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1.
The Cassini Visual and Infrared Mapping Spectrometer (VIMS) is an imaging spectrometer covering the wavelength range 0.3-5.2 μm in 352 spectral channels, with a nominal instantaneous field of view of 0.5 mrad. The Cassini flyby of Jupiter represented a unique opportunity to accomplish two important goals: scientific observations of the jovian system and functional tests of the VIMS instrument under conditions similar to those expected to obtain during Cassini's 4-year tour of the saturnian system. Results acquired over a complete range of visual to near-infrared wavelengths from 0.3 to 5.2 μm are presented. First detections include methane fluorescence on Jupiter, a surprisingly high opposition surge on Europa, the first visual-near-IR spectra of Himalia and Jupiter's optically-thin ring system, and the first near-infrared observations of the rings over an extensive range of phase angles (0-120°). Similarities in the center-to-limb profiles of H+3 and CH4 emissions indicate that the H+3 ionospheric density is solar-controlled outside of the auroral regions. The existence of jovian NH3 absorption at 0.93 μm is confirmed. Himalia has a slightly reddish spectrum, an apparent absorption near 3 μm, and a geometric albedo of 0.06±0.01 at 2.2 μm (assuming an 85-km radius). If the 3-μm feature in Himalia's spectrum is eventually confirmed, it would be suggestive of the presence of water in some form, either free, bound, or incorporated in layer-lattice silicates. Finally, a mean ring-particle radius of 10 μm is found to be consistent with Mie-scattering models fit to VIMS near-infrared observations acquired over 0-120° phase angle.  相似文献   
2.
Dale P. Cruikshank 《Icarus》1980,41(2):240-245
The reflectance spectrum of Io is presented from 2.8 to 5.2 μm, extending the earlier results of D. P. Cruikshank, T. J. Jones, and C. B. Pilcher (1978, Astrophys. J. 225, L89–L92), and demonstrating the full extent of the broad and deep spectral absorption between 3.5 and 4.8 μm. Laboratory spectra of nitrates and carborates diluted with sulfur do not satisfactorily reproduce the Io spectrum, but new information based on the recently discovered volcanic activity on the satellite lead to consideration of other classes of compounds as reported in a companion paper (F. P. Fanale, R. H. Brown, D. P. Cruikshank, and R. N. Clark, 1979, Nature280, 761–763).  相似文献   
3.
Spectrophotometric data show that major compositional groups among outer solar system (OSS) surfaces include bright ices and at least two distinct classes of blackish carbonaceous-like materials, called C-type and RD-type. VJHK colorimetry of asteroids, satellites, and laboratory samples shows that these three classes can be distinguished by VJHK colors. We define an “α index” that denotes the position of objects in VJHK color - color diagrams; it empirically increases with albedo and ice/dirt ratio. We use the above data to define color fields that may be useful in interpreting our observations of eight comets (1980–1981). All eight comets have colors generally resembling RD asteroids and are inconsistent with reflection off clean ice surfaces. The observations suggest that these comets' halos contain RD dirt or dirty ice grains colored by RD dirt, supporting J. Gradie and J. Veverka's [Nature283, 840–842 (1980)] prediction of RD, rather than C, material in comets. Remote Comet P/Schwassmann-Wachmann 1 was observed both during outburst and quiescence and had the highest α index of any observed comet. Comet α indices appear to be correlated with solar distance. Further work will be needed to clarify possible coloring effects due to particle size, dispersal, and composition. We suggest a number of physical interpretations based on a single two-component mixing model, which assumes that all OSS planetesimals formed primarily from bright ices and dark carboneceous-like dirt, consistent with condensation theory. We discuss differentiation processes that concentrated one component or the other at the surface. All measured OSS interplanetary bodies have surfaces of dark dirt or dark dirty ice colored by the dirt component. Comets, consistent with the Whipple dirty iceberg model, are such objects close enough to the Sun for volatilization to throw dirty ice grains into the coma. In remote comets, the ice component of the grains remains stable, and we see dirty ice grains; in near comets, the ice component vaporizes, and we see dirt grains. A volatile-depleted dusty regolith on P/Schwassmann-Wachmann 1 and other remote comets could explain their eruptive behavior by means of gas pressure buildup in the porous, weakly bonded dust.  相似文献   
4.
ABSTRACT

To investigate the uptake and depuration of polycyclic aromatic hydrocarbons associated with the Rena oil spill we sampled the surf clam Paphies subtriangulata at two open coast locations (6?km apart) just prior to oil coming ashore (7 October 2011), then at 1–3 week intervals for the next 4 months. Total polycyclic aromatic hydrocarbons (tPAH) increased at both sites from 1 to 96–124?µg?kg?1 (wet weight) by 18 October before declining to low levels (<4?µg?kg?1) by February 2012. Ongoing sampling throughout 2012–2014 included three additional sites to the north east (up to 30?km away) and a site 5?km to the south east revealing tPAH levels generally <10?µg?kg?1 except in October 2013 where levels ranged between 39–45?µg?kg?1 at all sites. A comparison of PAH component profiles with oil-contaminated beach sediment indicated that the high levels observed in surf clams between October–December 2011 were clearly associated with the Rena spill. However, the October 2013 peak had a PAH profile inconsistent with weathered Rena oil, suggesting an alternative source of contamination. Our results highlight the potential for P. subtriangulata as a PAH monitoring tool but recognise more study is needed to better quantify baseline levels and uptake and depuration dynamics.  相似文献   
5.
