ma, 2.6 Ma, 0.9 Ma and 0.45 Ma), the mapping of total sediment thickness and the determination of overall sedimentary volumes enabled us to provide a high‐resolution quantitative history of sediment volumes for the last 6 Ma along the Gulf of Lions margin. The results point to (i) a dramatic increase in terrigenous sediment input during the Messinian Salinity Crisis. This increased sedimentation reflects enhanced regional fluvial erosion related to the dramatic fall of Mediterranean base‐level. Stronger weathering due to a regional wetter climate probably also increased erosional fluxes. (ii) A sediment input three times higher during the Plio‐Quaternary compared to the Miocene seems in agreement with published measurements from World's ocean. However, the timing of this increase being uncertain, it implies that the trigger(s) also remain(s) uncertain. (iii) A decrease in detrital volume around 2.6 Ma is attributed to a regional change in the drainage pattern of rivers in the northwestern Alps. (iv) This study also highlights the Mid‐Pleistocene Revolution around 0.9 Ma, which resulted in an almost doubling of sediment input in the Provencal Basin.  相似文献   
8.
Computer-assisted analyses of more than 600 radiocarbon-dated sea-level indicators from northwestern Europe, concentrated around the North Sea margin, indicate that vertical crustal movements are more important that eustatic sea-level change in determining the locus of Holocene shoreline positions through time. For the past 14,000 radiocarbon years, the divergence of sea-level data for the northwest European sectors exceeds the maximum estimated sea-level rise by a factor of two or more. Projecting these data to a single meridian demonstrates the remarkable variety of vertical crustal movement in northwestern Europe.Accumulating radiocarbon-dated sea-level indicators into millennial cohorts, we generate isobase maps which begin to specify areas of notable vertical crustal mobility. These isobase maps appear to confirm that eustatic sea-level rise is subordinate to postglacial geoidal excursions in determining the locus of contemporary northwestern European shorelines.  相似文献   
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In this article, we propose an investigation of the modifications of the hydrological response of two Peruvian Amazonas–Andes basins in relationship with the modifications of the precipitation and evapotranspiration rates inferred by the IPCC. These two basins integrate around 10% of the total area of the Amazonian basin. These estimations are based on the application of two monthly hydrological models, GR2M and MWB3, and the climatic projections come from BCM2, CSMK3 and MIHR models for A1B and B1 emission scenarios (SCE A1B and SCE B1). Projections are approximated by two simple scenarios (anomalies and horizon) and annual rainfall rates, evapotranspiration rates and discharge were estimated for the 2020s (2008–2040), 2050s (2041–2070) and 2080s (2071–2099). Annual discharge shows increasing trend over Requena basin (Ucayali river), Puerto Inca basin (Pachitea river), Tambo basin (Tambo river) and Mejorada basin (Mantaro river) while discharge shows decreasing trend over the Chazuta basin (Huallaga river), the Maldonadillo basin (Urubamba river) and the Pisac basin (Vilcanota river). Monthly discharge at the outlet of Puerto Inca, Tambo and Mejorada basins shows increasing trends for all seasons. Trends to decrease are estimated in autumn discharge over the Requena basin and spring discharge over Pisac basin as well as summer and autumn discharges over both the Chazuta and the Maldonadillo basins. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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