We review the photometric work on eclipse reappearances of Io. New observations of eclipse reappearances of Io confirm the post-eclipse brightness anomaly reported by Binder and Cruikshank (1964) but testify to its intermittent nature. A post-eclipse anomaly of approximately 0.07 mag was observed on two occasions in 1972, while observations of Europa and Ganymede showed no brightness anomaly greater than 0.01 mag. The atmospheric condensation model for the anomaly on Io is reviewed in terms of the quantity of frost required to produce the effect and the corresponding amount of gas liberated to the atmosphere upon sublimation. The observational data and the results from a stellar occultation are in general accord with the theoretical predictions of the stability of heavy gases on Io, while both observational and theoretical criteria are satisfied by a tenuous atmosphere of a heavy gas such as methane or ammonia having a surface pressure ~10?7 bar.  相似文献   
6.
Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO2) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm−1), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO2 absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO2, CO2 clathrates, ternary mixtures of CO2 with other volatiles, implanted and adsorbed CO2 in non-volatile materials, and ab initio theoretical calculations of CO2 * nH2O. At the wavelength resolution of VIMS, the CO2 on Phoebe is indistinguishable from pure CO2 ice (each molecule’s nearby neighbors are also CO2) or type II clathrate of CO2 in H2O. In contrast, the CO2 band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm−1)) and broadened. These wavelengths are characteristic of complexes of CO2 with different near-neighbor molecules that are encountered in other volatile mixtures such as with H2O and CH3OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO2 is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO2 on the other three satellites results at least in part from particle or UV irradiation of native H2O plus a source of C, implantation or accretion from external sources, or redistribution of native CO2 from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO2 gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO2 absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO2 absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO2, as discussed in this paper.  相似文献   
7.
We present near-IR spectra of solid CO2 in H2O and CH3OH, and find they are significantly different from that of pure solid CO2. Peaks not present in either pure H2O or pure CO2 spectra become evident when the two are mixed. First, the putative theoretically forbidden CO2 (2ν3) overtone near 2.134 μm (4685 cm−1), that is absent from our spectrum of pure solid CO2, is prominent in the spectra of H2O/CO2=5 and 25 mixtures. Second, a 2.74-μm (3650 cm−1) dangling OH feature of H2O (and a potentially related peak at 1.89 μm) appear in the spectra of CO2-H2O ice mixtures, but are probably not diagnostic of the presence of CO2. Other CO2 peaks display shifts in position and increased width because of intermolecular interactions with H2O. Warming causes some peak positions and profiles in the spectrum of a H2O/CO2=5 mixture to take on the appearance of pure CO2. Absolute strengths for absorptions of CO2 in solid H2O are estimated. Similar results are observed for CO2 in solid CH3OH. Since the CO2 (2ν3) overtone near 2.134 μm (4685 cm−1) is not present in pure CO2 but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO2 is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies.  相似文献   
8.
This paper presents new photometric and spectrophotometric observations of the dark (leading) hemisphere of Saturn's satellite Iapetus. Spectrophotometry from 0.3–1.0 um (May 1979) shows the dark hemisphere to be very red, similar to a few asteroids and the Moon, but with no spectral features attributable to olivine or pyroxene. Near-infrared spectrophometry in the regions 1.4–2.5 um (May 1981) and 3.0–3.8 um (February 1981) reveals water ice absorption bands, probably resulting from the polar caps intruding onto the dark hemisphere. The reflectance of Iapetus is unlike that of carbonaceous chondrites or C-type asteroids and most closely resembles the reflectance (and low albedo) of carbonaceous (organic) residue from the Murchison C2 carbonaceous chondrite. The Murchison material has the same red slope and a probable spectral feature near 0.6 um seen in Iapetus data. Three hypotheses for the formation of the dark hemisphere are discussed in light of the observational data. The favored hypothesis is that debris from Phoebe or other unknown outer satellites of Saturn impacts the dark hemisphere of Iapetus as Poynting-Robertson drag causes the debris to spiral toward Saturn. The high-velocity impacts preferentially remove ice from the satellite's surface, causing enrichment of included carbonaceous material intrinsic to Iapetus. The reflectance of Phoebe itself is significantly different from that of Iapetus, suggesting that relatively little Phoebe debris lies on the dark hemisphere. There remains the possibility that the impacting debris originates from another body of composition similar to the Murchison residue and that this material is exposed on the surface of Iapetus.  相似文献   
9.
New spectra of Jupiter in the region 0.93–1.63 are presented. Laboratory comparisons of spectra of NH3 and CH4 permit estimates of the absorbing pathlength for various bands of these two gases. Abundances in a single transmission through the Jupiter atmosphere, above the mean reflecting level, vary from 10 to 100 m-atm for CH4 and from 0.2–5 m-atm for NH3, depending on the bands considered. Upper limits for other gases are derived from new laboratory spectra and comparison with the Jupiter spectra presented herein. These are as follows: C2H2<2 m-atm, H2S<0.25 m-atm, HCN<0.05 m-atm, CH3NH2<0.02 m-atm. A table summarizing the chemical composition of Jupiter's atmosphere is presented.  相似文献   
10.
Infrared spectrophotometric measurements of Neptune's satellite Triton obtained between 1980 and 1982 in the spectral range 0.8–2.5 μm show six individual absorption bands attributable to methane. An additional band in the Triton data is not methane. The Triton spectral data conform more closely to a laboratory spectrum of frozen methane than to a synthetic spectrum of methane gas computed for conditions of low temperature expected at the satellite. Additionally, the strength of the bands vary with Triton's orbital position. The data thus suggest that methane in the ice phase is mostly responsible for the bands in Triton's spectrum, and that the ice is distributed nonuniformly around the satellite's surface.  相似文献   
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